Giant electrocaloric effect in thin film Pb Zr_0.95 Ti_0.05 O_3

An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. This phenomenon has been largely ignored because only small effects (0.003 K V^-1) have been seen in bulk samples such as Pb0.99Nb0.02(Zr0.75Sn0.20Ti0.05)0.98O3 and there is no consensus on macroscopic models. Here we demonstrate a giant electrocaloric effect (0.48 K V^-1) in 300 nm sol-gel PbZr0.95Ti0.05O3 films near the ferroelectric Curie temperature of 222oC. We also discuss a solid state device concept for electrical refrigeration that has the capacity to outperform Peltier or magnetocaloric coolers. Our results resolve the controversy surrounding macroscopic models of the electrocaloric effect and may inspire ab initio calculations of electrocaloric parameters and thus a targeted search for new materials.Comment: 5 pages, 4 figure

The layer disorders defect in coir fiber under thermal and chemical treatment

Natural coir fibers, subjectd to thermal treatments in the range of 0oC to 200oC and alkali treatment with 5% to 30% concentration w/w, have been used in the present investigation to determine the interlayer variability of the cellulose planes (020), (110) and (110). Among the equatorial reflections (110), (110) and (020), the extent of variability is found to be more with the proportion of such affected planes less for (020) reflection in the native cellulose at lower temperature while at higher temperature (110) and (110) become more affected by variability defect. (110) and (1 10) planes are more affected also with alkali treatment.The layer disorders defect in coir fiber under thermal and chemical treatment D N Mahato*, B K Mathur and S Bhattacharjee Department of Physics, Indian Institute of Technology, Kharagpur-721 302, West Bengal, India E-mail : [email protected] of Physics, Indian Institute of Technology, Kharagpur-721 302, West Bengal, Indi

Nanoscale magnetic structure of ferromagnet/antiferromagnet manganite multilayers

Polarized Neutron Reflectometry and magnetometry measurements have been used to obtain a comprehensive picture of the magnetic structure of a series of La{2/3}Sr{1/3}MnO{3}/Pr{2/3}Ca{1/3}MnO{3} (LSMO/PCMO) superlattices, with varying thickness of the antiferromagnetic (AFM) PCMO layers (0<=t_A<=7.6 nm). While LSMO presents a few magnetically frustrated monolayers at the interfaces with PCMO, in the latter a magnetic contribution due to FM inclusions within the AFM matrix was found to be maximized at t_A~3 nm. This enhancement of the FM moment occurs at the matching between layer thickness and cluster size, where the FM clusters would find the optimal strain conditions to be accommodated within the "non-FM" material. These results have important implications for tuning phase separation via the explicit control of strain.Comment: 4 pages, submitted to PR

Phase Diagram of Half Doped Manganites

An analysis of the properties of half-doped manganites is presented. We build up the phase diagram of the system combining a realistic calculation of the electronic properties and a mean field treatment of the temperature effects. The electronic structure of the manganites are described with a double exchange model with cooperative Jahn-Teller phonons and antiferromagnetic coupling between the $Mn$ core spins. At zero temperature a variety of electronic phases as ferromagnetic (FM) charge ordered (CO) orbital ordered (OO), CE-CO-OO and FM metallic, are obtained. By raising the temperature the CE-CO-OO phase becomes paramagnetic (PM), but depending on the electron-phonon coupling and the exchange coupling the transition can be direct or trough intermediate states: a FM disorder metallic, a PM-CO-OO or a FM-CO-OO. We also discus the nature of the high temperature PM phase in the regime of finite electron phonon coupling. In this regime half of the oxygen octahedra surrounding the $Mn$ ions are distorted. In the weak coupling regime the octahedra are slightly deformed and only trap a small amount of electronic charge, rendering the system metallic consequentially. However in the strong coupling regime the octahedra are strongly distorted, the charge is fully localized in polarons and the system is insulator.Comment: 10 pagses, 9 figures include

The information paradox: A pedagogical introduction

The black hole information paradox is a very poorly understood problem. It is often believed that Hawking's argument is not precisely formulated, and a more careful accounting of naturally occurring quantum corrections will allow the radiation process to become unitary. We show that such is not the case, by proving that small corrections to the leading order Hawking computation cannot remove the entanglement between the radiation and the hole. We formulate Hawking's argument as a `theorem': assuming `traditional' physics at the horizon and usual assumptions of locality we will be forced into mixed states or remnants. We also argue that one cannot explain away the problem by invoking AdS/CFT duality. We conclude with recent results on the quantum physics of black holes which show the the interior of black holes have a `fuzzball' structure. This nontrivial structure of microstates resolves the information paradox, and gives a qualitative picture of how classical intuition can break down in black hole physics.Comment: 38 pages, 7 figures, Latex (Expanded form of lectures given at CERN for the RTN Winter School, Feb 09), typo correcte