A late medieval warm period in the Southern Ocean as a delayed response to external forcing?

International audienceOn the basis of long simulations performed with a three‐dimensional climate model, we propose an interhemispheric climate lag mechanism, involving the long‐term memory of deepwater masses. Warm anomalies, formed in the North Atlantic when warm conditions prevail at surface, are transported by the deep ocean circulation towards the Southern Ocean. There, the heat is released because of large scale upwelling, maintaining warm conditions and inducing a lagged response of about 150 years compared to the Northern Hemisphere. Model results and observations covering the first half of the second millenium suggest a delay between the temperature evolution in the Northern Hemisphere and in the Southern Ocean. The mechanism described here provides a reasonable hypothesis to explain such an interhemipsheric lag

Bidecadal North Atlantic ocean circulation variability controlled by timing of volcanic eruptions

International audienceWhile bidecadal climate variability has been evidenced in several North Atlantic paleoclimaterecords, its drivers remain poorly understood. Here we show that the subset of CMIP5historical climate simulations that produce such bidecadal variability exhibits a robustsynchronization, with a maximum in Atlantic Meridional Overturning Circulation (AMOC) 15years after the 1963 Agung eruption. The mechanisms at play involve salinity advection fromthe Arctic and explain the timing of Great Salinity Anomalies observed in the 1970s and the1990s. Simulations, as well as Greenland and Iceland paleoclimate records, indicate thatcoherent bidecadal cycles were excited following five Agung-like volcanic eruptions of the lastmillennium. Climate simulations and a conceptual model reveal that destructive interferencecaused by the Pinatubo 1991 eruption may have damped the observed decreasing trend of theAMOC in the 2000s. Our results imply a long-lasting climatic impact and predictabilityfollowing the next Agung-like eruption

Holocene climate variability from ice core records in the Ross Sea area (East Antarctica)

Past polar climate variability can be documented at high resolution thanks to ice core records, which have revealed significant Holocene variations in Antarctica. Paleotemperature reconstructions from Antarctic ice cores are mainly based on δ18O (δD) records, a proxy for local, precipitation-weighted atmospheric temperatures. Here, we present a new climate record spanning the past 12,000 years resulting from high resolution (10 cm) stable isotope analyses of the ice core drilled at Talos Dome (TD) in East Antarctica from 2003 to 2007 in the framework of the TALDICE (TALos Dome Ice CorE) project. Talos Dome (72° 49’S, 15911’E; 2315 m; -41°C) is an ice dome on the edge of the East Antarctic plateau, where moisture is mainly advected from the Indian and western Pacific sectors of the Southern Ocean. Pacific moisture arriving at TD has been transported above the Ross Sea, where extensive presence of sea ice also occurs during summer. High-resolution δ18O data have been measured using both IRMS and CRDS techniques on 10 cm samples, leading to a mean time resolution of two years. The long-term trend of the TALDICE δ18O profile shows characteristic features already observed in other ice cores from the East Antarctic plateau. Following the approach of Pol et al. (2011), high frequency climate variability has been investigated using a 3000-year running standard deviation on the de-trended record. The results are compared to the same analysis performed on the nearby Taylor Dome ice core δ18O O data, which is the single East Antarctic ice core showing a strong Holocene decreasing trend. Despite these trend differences, both sites share common features regarding changes in variance. We also investigate changes in deuterium excess, a proxy reflecting changes in moisture source conditions. Both deuterium excess records show a two-step increasing trend in the first part of the Holocene. Taylor Dome deuterium excess however depicts an enhanced variability since about 7000 years BP. A wavelet analysis shows a change in isotopic variability patterns at 6-7000 years BP at both sites, suggesting changes in regional climate variability attributed to the opening of the Ross Sea area after the deglaciation

Summer Temperature Trend Over the Past Two Millennia Using Air Content in Himalayan Ice

Two Himalayan ice cores display a factor-two decreasing trend of air content over the past two millennia, in contrast to the relatively stable values in Greenland and Antarctica ice cores over the same period. Because the air content can be related with the relative frequency and intensity of melt phenomena, its variations along the Himalayan ice cores provide an indication of summer temperature trend. Our reconstruction point toward an unprecedented warming trend in the 20th century but does not depict the usual trends associated with Medieval Warm Period (MWP), or Little Ice Age (LIA)

Ranges of moisture-source temperature estimated from Antarctic ice cores stable isotope records over glacial–interglacial cycles

A single isotope ratio (δD or δ18O) of water is widely used as an air-temperature proxy in Antarctic ice cores. These isotope ratios, however, do not solely depend on air-temperature but also on the extent of distillation of heavy isotopes out of atmospheric water vapor from an oceanic moisture source to a precipitation site. The temperature changes at the oceanic moisture source (ΔTsource) and at the precipitation site (ΔTsite) can be retrieved by using deuterium-excess (d) data. A new d record from Dome Fuji, Antarctica is produced spanning the past 360,000 years and compared with records from Vostok and EPICA Dome C ice cores. To retrieve ΔTsource and ΔTsite information, different linear regression equations have been proposed using theoretical isotope distillation models. A major source of uncertainty lies in the coefficient of regression, βsite which is related to the sensitivity of d to ΔTsite. We show that different ranges of temperature and selections of isotopic model outputs may increase the value of βsite by a factor of two. To explore the impacts of this coefficient on the reconstructed temperatures, we apply for the first time the exact same methodology to the isotope records from the three Antarctica ice cores. We show that uncertainties in the βsite coefficient strongly affect (i) the glacial-interglacial magnitude of ΔTsource; (ii) the imprint of obliquity in ΔTsource and in the site-source temperature gradient. By contrast, we highlight the robustness of ΔTsite reconstruction using water isotopes records

Developing a western Siberia reference site for tropospheric water vapour isotopologue observations obtained by different techniques (in situ and remote sensing)

Water stable isotopologues provide integrated tracers of the atmospheric water cycle, affected by changes in air mass origin, non-convective and convective processes and continental recycling. Novel remote sensing and in situ measuring techniques have recently offered opportunities for monitoring atmospheric water vapour isotopic composition. Recently developed infrared laser spectrometers allow for continuous in situ measurements of surface water vapour δD_v and δ¹⁸O_v. So far, very few intercomparisons of measurements conducted using different techniques have been achieved at a given location, due to difficulties intrinsic to the comparison of integrated with local measurements. Nudged simulations conducted with high-resolution isotopically enabled general circulation models (GCMs) provide a consistent framework for comparison with the different types of observations. Here, we compare simulations conducted with the ECHAM5-wiso model with two types of water vapour isotopic data obtained during summer 2012 at the forest site of Kourovka, western Siberia: hourly ground-based FTIR total atmospheric columnar δD_v amounts, and in situ hourly Picarro δD_v measurements. There is an excellent correlation between observed and predicted δD_v at surface while the comparison between water column values derived from the model compares well with FTIR estimates

Target atmospheric CO2: Supporting material

Additional material supporting the article "Target atmospheric CO2: Where should humanity aim?"Comment: 27 pages, 21 figures; final version accepted by Open Science Atmospheric Journal; main article separately submitted to arXiv as "Target atmospheric CO2: Where should humanity aim?", arxiv:0804.112

Storage of Carbon Dioxide in Saline Aquifers: Physicochemical Processes, Key Constraints, and Scale-Up Potential

Full text available at: https://www.annualreviews.org/doi/10.1146/annurev-chembioeng-093020-091447CO2 storage in saline aquifers offers a realistic means of achieving globally significant reductions in greenhouse gas emissions at the scale of billions of tonnes per year. We review insights into the processes involved using well-documented industrial-scale projects, supported by a range of laboratory analyses, field studies, and flow simulations. The main topics we address are (a) the significant physicochemical processes, (b) the factors limiting CO2 storage capacity, and (c) the requirements for global scale-up.Although CO2 capture and storage (CCS) technology can be considered mature and proven, it requires significant and rapid scale-up to meet the objectives of the Paris Climate Agreement. The projected growth in the number of CO2 injection wells required is significantly lower than the historic petroleum industry drill rates, indicating that decarbonization via CCS is a highly credible and affordable ambition for modern human society. Several technology developments are needed to reduce deployment costs and to stimulate widespread adoption of this technology, and these should focus on demonstration of long-term retention and safety of CO2 storage and development of smart ways of handling injection wells and pressure, cost-effective monitoring solutions, and deployment of CCS hubs with associated infrastructure.Bureau of Economic Geolog

Isotopic exchange on the diurnal scale between near-surface snow and lower atmospheric water vapor at Kohnen station, East Antarctica

Quantifying the magnitude of post-depositional processes affecting the isotopic composition of surface snow is essential for a more accurate interpretation of ice core data. To achieve this, high temporal resolution measurements of both lower atmospheric water vapor and surface snow iso- topic composition are required. This study presents contin- uous measurements of water vapor isotopes performed in East Antarctica (Kohnen station) from December 2013 to January 2014 using a laser spectrometer. Observations have been compared with the outputs of two atmospheric gen- eral circulation models (AGCMs) equipped with water va- por isotopes: ECHAM5-wiso and LMDZ5Aiso. During our monitoring period, the signals in the 2 m air temperature T , humidity mixing ratio q and both water vapor isotopes δD and δ18O are dominated by the presence of diurnal cycles. Both AGCMs simulate similar diurnal cycles with a mean amplitude 30 to 70 % lower than observed, possibly due to an incorrect simulation of the surface energy balance and the boundary layer dynamics. In parallel, snow surface samples were collected each hour over 35 h, with a sampling depth of 2–5 mm. A diurnal cycle in the isotopic composition of the snow surface is observed in phase with the water vapor, reaching a peak-to-peak amplitude of 3 ‰ for δD over 24 h (compared to 36 ‰ for δD in the water vapor). A simple box model treated as a closed system has been developed to study the exchange of water molecules between an air and a snow reservoir. In the vapor, the box model simulations show too much isotopic depletion compared to the observations. Mix- ing with other sources (advection, free troposphere) has to be included in order to fit the observations. At the snow surface, the simulated isotopic values are close to the observations with a snow reservoir of ∼ 5 mm depth (range of the snow sample depth). Our analysis suggests that fractionation oc- curs during sublimation and that vapor–snow exchanges can no longer be considered insignificant for the isotopic compo- sition of near-surface snow in polar regions

Climate dependent contrast in surface mass balance in East Antarctica over the past 216 ka

ABSTRACTDocumenting past changes in the East Antarctic surface mass balance is important to improve ice core chronologies and to constrain the ice-sheet contribution to global mean sea-level change. Here we reconstruct past changes in the ratio of surface mass balance (SMB ratio) between the EPICA Dome C (EDC) and Dome Fuji (DF) East Antarctica ice core sites, based on a precise volcanic synchronization of the two ice cores and on corrections for the vertical thinning of layers. During the past 216 000 a, this SMB ratio, denoted SMBEDC/SMBDF, varied between 0.7 and 1.1, being small during cold periods and large during warm periods. Our results therefore reveal larger amplitudes of changes in SMB at EDC compared with DF, consistent with previous results showing larger amplitudes of changes in water stable isotopes and estimated surface temperature at EDC compared with DF. Within the last glacial inception (Marine Isotope Stages, MIS-5c and MIS-5d), the SMB ratio deviates by up to 0.2 from what is expected based on differences in water stable isotope records. Moreover, the SMB ratio is constant throughout the late parts of the current and last interglacial periods, despite contrasting isotopic trends.This is the accepted manuscript. It is currently embargoed pending publication