Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of \u3cem\u3etrans\u3c/em\u3e-Pt(Pet\u3csub\u3e3\u3c/sub\u3e)\u3csub\u3e2\u3c/sub\u3e(SePh)\u3csub\u3e2\u3c/sub\u3e

The crystal structure of trans-[((bis)triethylphosphine)(bis(phenylselenato))platinum (II)] has been determined by single crystal X-ray diffraction. Crystallization occurs in the triclinic space group P-1 (No. 2) with a = 8.9964(2) Å, b = 11.5103(2) Å, c = 14.9335(3) Å; α = 85.8750(10)°, β = 72.5350(10)°, γ = 68.4450(10)°. Details of the structure and spectroscopic results are presented and discussed and comparisons are made with related square planar platinum (II) structures

\u3cem\u3eN\u3c/em\u3e-Methylbenzothiazole-2(3\u3cem\u3eH\u3c/em\u3e)-selone, C\u3csub\u3e8\u3c/sub\u3eH\u3csub\u3e7\u3c/sub\u3eNSSe

The crystal structure of N-methyl1,3-benzothiazole-2(3H)-selone, (mbts) has been studied to estimate the changes in the molecular geometry of the mbts ligand upon coordination. Hypervalent complexes of mbts with TeII and II have been studied by us previously. A significant elongation of the Se=C bond [from 1.817 (7) in mbts to 1.85-1.88 Å in the complexes] was found, but there were no significant changes in the other geometric parameters of the ligand. The only other bond-length decrease of note was for SeC-NMe [from 1.35 (1) in mbts to 1.32-1.34 Å in the complexes]. Thus, only the amino group takes part in electron redistribution upon coordination

Structural ambiguity of the Chinese version of the hospital anxiety and depression scale in patients with coronary heart disease

Background The Hospital Anxiety and Depression Scale (HADS) is a widely used screening tool designed as a case detector for clinically relevant anxiety and depression. Recent studies of the HADS in coronary heart disease (CHD) patients in European countries suggest it comprises three, rather than two, underlying sub-scale dimensions. The factor structure of the Chinese version of the HADS was evaluated in patients with CHD in mainland China. Methods Confirmatory factor analysis (CFA) was conducted on self-report HADS forms from 154 Chinese CHD patients. Results Little difference was observed in model fit between best performing three-factor and two-factor models. Conclusion The current observations are inconsistent with recent studies highlighting a dominant underlying tri-dimensional structure to the HADS in CHD patients. The Chinese version of the HADS may perform differently to European language versions of the instrument in patients with CHD

Modeling missing transverse energy in V+jets at CERN LHC

I discuss a method to model the instrumental response of the CMS and ATLAS detectors at high transverse missing energies to dominant standard model V+jets backgrounds, where V is a Z, gamma or W, using multi-jet QCD events. The method is developed for new physics searches in early data at the Large Hadron Collider (LHC) with minimal recourse to simulation.Comment: Replaced with the published versio

Information from leading neutrons at HERA

In principle, leading neutrons produced in photoproduction and deep-inelastic scattering at HERA have the potential to determine the pion structure function, the neutron absorptive cross section and the form of the pion flux. To explore this potential we compare theoretical predictions for the x_L and p_t spectra of leading neutrons, and the Q^2 dependence of the cross section, with the existing ZEUS data.Comment: 17 pages, 8 figure

Checking formalism for central exclusive production in the first LHC runs

We discuss how the early LHC data runs can provide crucial tests of the formalism used to predict the cross sections of central exclusive production.Comment: 7 pages, 6 figures; Based on a talk by A.D. Martin at the CERN - DESY Workshop "HERA and the LHC", 26 - 30 May 2008, CER

Lessons from LHC elastic and diffractive data

In the light of LHC data, we discuss the global description of all high energy elastic and diffractive data, using a one-pomeron model, but including multi-pomeron interactions. The LHC data indicate the need of a $k_t(s)$ behaviour, where $k_t$ is the gluon transverse momentum along the partonic ladder structure which describes the pomeron. We also discuss tensions in the data, as well as the $t$ dependence of the slope of $d\sigma_{el}/dt$ in the small $t$ domain.Comment: 5 pages, 3 figures, Proceedings of Diffraction 2014, Primosten, Croatia, Sept. 10-1

Diffraction at the LHC

We show that the diffractive pp (and p\bar{p}) data (on \sigma_tot, d\sigma_el/dt, proton dissociation into low-mass systems, \sigma^D(low M), and high-mass dissociation, d\sigma/d(\Delta\eta)) in a wide energy range from CERN-ISR to LHC energies, may be described in a two-channel eikonal model with only one `effective' pomeron. By allowing the pomeron coupling to the diffractive eigenstates to depend on the collider energy (as is expected theoretically) we are able to explain the low value of \sigma^D(low M) measured at the LHC. We calculate the survival probability, S^2, of a rapidity gap to survive `soft rescattering'. We emphasize that the values found for S^2 are particularly sensitive to the detailed structure of the diffractive eigenstates.Comment: 20 pages, 6 figures. Version to be published in EPJC. Typos corrected in eqs.(4) and (11