7 research outputs found
Spatially resolved X ray absorption spectroscopy investigation of individual cation intercalated multi layered Ti3C2Tx MXene particles
Ti3C2Tx MXene is a two dimensional 2D material possessing highly active hydrophilic surfaces coupled with high metallic conductivity. Cations intercalation between the Ti3C2Tx nanosheets has a significant role in many applications such as water purification, desalination, and electrochemical energy storage. The pseudocapacitive charging mechanism involving surface redox reactions at the Ti3C2Tx surface enables higher energy densities than electrical double layer capacitors, and higher power densities than batteries. In this context, the oxidation state of surface Ti atoms involved in redox reactions has a high impact on the capacitance of Ti3C2Tx MXene and this can be impacted by cation intercalation. Thus, the electronic structure of multi layered Ti3C2Tx particles is investigated by X ray absorption XA spectroscopy, while also benefitting from a high spatial resolution of 30 nm from X ray photoemission electron microscopy. In this work, the XA spectra from multi layered intercalated Ti3C2Tx particles of different thicknesses were recorded at the Ti L and O K edges. The Ti oxidation state in pristine, Li , and Mg intercalated Ti3C2Tx was found to be thickness dependent, while Na and K intercalated Ti3C2Tx particles did not reveal differences upon changing thickness. This work demonstrates thickness dependent modification of the MXene surface chemistry upon cation intercalation in different individual Ti3C2Tx particle
Enhancement of Ti3C2 MXene Pseudocapacitance after Urea Intercalation Studied by Soft X ray Absorption Spectroscopy
MXenes have shown outstanding properties due to their highly active hydrophilic surfaces coupled with high metallic conductivity. Many applications rely on the intercalation between Ti3C2Tx Tx describes the OH, F and O surface terminations flakes by ions or molecules, which in turn might alter the Ti3C2Tx surface chemistry and electrochemical properties. In this work, we show that the capacitance, rate capability, and charge carrier kinetics in Ti3C2Tx MXene electrodes are remarkably enhanced after urea intercalation u Ti3C2Tx . In particular, the areal capacitance increased to 1100 mF cm2, which is 56 higher than that of pristine Ti3C2Tx electrodes. We attribute this dramatic improvement to changes in the Ti3C2Tx surface chemistry upon urea intercalation. The oxidation state and the oxygen bonding of individual Ti3C2Tx flakes before and after urea intercalation are probed by soft X ray absorption spectroscopy XAS at the Ti L and O K edges with 30 nm spatial resolution in vacuum. After urea intercalation, a higher Ti oxidation state is observed across the entire flake compared to pristine Ti3C2Tx. Additionally, in situ XAS of u Ti3C2Tx aqueous dispersions reveal a higher Ti oxidation similar to dry samples, while for pristine Ti3C2Tx the Ti atoms are significantly reduced in water compared to dry sample
Layer Dependent Magnetic Domains in Atomically Thin Fe5GeTe2
Magnetic domain formation in two dimensional 2D materials gives perspectives into the fundamental origins of 2D magnetism and also motivates the development of advanced spintronics devices. However, the characterization of magnetic domains in atomically thin van der Waals vdW flakes remains challenging. Here, we employ X ray photoemission electron microscopy XPEEM to perform layer resolved imaging of the domain structures in the itinerant vdW ferromagnet Fe5GeTe2 which shows near room temperature bulk ferromagnetism and a weak perpendicular magnetic anisotropy PMA . In the bulk limit, we observe the well known labyrinth type domains. Thinner flakes, on the other hand, are characterized by increasingly fragmented domains. While PMA is a characteristic property of Fe5GeTe2, we observe a spin reorientation transition with the spins canting in plane for flakes thinner than six layers. Notably, a bubble phase emerges in four layer flakes. This thickness dependence, which clearly deviates from the single domain behavior observed in other 2D magnetic materials, demonstrates the exciting prospect of stabilizing complex spin textures in 2D vdW magnets at relatively high temperature
Strain induced shape anisotropy in antiferromagnetic structures
We demonstrate how shape dependent strain can be used to control antiferromagnetic order in NiO Pt thin films. For rectangular elements patterned along the easy and hard magnetocrystalline anisotropy axes of our film, we observe different domain structures and we identify magnetoelastic interactions that are distinct for different domain configurations. We reproduce the experimental observations by modeling the magnetoelastic interactions, considering spontaneous strain induced by the domain configuration, as well as elastic strain due to the substrate and the shape of the patterns. This allows us to demonstrate and explain how the variation of the aspect ratio of rectangular elements can be used to control the antiferromagnetic ground state domain configuration. Shape dependent strain does not only need to be considered in the design of antiferromagnetic devices, but can potentially be used to tailor their properties, providing an additional handle to control antiferromagnet
From stripes to bubbles Deterministic transformation of magnetic domain patterns in Co Pt multilayers induced by laser helicity
The optical control of magnetism offers an attractive possibility to manipulate small magnetic domains for prospective memory devices on ultrashort timescales. Here, we report on the local deterministic transformation of the magnetic domain pattern from stripes to bubbles in out of plane magnetized Co Pt multilayers controlled only by the helicity of ultrashort laser pulses. Relying on the experimentally determined average size of stripe domains and the magnetic layer thickness, we calculate the temperature and characteristic fields at which the stripe bubble transformation occurs. Furthermore, we demonstrate that in the narrow range of the laser power, the helicity induces a drag on domain wall
Domain Wall Damping in Ultrathin Nanostripes with Dzyaloshinskii Moriya Interaction
Asymmetrically sandwiched thin magnetic layers with perpendicular anisotropy and Dzyaloshinskii Moriya interaction DMI is the prospective material science platform for spin orbitronic technologies that rely on the motion of chiral magnetic textures, like skyrmions or chiral domain walls DWs . The dynamic performance of a DW based racetrack is defined by the strength of the DMI and the DW damping. The determination of the latter parameter is typically done based on technically challenging DW motion experiments. Here, we propose a method to access both the DMI constant and DW damping from static experiments by monitoring the tilt of magnetic DWs in nanostripes. We experimentally demonstrate that in perpendicularly magnetized CrOx Co Pt stacks, DWs can be trapped on edge roughness in a metastable tilted state as a result of the DW dynamics driven by an external magnetic field. The measured tilt can be correlated to the DMI strength and DW damping in a self consistent way in the frame of a theoretical formalism based on the collective coordinate approac
Scaling of intrinsic domain wall magnetoresistance with confinement in electromigrated nanocontacts
In this work we study the evolution of intrinsic domain wall magnetoresistance DWMR with domain wall confinement. Notched half ring nanocontacts are fabricated from Permalloy using a special ultrahigh vacuum electromigration procedure to tailor the size of the wire in situ and through the resulting domain wall confinement, we tailor the domain wall width from a few tens of nm down to a few nm. Through measurements of the dependence of the resistance with respect to the applied field direction, we extract the contribution of a single domain wall to the MR of the device, as a function of the width of the domain wall in the confining potential at the notch. In this size range, an intrinsic positive MR is found which dominates over anisotropic MR, as confirmed by comparison to micromagnetic simulations. Moreover, the MR is found to scale monotonically with the size of the domain wall, amp; 948;DW, as 1 amp; 948;bDW, with b 2.31 0.39. The experimental result is supported by quantum mechanical transport simulations based on ab initio density functional theory calculation