Fingering instability in wildfire fronts

A two-dimensional model for the evolution of the fire line – the interface between burned and unburned regions of a wildfire – is formulated. The fire line normal velocity has three contributions: (i) a constant rate of spread representing convection and radiation effects; (ii) a curvature term that smooths the fire line; and (iii) a Stefan-like term in the direction of the oxygen gradient. While the first two effects are geometrical, (iii) is dynamical and requires the solution of the steady advection–diffusion equation for oxygen, with advection owing to a self-induced ‘fire wind’, modelled by the gradient of a harmonic potential field. The conformal invariance of this coupled pair of partial differential equations, which has the Péclet number Pe as its only parameter, is exploited to compute numerically the evolution of both radial and infinitely long periodic fire lines. A linear stability analysis shows that fire line instability is possible, dependent on the ratio of curvature to oxygen effects. Unstable fire lines develop finger-like protrusions into the unburned region; the geometry of these fingers is varied and depends on the relative magnitudes of (i)–(iii). It is argued that for radial fires, the fire wind strength scales with the fire's effective radius, meaning that Pe increases in time, so all fire lines eventually become unstable. For periodic fire lines, Pe remains constant, so fire line stability is possible. The results of this study provide a possible explanation for the formation of fire fingers observed in wildfires

Killing squirrels: Exploring motivations and practices of lethal wildlife management

This is the author accepted manuscript. The final version is available from Sage via the DOI in this record.Wildlife management, pest control and conservation projects often involve killing nonhuman animals. In the United Kingdom, introduced grey squirrels Sciurus carolinensis are killed in large numbers to protect remnant populations of European red squirrels Sciurus vulgaris. Grey squirrels are also killed outside of red squirrel areas to protect broadleaved trees from squirrel damage, and as part of routine pest control, opportunistically, and sometimes recreationally. In order to investigate the ways in which this killing is conceived and practised in the United Kingdom, we conducted semi-structured interviews with practitioners and undertook participant observation of squirrel management activities, including lethal control. Analysing these field data, we identified important variations in practitioners’ approaches to killing squirrels, and here we outline three ‘modes of killing’ – reparative/sacrificial, stewardship, and categorical – which comprise different primary motivations, moral principles, ultimate aims, and practical methods. We explore both productive alliances and possible tensions between these modes, and propose that clear, explicit consideration of how and why animals are both killed and ‘made killable’ should be a key component of any wildlife management initiative that involves lethal control.SLC was supported by a scholarship from the University of Exeter

The structure of latherin, a surfactant allergen protein from horse sweat and saliva

Latherin is a highly surface-active allergen protein found in the sweat and saliva of horses and other equids. Its surfactant activity is intrinsic to the protein in its native form, and is manifest without associated lipids or glycosylation. Latherin probably functions as a wetting agent in evaporative cooling in horses, but it may also assist in mastication of fibrous food as well as inhibition of microbial biofilms. It is a member of the PLUNC family of proteins abundant in the oral cavity and saliva of mammals, one of which has also been shown to be a surfactant and capable of disrupting microbial biofilms. How these proteins work as surfactants while remaining soluble and cell membrane-compatible is not known. Nor have their structures previously been reported. We have used protein nuclear magnetic resonance spectroscopy to determine the conformation and dynamics of latherin in aqueous solution. The protein is a monomer in solution with a slightly curved cylindrical structure exhibiting a ‘super-roll’ motif comprising a four-stranded anti-parallel β-sheet and two opposing α-helices which twist along the long axis of the cylinder. One end of the molecule has prominent, flexible loops that contain a number of apolar amino acid side chains. This, together with previous biophysical observations, leads us to a plausible mechanism for surfactant activity in which the molecule is first localized to the non-polar interface via these loops, and then unfolds and flattens to expose its hydrophobic interior to the air or non-polar surface. Intrinsically surface-active proteins are relatively rare in nature, and this is the first structure of such a protein from mammals to be reported. Both its conformation and proposed method of action are different from other, non-mammalian surfactant proteins investigated so far

New insights into the relationship between draw solution chemistry and trace organic rejection by forward osmosis

© 2019 This study elucidates the impact of draw solution chemistry (in terms of pH and draw solute species) and membrane fouling on water flux and the rejection of trace organic contaminants by forward osmosis. The results show that draw solution chemistry could induce a notable impact on both water flux and TrOCs rejection. In addition, the impact was further influenced by membrane fouling. The reverse flux of proton (or hydroxyl) could alter the feed solution pH, which governed the separation of ionisable TrOCs. In addition, charged compounds generally exhibited higher rejections than neutral ones by the clean membrane. Electrostatic interaction, rather than size exclusion, was therefore the dominant rejection mechanism for most compounds. There was also a weak correlation between rejection and molecular sizes of the 43 TrOCs. Compared with Na+, Li+ with a larger hydrated radius showed a significantly lower reverse salt flux, resulting in a lower ionic strength and therefore a stronger electrostatic interaction. A fouling cake layer consisted of low molecular weight neutral organics could also affect TrOC rejection due to pore blockage and cake-enhanced concentration polarisation

Psychosocial therapy for Parkinson's-related dementia: intervention development.

Background: Group-based psychosocial therapy, such as group Cognitive Stimulation Therapy, improves cognition and quality of life in people living with dementia. Neuropsychiatric symptoms and restricted mobility are common complications for people with Parkinson's-related dementia (PRD) and may limit access to, and participation in, group activities. This study describes the development of a condition-specific, home-based psychosocial therapy for people with PRD ready to be trialled in a clinical population. Methods: By means of a multistage process, a draft therapy manual was developed in an iterative manner through collaboration with medical experts, researchers and Patient and Public Involvement (PPI) representatives. In stage 1, an extensive literature search of psychosocial therapies for dementia with potential relevance for Parkinson's disease (PD) was undertaken to select a candidate therapy for adaptation. In stage 2, qualitative feedback from stakeholders and intelligence regarding existing nonpharmacological therapies for cognitive impairment in PD was combined to produce a prototype therapy manual. In stage 3, the manual was field tested in: 1) a home-setting using a 25-item assessment tool; and 2) at a local PD support group with PPI representatives. Based on the feedback from this phase, final design modifications were implemented and a draft therapy manual produced. Results: The manual was developed in an iterative manner. Interview and focus group transcripts identified three enduring themes: manual form and content, therapy acceptability by people with PRD, and companion guidance and support. Major adaptations included: removal of discrete levels of task complexity, removal of images that were potentially hallucinogenic or lacked clarity, and updating of the content. Conclusion: We have successfully developed a Cognitive Stimulation Therapy-based psychosocial therapy specifically adapted for people with PRD. The therapy is ready to trial in a pilot randomized controlled study

Removal of organic matter from wastewater reverse osmosis concentrate using granular activated carbon and anion exchange resin adsorbent columns in sequence.

Reverse osmosis concentrate (ROC) generated as a waste stream during reverse osmosis treatment of reclaimed wastewater, presents significant disposal challenges. This is because it causes environmental pollution when it is disposed to lands and natural water bodies. A long-term dynamic adsorption experiment was conducted by passing ROC from a wastewater reclamation plant, firstly through a granular activated carbon (GAC) column, and subsequently through an anion exchange resin (Purolite) column, for the removal of two major ROC pollutants, namely dissolved organic carbon (DOC) and microorganic pollutants (MOP). GAC removed most of the smaller-sized low molecular weight neutrals and building block fractions as well as the hydrophobic fraction of DOC with much less removal by the subsequent Purolite column. In contrast, the humics fraction was less well removed by the GAC column; however, Purolite column removed all that was remaining of this fraction. This study demonstrated that combining adsorbents having different affinities towards a variety of DOC fractions constitute an effective method of taking advantage of their different properties and achieving larger DOC removals. Almost 100% of all 17 MOPs were removed by the GAC column, even after 2880 bed volumes of continuous use. This contrasted with the DOC fractions' removal which was much lower

An anaerobic membrane bioreactor – membrane distillation hybrid system for energy recovery and water reuse: Removal performance of organic carbon, nutrients, and trace organic contaminants

© 2018 In this study, a direct contact membrane distillation (MD) unit was integrated with an anaerobic membrane bioreactor (AnMBR) to simultaneously recover energy and produce high quality water for reuse from wastewater. Results show that AnMBR could produce 0.3–0.5 L/g CODadded biogas with a stable methane content of approximately 65%. By integrating MD with AnMBR, bulk organic matter and phosphate were almost completely removed. The removal of the 26 selected trace organic contaminants by AnMBR was compound specific, but the MD process could complement AnMBR removal, leading to an overall efficiency from 76% to complete removal by the integrated system. The results also show that, due to complete retention, organic matter (such as humic-like and protein-like substances) and inorganic salts accumulated in the MD feed solution and therefore resulted in significant fouling of the MD unit. As a result, the water flux of the MD process decreased continuously. Nevertheless, membrane pore wetting was not observed throughout the operation

Electroweak Constraints on Warped Geometry in Five Dimensions and Beyond

Here we consider the tree level corrections to electroweak (EW) observables from standard model (SM) particles propagating in generic warped extra dimensions. The scale of these corrections is found to be dominated by three parameters, the Kaluza-Klein (KK) mass scale, the relative coupling of the KK gauge fields to the Higgs and the relative coupling of the KK gauge fields to fermion zero modes. It is found that 5D spaces that resolve the hierarchy problem through warping typically have large gauge-Higgs coupling. It is also found in $D>5$ where the additional dimensions are warped the relative gauge-Higgs coupling scales as a function of the warp factor. If the warp factor of the additional spaces is contracting towards the IR brane, both the relative gauge-Higgs coupling and resulting EW corrections will be large. Conversely EW constraints could be reduced by finding a space where the additional dimension's warp factor is increasing towards the IR brane. We demonstrate that the Klebanov Strassler solution belongs to the former of these possibilities.Comment: 18 pages, 3 figures (references added) version to appear in JHE

Effects of sulphur on the performance of an anaerobic membrane bioreactor: Biological stability, trace organic contaminant removal, and membrane fouling

© 2017 This study investigated the impact of sulphur content on the performance of an anaerobic membrane bioreactor (AnMBR) with an emphasis on the biological stability, contaminant removal, and membrane fouling. Removal of 38 trace organic contaminants (TrOCs) that are ubiquitously present in municipal wastewater by AnMBR was evaluated. Results show that basic biological performance of AnMBR regarding biomass growth and the removal of chemical oxygen demand (COD) was not affected by sulphur addition when the influent COD/SO42− ratio was maintained higher than 10. Nevertheless, the content of hydrogen sulphate in the produced biogas increased significantly and membrane fouling was exacerbated with sulphur addition. Moreover, the increase in sulphur content considerably affected the removal of some hydrophilic TrOCs and their residuals in the sludge phase during AnMBR operation. By contrast, no significant impact on the removal of hydrophobic TrOCs was noted with sulphur addition to AnMBR

The fate of trace organic contaminants during anaerobic digestion of primary sludge: A pilot scale study

© 2018 A pilot-scale study was conducted to investigate the fate of trace organic contaminants (TrOCs) during anaerobic digestion of primary sludge. Of the 44 TrOCs monitored, 24 were detected in all primary sludge samples. Phase distribution of TrOCs was correlated well with their hydrophobicity (>67% mass in the solid phase when LogD > 1.5). The pilot-scale anaerobic digester achieved a steady performance with a specific methane yield of 0.39–0.92 L/gVSremoved and methane composition of 63–65% despite considerable variation in the primary sludge. The fate of TrOCs in the aqueous and solid phases was governed by their physicochemical properties. Biotransformation was significant (>83%) for five TrOCs with logD 1.5 were poorly removed under anaerobic conditions. Sorption onto the solid phase appears to impede the biodegradation of these TrOCs