Electrochemical behavior of Sn-Zn alloys with different grain structures in chloride-containing solutions

In the present research the electrochemical behavior of the Sn-Zn alloys (Sn-1 wt.%Zn, Sn-4 wt.%Zn and 8.9 wt.%Zn) in 3% NaCl solution is analyzed using potentiodynamic cyclic polarization measurements and Electrochemical Impedance Spectroscopy (EIS) technique. Specimens were longitudinally solidified with simultaneous heat extraction in two opposite directions. Working electrodes were constructed using longitudinal and cross sections of the specimens with both types of structure: columnar and equiaxed. Results obtained from the polarization curves indicated that the two types of grain structures of Sn-Zn alloys (Sn-1 wt.%Zn, Sn-4 wt.%Zn and Sn-8.9 wt.%Zn) corresponding to longitudinal section present a pseudo passive zone. In the case of specimens from cross sections of the samples, the columnar and equiaxed zones of Sn-8.9 wt.%Zn are the only ones that do not have this pseudo passive region. In addition, the interdendritic zone of alloys is susceptible to corrosion by dealloying because this phase is zinc-rich. This type of corrosion also occurs in the zinc rich lamellar structure present in the eutectic. The percentage of zinc in the alloy increases with increasing susceptibility to pitting corrosion. The EIS values obtained revealed that the susceptibility to corrosion increases with increasing zinc content in alloys, for both the columnar and equiaxed zones. In addition, the columnar zones of Sn-4 wt.%Zn and Sn-8.9 wt.%Zn specimens are more resistant to corrosion than the equiaxed grain specimens. However, the equiaxed zone of Sn-1 wt.%Zn alloy is less susceptible to corrosion than the columnar zone. After adjustment by equivalent circuits it is revealed that the equiaxed zone of Sn-8.9 wt.%Zn alloy has a second porous layer composed of corrosion products on the electrode surface.Fil: Mendez, Claudia Marcela. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Scheiber, Verónica L.. Provincia de Misiones. Comité de Desarrollo e Innovación Tecnológica. Centro de Desarrollo e Innovación Tecnológica; ArgentinaFil: Rozicki, Roberto S.. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales; ArgentinaFil: Kociubczyk, Alex Iván. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Ares, Alicia Esther. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentin

Guidance, flight mechanics and trajectory optimization. Volume 6 - The N-body problem and special perturbation techniques

Analytical formulations and numerical integration methods for many body problem and special perturbative technique

The relation between bar formation, galaxy luminosity, and environment

We derive the bar fraction in three different environments ranging from the field to Virgo and Coma clusters, covering an unprecedentedly large range of galaxy luminosities (or, equivalently, stellar masses). We confirm that the fraction of barred galaxies strongly depends on galaxy luminosity. We also show that the difference between the bar fraction distributions as a function of galaxy luminosity (and mass) in the field and Coma cluster are statistically significant, with Virgo being an intermediate case. We interpret this result as a variation of the effect of environment on bar formation depending on galaxy luminosity. We speculate that brighter disk galaxies are stable enough against interactions to keep their cold structure, thus, the interactions are able to trigger bar formation. For fainter galaxies the interactions become strong enough to heat up the disks inhibiting bar formation and even destroying the disks. Finally, we point out that the controversy regarding whether the bar fraction depends on environment could be resolved by taking into account the different luminosity ranges of the galaxy samples studied so far.Comment: 4 pages, 2 figures. To appear in the proceedings of EWASS 2012 Special Session 4, Structure of galaxy disks shaped by secular evolution and environmental processes, ed. P. Di Matteo and C. Jog, Memorie della Societ\`a Astronomica Italiana Supplement Serie

Peanut-shaped bulges in face-on disk galaxies

We present high resolution absorption-line spectroscopy of 3 face-on galaxies, NGC 98, NGC 600, and NGC 1703 with the aim of searching for box/peanut (B/P)-shaped bulges. These observations test and confirm the prediction of Debattista et al. (2005) that face-on B/P-shaped bulges can be recognized by a double minimum in the profile of the fourth-order Gauss-Hermite moment h_4. In NGC 1703, which is an unbarred control galaxy, we found no evidence of a B/P bulge. In NGC 98, a clear double minimum in h_4 is present along the major axis of the bar and before the end of the bar, as predicted. In contrast, in NGC 600, which is also a barred galaxy but lacks a substantial bulge, we do not find a significant B/P shape.Comment: 4 pages, 1 figure. To appear in "Tumbling, twisting, and winding galaxies: Pattern speeds along the Hubble sequence", E. M. Corsini and V. P. Debattista (eds.), Memorie della Societa` Astronomica Italian

Multi-screen and multi-device game development

Users are interacting with an increasing number of devices and screens. However, these screens are usually used independently without collaboration between them. Although there have been several advances in multi-screen applications the game community does not seem to have fully explored this opportunity as yet. This paper presents an approach for the development of mobile multi-screen and multi-device games. The approach aims to enable and foster the creation of multi-device games sharing information via a centralized screen and is demonstrated by means of an example, the well-known Casino Roulette game. The results of a preliminary evaluation of the game are also presented.info:eu-repo/semantics/acceptedVersio

Delocalization of Wannier-Stark ladders by phonons: tunneling and stretched polarons

We study the coherent dynamics of a Holstein polaron in strong electric fields. A detailed analytical and numerical analysis shows that even for small hopping constant and weak electron-phonon interaction, polaron states can become delocalized if a resonance condition develops between the original Wannier-Stark states and the phonon modes, yielding both tunneling and `stretched' polarons. The unusual stretched polarons are characterized by a phonon cloud that {\em trails} the electron, instead of accompanying it. In general, our novel approach allows us to show that the polaron spectrum has a complex nearly-fractal structure, due to the coherent coupling between states in the Cayley tree which describes the relevant Hilbert space. The eigenstates of a finite ladder are analyzed in terms of the observable tunneling and optical properties of the system.Comment: 7 pages, 4 figure

Interaction Effects Among Two-Dimensional Electrons and Holes

We report large logarithmic corrections to the conductivity of two-dimensional electrons and holes in GaSb-InAs-GaSb double heterostructures. From ∼ 40 mK to 1 K, the conductivity increased with the logarithm of the temperature but with a slope as much as 30 times larger than estimated from the theories of weak localization and carrier interaction. The discrepancy apparently results from electron-hole interactions not included in the theory