Mn valence instability in La2/3Ca1/3MnO3 thin films

A Mn valence instability on La2/3Ca1/3MnO3 thin films, grown on LaAlO3 (001)substrates is observed by x-ray absorption spectroscopy at the Mn L-edge and O K-edge. As-grown samples, in situ annealed at 800 C in oxygen, exhibit a Curie temperature well below that of the bulk material. Upon air exposure a reduction of the saturation magnetization, MS, of the films is detected. Simultaneously a Mn2+ spectral signature develops, in addition to the expected Mn3+ and Mn4+ contributions, which increases with time. The similarity of the spectral results obtained by total electron yield and fluorescence yield spectroscopy indicates that the location of the Mn valence anomalies is not confined to a narrow surface region of the film, but can extend throughout the whole thickness of the sample. High temperature annealing at 1000 C in air, immediately after growth, improves the magnetic and transport properties of such films towards the bulk values and the Mn2+ signature in the spectra does not appear. The Mn valence is then stable even to prolonged air exposure. We propose a mechanism for the Mn2+ ions formation and discuss the importance of these observations with respect to previous findings and production of thin films devices.Comment: Double space, 21 pages, 6 figure

Study on oxidation layer of size controlled Nickel nanoparticles

Documento submetido para revisão pelos pares. A publicar em Nanoscale Research Letters. ISSN 1556-276XResearch on morphology and structure of oxidation layer of Ni nanoparticles (NPs) is reported. Ni NPs were obtained by wet chemical solution method and their size controlled in the nickel nucleation step using a non-ionic surfactant. Particles were about 50nm in size and polycrystalline. Combining high-angle annular dark field (HAADF) and electron energy loss spectroscopy (EELS), the nickel oxide layer was identified as not continuous and with non homogenous thickness

Estudio comparativo de dos regímenes de preanestesia : acepromacina/petidina y medetominidina sobre la anestesia con ketamina o alfazalona/alfadolona en el gato

Medicin

Determination of the light exposure on the photodiodes of a new instrumented baffle for the Virgo input mode cleaner end-mirror

As part of the upgrade program of the advanced Virgo interferometer, the installation of new instrumented baffles surrounding the main test masses is foreseen. As a demonstrator, and to validate the technology, the existing baffle in the area of the input mode cleaner end-mirror will be first replaced by a baffle equipped with photodiodes. This paper presents detailed simulations of the light distribution on the input mode cleaner baffle. They served to validate the proposed layout of the sensors in the baffle, and determine the light exposure of the photodiodes under different scenarios of the interferometer operations, in order to define mitigation strategies for preserving the detector integrity

Simple analytical model for the magnetophoretic separation of superparamagnetic dispersions in a uniform magnetic gradient

Magnetophoresis-the motion of magnetic particles under applied magnetic gradient-is a process of great interest in novel applications of magnetic nanoparticles and colloids. In general, there are two main different types of magnetophoresis processes: cooperative magnetophoresis (a fast process enhanced by particle-particle interactions) and noncooperative magnetophoresis (driven by the motion of individual particles in magnetic fields). In the case of noncooperative magnetophoresis, we have obtained a simple analytical solution which allows the prediction of the magnetophoresis kinetics from particle characterization data (size and magnetization). Our comparison with new experimental results shows good quantitative agreement. In addition, we show the existence of a universal curve onto which all experimental results should collapse after proper rescaling. The range of applicability of the analytical solution is discussed in light of the predictions of a magnetic aggregation model

Evidence of strong antiferromagnetic coupling between localized and itinerant electrons in ferromagnetic Sr2FeMoO6

Magnetic dc susceptibility ($\chi$) and electron spin resonance (ESR) measurements in the paramagnetic regime, are presented. We found a Curie-Weiss (CW) behavior for $\chi$(T) with a ferromagnetic $\Theta = 446(5)$ K and $\mu_{eff} = 4.72(9) \mu_{B}/f.u.$, this being lower than that expected for either $Fe^{3+}(5.9\mu_{B})$ or $Fe^{2+}(4.9\mu_{B})$ ions. The ESR g-factor $g = 2.01(2)$, is associated with $Fe^{3+}$. We obtained an excellent description of the experiments in terms of two interacting sublattices: the localized $Fe^{3+}$ ($3d^{5}$) cores and the delocalized electrons. The coupled equations were solved in a mean-field approximation, assuming for the itinerant electrons a bare susceptibility independent on $T$. We obtained $\chi_{e}^{0} = 3.7$ $10^{-4}$ emu/mol. We show that the reduction of $\mu_{eff}$ for $Fe^{3+}$ arises from the strong antiferromagnetic (AFM) interaction between the two sublattices. At variance with classical ferrimagnets, we found that $\Theta$ is ferromagnetic. Within the same model, we show that the ESR spectrum can be described by Bloch-Hasegawa type equations. Bottleneck is evidenced by the absence of a $g$-shift. Surprisingly, as observed in CMR manganites, no narrowing effects of the ESR linewidth is detected in spite of the presence of the strong magnetic coupling. These results provide evidence that the magnetic order in $Sr_{2}FeMoO_{6}$ does not originates in superexchange interactions, but from a novel mechanism recently proposed for double perovskites

The best fit for the observed galaxy Counts-in-Cell distribution function

The Sloan Digital Sky Survey (SDSS) is the first dense redshift survey encompassing a volume large enough to find the best analytic probability density function that fits the galaxy Counts-in-Cells distribution $f_V(N)$, the frequency distribution of galaxy counts in a volume $V$. Different analytic functions have been previously proposed that can account for some of the observed features of the observed frequency counts, but fail to provide an overall good fit to this important statistical descriptor of the galaxy large-scale distribution. Our goal is to find the probability density function that better fits the observed Counts-in-Cells distribution $f_V(N)$. We have made a systematic study of this function applied to several samples drawn from the SDSS. We show the effective ways to deal with incompleteness of the sample (masked data) in the calculation of $f_V(N)$. We use LasDamas simulations to estimate the errors in the calculation. We test four different distribution functions to find the best fit: the Gravitational Quasi-Equilibrium distribution, the Negative Binomial Distribution, the Log Normal distribution and the Log Normal Distribution including a bias parameter. In the two latter cases, we apply a shot-noise correction to the distributions assuming the local Poisson model. We show that the best fit for the Counts-in-Cells distribution function is provided by the Negative Binomial distribution. In addition, at large scales the Log Normal distribution modified with the inclusion of the bias term also performs a satisfactory fit of the empirical values of $f_V(N)$. Our results demonstrate that the inclusion of a bias term in the Log Normal distribution is necessary to fit the observed galaxy Count-in-Cells distribution function.Comment: 12 pages, 16 figures. Accepted for publication in Astronomy & Astrophysic

Hydrothermal assisted synthesis of iron oxide-based magnetic silica spheres and their performance in magnetophoretic water purification

Porous Magnetic Silica (PMS) spheres of about 400 nm diameter were synthesised by one-pot process using the classical Stӧber method combined with hydrothermal treatment. Maghemite nanoparticles (γ-Fe2O3) were used as fillers and cetyltrimethylammonium bromide (CTAB) was used as templating agent. The application of the hydrothermal process (120 °C during 48 h) before the calcination leads to the formation of homogeneous and narrow size distribution PMS spheres. X-ray diffraction patterns (XRD), Infrared measurements (FTIR) and Transmission Electron microscopy (TEM) methods were used to determine the composition and morphology of the obtained PMS spheres. The results show a homogeneous distribution of the γ-Fe2O3 nanoparticles in the silica matrix with a “hollow-like” morphology. Magnetophoresis measurements at 60 T m−1 show a total separation time of the PMS spheres suspension of about 16 min. By using this synthesis method, the limitation of the formation of silica spheres without incorporation of magnetic nanoparticles is overcome. These achievements make this procedure interesting for industrial up scaling. The obtained PMS spheres were evaluated as adsorbents for Ni2+ in aqueous solution. Their adsorption capacity was compared with the adsorption capacity of magnetic silica spheres obtained without hydrothermal treatment before calcination process. PMS spheres show an increase of the adsorption capacity of about 15% of the initial dissolution of Ni2+ without the need to functionalize the silica surface.Fundação para a Ciência e a Tecnologia (FCT