Comment on "Perfect imaging with positive refraction in three dimensions"

Leonhard and Philbin [Phys. Rev. A 81, 011804(R) (2010)] have recently constructed a mathematical proof that the Maxwell's fish-eye lens provides perfect imaging of electromagnetic waves without negative refraction. In this comment, we argue that the unlimited resolution is an artifact of having introduced an unphysical drain at the position of the geometrical image. The correct solution gives focusing consistent with the standard diffraction limit

Exciton Beats in GaAs Quantum Wells: Bosonic Representation and Collective Effects

We discuss light-heavy hole beats observed in transient optical experiments in GaAs quantum wells in terms of a free-boson coherent state model. This approach is compared with descriptions based on few-level representations. Results lead to an interpretation of the beats as due to classical electromagnetic interference. The boson picture correctly describes photon excitation of extended states and accounts for experiments involving coherent control of the exciton density and Rayleigh scattering beating.Comment: 4 pages, no figures. Accepted for publication in Solid State Communication

Magnon squeezing in an antiferromagnet: reducing the spin noise below the standard quantum limit

At absolute zero temperature, thermal noise vanishes when a physical system is in its ground state, but quantum noise remains as a fundamental limit to the accuracy of experimental measurements. Such a limitation, however, can be mitigated by the formation of squeezed states. Quantum mechanically, a squeezed state is a time-varying superposition of states for which the noise of a particular observable is reduced below that of the ground state at certain times. Quantum squeezing has been achieved for a variety of systems, including the electromagnetic field, atomic vibrations in solids and molecules, and atomic spins, but not so far for magnetic systems. Here we report on an experimental demonstration of spin wave (i.e., magnon) squeezing. Our method uses femtosecond optical pulses to generate correlations involving pairs of magnons in an antiferromagnetic insulator, MnF2. These correlations lead to quantum squeezing in which the fluctuations of the magnetization of a crystallographic unit cell vary periodically in time and are reduced below that of the ground state quantum noise. The mechanism responsible for this squeezing is stimulated second order Raman scattering by magnon pairs. Such squeezed states have important ramifications in the emerging fields of spintronics and quantum computing involving magnetic spin states or the spin-orbit coupling mechanism

Observation of Surface-Avoiding Waves: A New Class of Extended States in Periodic Media

Coherent time-domain optical experiments on GaAs-AlAs superlattices reveal the exis-tence of an unusually long-lived acoustic mode at ~ 0.6 THz, which couples weakly to the environment by evading the sample boundaries. Classical as well as quantum states that steer clear of surfaces are generally shown to occur in the spectrum of periodic struc-tures, for most boundary conditions. These surface-avoiding waves are associated with frequencies outside forbidden gaps and wavevectors in the vicinity of the center and edge of the Brillouin zone. Possible consequences for surface science and resonant cavity ap-plications are discussed.Comment: 16 pages, 3 figure

Generation and remote detection of THz sound using semiconductor superlattices

The authors introduce a novel approach to study the propagation of high frequency acoustic phonons in which the generation and detection involves two spatially separated superlattices $\sim 1 {\rm \mu m}$ apart. Propagating modes of frequencies up to $\sim 1 {\rm THz}$ escape from the superlattice where they are generated and reach the second superlattice where they are detected. The measured frequency spectrum reveals finite size effects, which can be accounted for by a continuum elastic model.Comment: Submitted to Applied Physics Letter

Improved access to polythioesters by heterobimetallic aluminium catalysis

Bimetallic Al(III) catalysis mediates thioanhydride/epoxide copolymerisation at greatly improved rates and monomer tolerance than analogous Cr(III) catalysis. Moving to sulfurated monomers furthermore generally improves rates and selectivites

Long-lived optical phonons in ZnO studied with impulsive stimulated Raman scattering

The anharmonic properties of the low-frequency E2 phonon in ZnO were measured using impulsive stimulated Raman scattering. At 5 K, the frequency and lifetime are (2.9787 +/- 0.0002) THz and (211 +/- 7) ps. The unusually long lifetime and the high accuracy in the determination of the frequency hold promise for applications in metrology, quantum computation and materials characterization. The temperature dependence of the lifetime is determined by two-phonon up-conversion decay contributions, which vanish at zero temperature. Results suggest that the lifetime is limited by isotopic disorder and that values in the nanosecond range may be achievable in isotopically-pure samples

Exciton condensates in semiconductor quantum wells emit coherent light

We show that a quasi-two dimensional condensate of optically active excitons emits coherent light even in the absence of population inversion. This allows an unambiguous and clear experimental detection of the condensed phase. We prove that, due to the exciton-photon coupling, quantum and thermal fluctuations do not destroy condensation at finite temperature. Suitable conditions to achieve condensation are temperatures of a few K for typical exciton densities, and the use of a pulsed, and preferably circularly polarized, laser.Comment: 5 pages, no figure

Control of spin dynamics with laser pulses: Generation of entangled states of donor-bound electrons in a Cd1-xMnxTe quantum well

A quantum-mechanical many-particle system may exhibit non-local behavior in that measurements performed on one of the particles can affect a second one that is far apart. These so-called entangled states are crucial for the implementation of quantum information protocols and gates for quantum computation. Here, we use ultrafast optical pulses and coherent pump-probe techniques to create and control spin entangled states in an ensemble of up to three non-interacting electrons bound to donors in a Cd1-xMnxTe quantum well. Our method, relying on the exchange interaction between optically-excited excitons and the paramagnetic impurities, can in principle be applied to entangle an arbitrarily large number of electrons. A microscopic theory of impulsive stimulated Raman scattering and a model for multi-spin entanglement are presented. The signature of entanglement is the observation of overtones of donor spin-flips in the differential reflectivity of the probe pulse. Results are shown for resonant excitation of localized excitons below the gap, and above the gap where the signatures of entanglement are significantly enhanced. Data is also presented on the generation of coherent excitations of antiferromagnetically-coupled manganese pairs, folded acoustic phonons, exciton Zeeman beats and entanglement involving two Mn2+ ions.Comment: Long version of quant-ph/020619

Ring-opening terpolymerisation of phthalic thioanhydride with carbon dioxide and epoxides

In seeking to expand the portfolio of accessible polymer structures from CO2 waste, we report the ring-opening terpolymerisation (ROTERP) of phthalic thioanhydride with CO2 and epoxides, forming statistical poly(ester-thioester-carbonates) by employing heterobimetallic catalysts. Both metal choice and ligand chemistry modulate the amount of CO2 incorporated into the polymer microstructure. Terpolymerisation occurs when maintaining polymerisation rates of the faster parent ring-opening copolymerisation and this finding led us to develop the formation of CO2-derived terpolymers with butylene oxide at low CO2 pressure under bicomponent catalysis. Tetrapolymerisation with added phthalic anhydride leads to the preferential polymerisation of phthalic anhydride before the polymerisation of sulfur derivatives with CO2 and epoxides. Finally, we show that the presence of sulfur-containing thioester links leads to polymers with degradability benefits compared to those from all-oxygen derivatives