Observations of Small Scale ISM Structure in Dense Atomic Gas

We present high resolution (R~170,000) Kitt Peak National Observatory Co'ude Feed telescope observations of the interstellar KI 7698 angstrom line towards 5 multiple star systems with saturated NaI components. We compare the KI absorption line profiles in each of the two (or three) lines of sight in these systems, and find significant differences between the sight-lines in 3 out of the 5 cases. We infer that the small scale structure traced by previous NaI observations is also present in at least some of the components with saturated NaI absorption lines, and thus the small scale structures traced by the neutral species are occurring at some level in clouds of all column densities. We discuss the implications of that conclusion and a potential explanation by density inhomogeneities

Non-linear Preheating with Scalar Metric Perturbations

We have studied preheating of field perturbations in a 3-dimensional lattice including the effect of scalar metric perturbations, in two generic models of inflation: chaotic inflation with a quartic potential, and standard hybrid inflation. We have prepared the initial state for the classical evolution of the system with vanishing vector and tensor metric perturbations, consistent with the constraint equations, the energy and momentum constraints. The non-linear evolution inevitably generates vector and tensor modes, and this reflects on how well the constraint equations are fulfilled during the evolution. The induced preheating of the scalar metric perturbations is not large enough to backreact onto the fields, but it could affect the evolution of vector and tensor modes. This is the case in hybrid inflation for some values of the coupling $g$ and the height of potential $V_0^{1/4}$. For example with $V_0^{1/4} \simeq 10^{15}$ GeV, preheating of scalar perturbations is such that their source term in the evolution equation of tensor and vector becomes comparable to that of the field anisotropic stress.Comment: 15 pages, 12 eps figure

An extension problem for the CR fractional Laplacian

We show that the conformally invariant fractional powers of the sub-Laplacian on the Heisenberg group are given in terms of the scattering operator for an extension problem to the Siegel upper halfspace. Remarkably, this extension problem is different from the one studied, among others, by Caffarelli and Silvestre.Comment: 33 pages. arXiv admin note: text overlap with arXiv:0709.1103 by other author

Low-Metallicity Gas Clouds in a Galaxy Proto-Cluster at Redshift 2.38

We present high resolution spectroscopy of a QSO whose sight-line passes through the halo of a pair of elliptical galaxies at redshift 2.38. This pair of galaxies probably lies at the center of a galaxy proto-cluster, and is embedded in a luminous extended Ly-alpha nebula. The QSO sight-line intersects two small gas clouds within this halo. These clouds have properties similar to those of high velocity clouds (HVCs) seen in the halo of the Milky Way. The gas is in a cool (< 2 x 10^4 K) and at least 20% neutral phase, with metallicities in the range -3.0 < [Fe/H] < -1.1 and neutral hydrogen column densities of ~10^19.5 /cm^2. The origin of these clouds is unclear. The presence of low metallicity gas within this possible proto-cluster implies either that the intra-cluster medium has not been enriched with metals at this redshift, or the clouds are embedded within a hot, ionized, metal-rich gas phase.Comment: Accepted to appear in ApJ Letter

Small-Scale Interstellar Na I Structure Toward M92

We have used integral field echelle spectroscopy with the DensePak fiber-optic array on the KPNO WIYN telescope to observe the central 27" x 43" of the globular cluster M92 in the Na I D wavelength region at a spatial resolution of 4". Two interstellar Na I absorption components are evident in the spectra at LSR velocities of 0 km/s (Cloud 1) and -19 km/s (Cloud 2). Substantial strength variations in both components are apparent down to scales limited by the fiber-to-fiber separations. The derived Na I column densities differ by a factor of 4 across the Cloud 1 absorption map and by a factor of 7 across the Cloud 2 map. Using distance upper limits of 400 and 800 pc for Cloud 1 and Cloud 2, respectively, the absorption maps indicate structure in the ISM down to scales of 1600 and 3200 AU. The fiber-to-fiber Na I column density differences toward M92 are comparable to those found in a similar study of the ISM toward the globular cluster M15. Overall, the structures in the interstellar components toward M92 have significantly lower column densities than those toward M15. We interpret these low column density structures as small-scale turbulent variations in the gas and compare them to the larger-scale, higher column density variations toward M15, which may be the hallmarks of actual H I structures.Comment: 9 pages, 2 figures, accepted for publication in ApJ Letter

Voltage-controlled electron tunnelling from a single self-assembled quantum dot embedded in a two-dimensional-electron-gas-based photovoltaic cell

We perform high-resolution photocurrent (PC) spectroscopy to investigate resonantly the neutral exciton ground-state (X0) in a single InAs/GaAs self-assembled quantum dot (QD) embedded in the intrinsic region of an n-i-Schottky photodiode based on a two-dimensional electron gas (2DEG), which was formed from a Si delta-doped GaAs layer. Using such a device, a single-QD PC spectrum of X0 is measured by sweeping the bias-dependent X0 transition energy through that of a fixed narrow-bandwidth laser via the quantum-confined Stark effect (QCSE). By repeating such a measurement for a series of laser energies, a precise relationship between the X0 transition energy and bias voltage is then obtained. Taking into account power broadening of the X0 absorption peak, this allows for high-resolution measurements of the X0 homogeneous linewidth and, hence, the electron tunnelling rate. The electron tunnelling rate is measured as a function of the vertical electric field and described accurately by a theoretical model, yielding information about the electron confinement energy and QD height. We demonstrate that our devices can operate as 2DEG-based QD photovoltaic cells and conclude by proposing two optical spintronic devices that are now feasible.Comment: 34 pages, 11 figure

Depolymerization Pathways for Branching Lignin Spirodienone Units Revealed with ab Initio Steered Molecular Dynamics

Lignocellulosic biomass is an abundant, rich source of aromatic compounds, but direct utilization of raw lignin has been hampered by both the high heterogeneity and variability of linking bonds in this biopolymer. Ab initio steered molecular dynamics (AISMD) has emerged both as a fruitful direct computational screening approach to identify products that occur through mechanical depolymerization (i.e., in sonication or ball-milling) and as a sampling approach. By varying the direction of force and sampling over 750 AISMD trajectories, we identify numerous possible pathways through which lignin depolymerization may occur in pyrolysis or through catalytic depolymerization as well. Here, we present eight unique major depolymerization pathways discovered via AISMD for the recently characterized spirodienone lignin branching linkage that may comprise around 10% weight of all lignin in some softwoods. We extract representative trajectories from AISMD and carry out reaction pathway analysis to identify energetically favorable pathways for lignin depolymerization. Importantly, we identify dynamical effects that could not be observed through more traditional calculations of bond dissociation energies. Such effects include thermodynamically favorable recovery of aromaticity in the dienone ring that leads to near-barrierless subsequent ether cleavage and hydrogen bonding effects that stabilize newly formed radicals. Some of the most stable spirodienone fragments that reside at most 1 eV above the reactant structure are formed with only 2 eV barriers for C-C bond cleavage, suggesting key targets for catalyst design to drive targeted depolymerization of lignin.National Science Foundation (U.S.) (Grant ECCS1449291)Massachusetts Institute of Technology (Research Support Corporation Reed Grant)Burroughs Wellcome Fund (Career Award at the Scientific Interface