Used food oils: physical-chemical indicators of quality degradation

Comunicação apresentada em 11th Baltic Conference on Food Science and Technology “Food science and technology in achanging world” FOODBALT 2017 Conference Proceedings. Jelgava, LLUUsed food oil (UFO), designated as frying oil, is a residue. Degradation by reuse or during storage, may occur by contacting, chemical, enzymatic and microbiological pathways, but oxidation is a major concern of the industry, as it affects sensory and nutritional quality of edible oils, with potentially toxic compounds formation. In Portugal, UFO's main destination still is the sewerage system, an environmental problem and waste of raw material, which can be re-qualified for non-food uses. However, quality control applied to UFO's, often results into expensive analysis inappropriate for small laboratories and catering industry. This project, developed with the Musketeers Group Portugal co-promotion (2012-2016), aimed to identify low-cost physicochemical parameters for further implementation as UFO's Quality Degradation Indicators (QDI) indicating defects quickly and accurately. UFO's analysis was tested on the use, for industrial frying, and by degradation induced in the laboratory (frying and heat stability tests) by applying following parameters: moisture, water activity (a(w)), total acidity, peroxide index, iodine index, colour (CIE, CIE Lab), UV absorbency, total polar compounds and microbiological indicators. Internal procedures (ESAS) were validated, redefining working ranges and test conditions, as standards procedures did not provide reliable results for the entire life cycle of oils, whose profile changes with time and reuse. Results demonstrate significant differences with quick response parameters as Total Acidity, Peroxide Index and CIE Lab colour, outlined as QDI's. Moisture, aw and CIE Lab colour proved to be inadequate for this purpose. Iodine Index and UV Absorbency are more complex and time-consuming and were profiled as reference methods.info:eu-repo/semantics/publishedVersio

Finding AGN in Deep X-ray Flux States with Swift

We report on our ongoing project of finding Active Galactic Nuclei (AGN) that go into deep X-ray flux states detected by Swift. Swift is performing an extensive study on the flux and spectral variability of AGN using Guest Investigator and team fill-in programs followed by triggering XMM_Newton for deeper follow-up observations. So far this program has been very successful and has led to a number of XMM-Newton follow up observations, including Mkn 335, PG 0844+349, and RX J2340.8-5329. Recent analysis of new Swift AGN observations reveal several AGN went into a very low X-ray flux state, particularly Narrow-Line Seyfert 1 galaxies. One of these is RX J2317-4422, which dropped by a factor of about 60 when compared to the ROSAT All-Sky Survey.Comment: 6 pages, 3 figures, Proceedings of the "10 Years of Swift" Meeting held in Rome in December 2014. Submitted to Po

Enhanced mitochondrial testicular antioxidant capacity in Goto-Kakizaki diabetic rats: role of coenzyme Q

Because diabetes mellitus is associated with impairment of testicular function, ultimately leading to reduced fertility, this study was conducted to evaluate the existence of a cause-effect relationship between increased oxidative stress in diabetes and reduced mitochondrial antioxidant capacity. The susceptibility to oxidative stress and antioxidant capacity (in terms of glutathione, coenzyme Q, and vitamin E content) of testis mitochondrial preparations isolated from Goto-Kakizaki (GK) non-insulin-dependent diabetic rats and from Wistar control rats, 1 yr of age, was evaluated. It was found that GK mitochondrial preparations showed a lower susceptibility to lipid peroxidation induced by ADP/Fe(2+), as evaluated by oxygen consumption and reactive oxygen species generation. The decreased susceptibility to oxidative stress in diabetic rats was associated with an increase in mitochondrial glutathione and coenzyme Q9 contents, whereas vitamin E was not changed. These results demonstrate a higher antioxidant capacity in diabetic GK rats. We suggest this is an adaptive response of testis mitochondria to the increased oxidative damage in diabetes mellitu

Evaluation of the Simulated Annealing and the Discrete Artificial Bee Colony in the Weight Tardiness Problem with Taguchi Experiments Parameterization

Meta-Heuristics (MH) are the most used optimization techniques to approach Complex Combinatorial Problems (COPs). Their ability to move beyond the local optimums make them an especially attractive choice to solve complex computational problems, such as most scheduling problems. However, the knowledge of what Meta-Heuristics perform better in certain problems is based on experiments. Classic MH, as the Simulated Annealing (SA) has been deeply studied, but newer MH, as the Discrete Artificial Bee Colony (DABC) still need to be examined in more detail. In this paper DABC has been compared with SA in 30 academic benchmark instances of the weighted tardiness problem (1 parallel to Sigma w(j)T(j)). Both MH parameters were fine-tuned with Taguchi Experiments. In the computational study DABC performed better and the subsequent statistical study demonstrated that DABC is more prone to find near-optimum solutions. On the other hand SA appeared to be more efficient.This work is supported by FEDER Funds through the "Programa Operacional Factores de Competitividade - COMPETE" program and by National Funds through FCT "Fundacao para a Ciencia e a Tecnologia" under the project: PEst-OE/EEI/UI0760/2014, and PEst2015-2020.info:eu-repo/semantics/publishedVersio

Immunization and Aging: a Learning Process in the Immune Network

The immune system can be thought as a complex network of different interacting elements. A cellular automaton, defined in shape-space, was recently shown to exhibit self-regulation and complex behavior and is, therefore, a good candidate to model the immune system. Using this model to simulate a real immune system we find good agreement with recent experiments on mice. The model exhibits the experimentally observed refractory behavior of the immune system under multiple antigen presentations as well as loss of its plasticity caused by aging.Comment: 4 latex pages, 3 postscript figures attached. To be published in Physical Review Letters (Tentatively scheduled for 5th Oct. issue

Study on the Impact of the NS in the Performance of Meta-Heuristics in the TSP

Meta-heuristics have been applied for a long time to the Travelling Salesman Problem (TSP) but information is still lacking in the determination of the parameters with the best performance. This paper examines the impact of the Simulated Annealing (SA) and Discrete Artificial Bee Colony (DABC) parameters in the TSP. One special consideration of this paper is how the Neighborhood Structure (NS) interact with the other parameters and impacts the performance of the meta-heuristics. NS performance has been the topic of much research, with NS proposed for the best-known problems, which seem to imply that the NS influences the performance of meta-heuristics, more that other parameters. Moreover, a comparative analysis of distinct meta-heuristics is carried out to demonstrate a non-proportional increase in the performance of the NS.This work is supported by FEDER Funds through the "Programa Operacional Factores de Competitividade - COMPETE" program and by National Funds through FCT "FundaqAo para a Ciencia e a Tecnologia" under the project: FCOMP-01-0124-FEDER-PEst-OE/EEl/U10760/2011, PEst-OE/EEI/UI0760/2014, and PEst2015-2020.info:eu-repo/semantics/publishedVersio

Low temperature matrix-isolation and solid state vibrational spectra of tetrazole

Infrared spectra of tetrazole (CN isolated in an argon matrix (T \10 K) and in the solid state (at room 4H2) temperature) were investigated. In the crystalline phase, tetrazole exists in its 1H-tautomeric form and new assignments of the vibrational spectra (both infrared and Raman) of this phase are presented. The infrared spectrum of the matrix-isolated monomeric form of tetrazole is now reported and assigned for the Ðrst time, showing essentially the expected signature of the 2H-tetrazole tautomer. From relative intensities of the infrared bands ascribable to the two tautomers, the amount of the 1H-tautomer in the argon matrix was estimated to be ca. 10% of the most stable tautomer. Assuming that gas-phase relative populations of the two tautomers could be efficiently trapped in the argon matrix during deposition, the energy di erence between 1H- and 2H-tetrazole (*E was then obtained. The experimental value, kJ mol~1, 1Hh2H) *E1Hh2H\6.95^1.50 now determined for the Ðrst time, compares fairly well with the theoretical predictions for the molecule in vacuum (e.g., the zero point vibrational energy corrected energy di erence obtained at the B3LYP/6È31G* level of theory is 9.96 kJ mol~1)

GRASS UTILIZATION IN GROWING FINISHING BÍSARO PIGS (85-107 KG). PERFORMANCE AND CARCASS COMPOSITION

The use of different quantities of vegetables, forages or fresh grass as fodder for growing-finishing pigs is an important factor of the northern Portugal traditional system. The increasing development of swine production in outdoor systems, extensive and organic production, turns to upcoming natural diets, in which grass performs a significant part. With regard to this, some investigation has been made concerning the use of fibre-rich feed ingredients in pig nutrition. Metabolic effects of its ingestion are analysed concerning different sights (economical, social, environmental and physiological ones). The aim of this work was to study the effects of grass utilization in the diets on performances of finishing Bísaro pigs. A total of 22 pigs (16 castrated males and 6 females) was housed outdoor and fed ad libitum (37 – 85 kg live weight) with a growing diet and then transferred to an indoor system (with free access to an outdoor area) for 49 days, according to 3 different treatments: 100% concentrate (C), 75% concentrate + ad libitum grass (CE75), 50% concentrate + ad libitum grass (CE50). The grass was supplied and its intake registered on a daily basis. Every 14 days, the pigs were weighted and their back fat (P2 in vivo) measured. After slaughter (average weight of 107 kg LW), yield and ½ left carcass characteristics were controlled. During the outdoor growing phase, the ADG was 513 g/day. During the indoor finishing phase, the increase grass intake was proportional to the reduction of concentrate in the diet. The ADG (g) and the fat deposition (P2 cm) were significantly different (P<0,05) in the 3 treatments (ADG: C=641, CE75=467, CE50=356 and: C=11,4, CE75=+9,5, CE50=+6,2). The empty body weight (kg) was also proportional to the intake of concentrate (C=116,2; CE75=107,7; CE50=102,2). Comparatively to the weight of the body parts, pigs that had higher intake of grass and lower of concentrate showed a higher % of shoulder (P<0,05; C=20,4, CE75=21,7, CE50=22,2) and the pH45min of CE carcasses was significantly higher (P<0,05). As a conclusion, concentrate substitution for grass showed a slower growing rate, thinner carcasses and a high technological quality. Neverthelles variability (CV %) of the productive parameters at the end of this study were higher in the treatments that included grass: live weight (C= 10,5%; C75=10,7%; C50=14,3%), finishing ADG (C=24%; C75=37%, C50=42%), and final fat (C=37%; C75=32%, C50=52%). These values suggest that the utilization of fibrous feeds in growing-finishing swine may be one of the possible explanations of the more heterogeneous products and carcasses found in the traditional or extensive systems, common users of fibrous feeds in the carcass finishing phase