88 research outputs found
Structure and magnetic properties of MnII[N(CN)2]2(pyrazine). An antiferromagnet with an interpenetrating 3-D network structure
Journal ArticleMn[N(CN)2]2(pyz) (pyz = pyrazine) orders antiferromagnetically at low temperature and possesses intralayer u-NCNCN and interlayer u-pyz ligands that form a pseudo-ReO3 interpenetrating network structure
Crystal structure and magnetic properties of [Fe{N(CN)2}2(MeOH)2] a 2-D layered network consisting of hydrogen-bonded 1-D chains
Journal ArticleA novel 2-D layered network structure [Fe{N(CN)2}2(MeOH)2] was synthesized and characterized by X-ray crystallography, vibrational, and magnetic susceptibility. The neutral 2-D stair-like framework consists of hydrogen-bonded infinite 1-D {Fe[N(CN)2]2} ribbons that pack in a staggered arrangement where nearest-neighboring chains are slipped a/2 relative to one another. Two methanol molecules are coordinated to the FeII center via the oxygen atoms in a trans configuration resulting in a compressed FeN4O2 octahedron. Hydrogen-bond interactions occur via N(2)...H(1)--O(1) where N(2) is the amide nitrogen atom of a nearby ribbon. The magnetic susceptibility was interpreted according to an S=2 expression which includes the Weiss constant and zero-field splitting giving g=2.04, 0=-2.0 K, and D=-1.7 K. Intrachain exchange interactions were determined from a fit to an S=2 antiferromagnetic chain model leading to g=2.04 and J/kB=0.23 K. Further interchain interaction via the hydrogen bond was determined by incorporation of a molecular-field correction term yielding J'/kB=-0.02 K indicating very weak antiferromagnetic coupling between chains
MnII(N3)2(pyrazine).A 2-D layered structure consisting of ferromagnetically coupled 1-D {Mn(U-1,1-N3)2}n chains
Journal ArticleMn(N3)2(pyz) (pyz = pyrazine) consists of ferromagnetically coupled linear chains of {Mn(N3)2}n comprised of u-1,1-azido bridges together with u-pyz ligands to afford 2-D planar layers
Interpenetrating three-dimensional rutile-like frameworks. Crystal structure and magnetic properties of MnII[C(CN)3]2
Journal ArticleThe interpenetrating double-density rutile-like structure and magnetic properties of MnII[C(CN)3]2 are determined
Measurement Of Magnetic Susceptibility In Pulsed Magnetic Fields Using A Proximity Detector Oscillator
We present a novel susceptometer with a particularly small spatial footprint and no moving parts. The susceptometer is suitable for use in systems with limited space where magnetic measurements may not have been previously possible, such as in pressure cells and rotators, as well as in extremely high pulsed fields. The susceptometer is based on the proximity detector oscillator, which has a broad dynamic resonant frequency range and has so far been used predominantly for transport measurements. We show that for insulating samples, the resonance frequency behavior as a function of field consists of a magnetoresistive and an inductive component, originating, respectively, from the sensor coil and the sample. The response of the coil is modeled, and upon subtraction of the magnetoresistive component the dynamic magnetic susceptibility and magnetization can be extracted. We successfully measure the magnetization of the organic molecular magnets Cu(H2O)(5)(VOF4)(H2O) and [Cu(HF2)(pyz)(2)]BF4 in pulsed magnetic fields and by comparing the results to that from a traditional extraction susceptometer confirm that the new system can be used to measure and observe magnetic susceptibilities and phase transitions. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3653395
Magnetic Order In The Quasi-One-Dimensional Spin-1/2 Molecular Chain Compound Copper Pyrazine Dinitrate
We present evidence of magnetic order in the quasi-one-dimensional spin-1/2 molecular chain compound, copper pyrazine dinitrate Cu(C4H4N2)(NO3)(2). Zero field muon-spin relaxation measurements made at dilution refrigerator temperatures show oscillations in the measured asymmetry characteristic of a quasistatic magnetic field at the muon sites. Our measurements provide convincing evidence for long-range magnetic order below a temperature T-N=107(1) mK. This leads to an estimate of the interchain coupling constant of vertical bar J\u27vertical bar/k(B)=0.046 K and to a ratio of vertical bar J\u27/J vertical bar=4.4x10(-3)
Field-Induced Xy And Ising Ground States In A Quasi-Two-Dimensional S=1/2 Heisenberg Antiferromagnet
High field specific heat up to 35 T, C-p, and magnetic susceptibility, chi, measurements were performed on the quasi-two-dimensional (2D) Heisenberg antiferromagnet [Cu(pyz)(2)(pyO)(2)](PF6)(2). While no C-p anomaly is observed down to 0.5 K in zero magnetic field, the application of field parallel to the crystallographic ab-plane induces a lambda-like anomaly in C-p, suggesting Ising-type magnetic order. On the other hand when the field is parallel to the c-axis, C-p and chi show evidence of XY-type antiferromagnetism. This dependence upon the field orientation occurs because the extreme two-dimensionality allows the intrinsic (zero field) spin anisotropy to dominate the interlayer coupling, which has hitherto masked such effects in other materials
Muon-Fluorine Entangled States In Molecular Magnets
The information accessible from a muon-spin relaxation experiment can be limited due to a lack of knowledge of the precise muon stopping site. We demonstrate here the possibility of localizing a spin polarized muon in a known stopping state in a molecular material containing fluorine. The muon-spin precession that results from the entangled nature of the muon spin and surrounding nuclear spins is sensitive to the nature of the stopping site. We use this property to identify three classes of sites that occur in molecular magnets and describe the extent to which the muon distorts its surroundings
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