6,613 research outputs found
Return migration as channel of brain gain
Recent theoretical and empirical studies have emphasized the fact that the prospect of international migration increases the expected returns to skills in poor countries,
linking the possibility of migrating (brain drain) with incentives to higher education (brain gain). If emigration is uncertain and some of the highly educated remain,
such a channel may, at least in part, counterbalance the negative effects of brain drain. Moreover, recent empirical evidence seems to show that temporary migration
is widespread among highly skilled migrants (such as Eastern Europeans in Western Europe and Asians in the U.S.). This paper develops a simple tractable overlapping
generations model that provides an economic rationale for return migration and which predicts who will migrate and who will return among agents with heterogeneous abilities. We use parameter values from the literature and the data
on return migration to calibrate our model and simulate and quantify the effects of increased openness on human capital and wages of the sending countries. We find that, for plausible values of the parameters, the return migration channel is very important and combined with the incentive channel reverses the brain drain into significant brain gain for the sending country
Cycloadditionsreaktionen von Allenyl-Kationen mit Cyclopentadien
Propargylhalogenide R1 C C CR2R3X (14) und Cyclopentadien reagieren in Gegenwart von Zinkhalogeniden in Ether/Dichlormethan unter Bildung von 3-Halogenbicyclo[3.2.1]octa-2,6-dienen 13 (R1 = Alkyl) oder 5-(-Halogenbenzyliden)norbornenen 15 (R1 = Aryl). Die Reaktionen werden durch stufenweise [3 + 4]- bzw. [2 + 4]-Cycloadditionen intermediärer Allenyl-Kationen 1 erklärt, wobei die Propargylcyclopentenyl-Kationen 5 sowie die bicyclischen Vinyl-Kationen 9 oder 12 als Zwischenstufen durchlaufen werden. Initiiert man diese Reaktionen durch äquimolare Mengen Silbertrifluoracetat, lassen sich Abfangprodukte aller postulierten Zwischenstufen isolieren. Die relativen Energieinhalte der intermediären Carbenium-Ionen werden mit Hilfe von Kraftfeldrechnungen unter Verwendung von Gasphasenstabilitäten einfacher Carbokationen ermittelt. Stereochemische Untersuchungen zeigen, daß die Additionsreaktionen den kompakten Übergangszustand 42 gegenüber 41 bevorzugen. Bei der Umsetzung des Propargylchlorids 14e mit Cyclopentadien erhält man unter Zinkchloridkatalyse außer dem 1:1-Produkt 15e noch ein pentacyclisches 2:1-Produkt 17, das durch Röntgenstrukturanalyse aufgeklärt wurde. Seine Bildung läßt sich durch [2 + 2]-Cycloaddition eines Allenyl-Kations mit Cyclopentadien erklären
On the global circulation and the hurricane system of the Jovian atmosphere
An argument is made to support the proposal that Jupiter's red spot and the white and brown ovals are hurricanes or cyclones. Against the background of a convectively unstable troposphere, the general condition exists for the formation of hurricanes. The energy Jupiter emits must be transported upwards through the troposphere. If that transport is accelerated by the prevailing upward motions in the solar driven multicellular meridional circulation, eastward jets develop such as observed in the l region. But if that vertical transport is impeded by the prevailing downward motions in the meridional circulation, the atmosphere reacts and tends to maintain the process through the development of hurricanes. Dynamically induced by solar differential heating, an ordered latitudinal structure with alternating stability and instability is impressed on the troposphere to form alternating zonal strata where hurricanes are forbidden and permitted, respectively
Plastic deformation of metallic glasses: Size of shear transformation zones from molecular dynamics simulations
Plastic deformation in metallic glasses well below their glass transition temperatures Tg occurs spatially heterogeneously within highly localized regions, termed shear transformation zones (STZs). Yet, their size and the number of atoms involved in a local shear event, remains greatly unclear. With the help of classical molecular dynamics (MD) computer simulations on plastic deformation of the model glass CuTi during pure shearing, we address this issue by evaluating correlations in atomic-scale plastic displacements, viz. the displacement correlation function. From the correlation length, a universal diameter of about 15 Å, or, equivalently, approximately 120 atoms is derived for a variety of conditions, such as variable strains, strain rates, temperatures, and boundary conditions. Our findings are consistent with a recent model proposed by Johnson and Samwer [Phys. Rev. Lett. 95, 195501 (2005)]
On the Seasonal and Day to Day Variations in the F2 Region
Thermoelectric scatter measurements on seasonal and daily variations in F region electron concentratio
Amorphous thin film growth: theory compared with experiment
Experimental results on amorphous ZrAlCu thin film growth and the dynamics of
the surface morphology as predicted from a minimal nonlinear stochastic
deposition equation are analysed and compared. Key points of this study are (i)
an estimation procedure for coefficients entering into the growth equation and
(ii) a detailed analysis and interpretation of the time evolution of the
correlation length and the surface roughness. The results corroborate the
usefulness of the deposition equation as a tool for studying amorphous growth
processes.Comment: 7 pages including 5 figure
Electronic and phonon excitations in {\alpha}-RuCl
We report on THz, infrared reflectivity and transmission experiments for wave
numbers from 10 to 8000 cm ( 1 meV - 1 eV) and for temperatures
from 5 to 295 K on the Kitaev candidate material {\alpha}-RuCl. As reported
earlier, the compound under investigation passes through a first-order
structural phase transition, from a monoclinic high-temperature to a
rhombohedral low-temperature phase. The phase transition shows an extreme and
unusual hysteretic behavior, which extends from 60 to 166 K. In passing this
phase transition, in the complete frequency range investigated we found a
significant reflectance change, which amounts almost a factor of two. We
provide a broadband spectrum of dielectric constant, dielectric loss and
optical conductivity from the THz to the mid infrared regime and study in
detail the phonon response and the low-lying electronic density of states. We
provide evidence for the onset of an optical energy gap, which is of order 200
meV, in good agreement with the gap derived from measurements of the DC
electrical resistivity. Remarkably, the onset of the gap exhibits a strong blue
shift on increasing temperatures.Comment: 18 pages, 7 figure
Phonon anomalies and charge dynamics in Fe_{1-x}Cu_{x}Cr_{2}S_{4} single crystals
A detailed investigation of phonon excitations and charge carrier dynamics in
single crystals of Fe_{1-x}Cu_{x}Cr_{2}S_{4} (x = 0, 0.2, 0.4, 0.5) has been
performed by using infrared spectroscopy. In FeCr_{2}S_{4} the phonon
eigenmodes are strongly affected by the onset of magnetic order. Despite
enhanced screening effects, a continuous evolution of the phonon excitations
can be observed in the doped compounds with x = 0.2 (metallic) and x = 0.4, 0.5
(bad metals), but the effect of magnetic ordering on the phonons is strongly
reduced compared to x = 0. The Drude-like charge-carrier contribution to the
optical conductivity in the doped samples indicates that the colossal
magneto-resistance effect results from the suppression of spin-disorder
scattering.Comment: 8 pages, 6 figure
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