106 research outputs found
Instability of metal-insulator transition against thermal cycling in phase separated Cr-doped manganites
We show that metal-insulator transition in Pr0.5Ca0.5Mn1-xCrxO3 (x =
0.015-0.025) is unstable against thermal cycling. Insulator-metal transition
shifts down and low temperature resistivity increases each time when the sample
is cycled between a starting temperature TS and a final temperature TF. The
effect is dramatic lower is x. Insulator-metal transition in x = 0.015 can be
completely destroyed by thermal cycling in absence of magnetic field as well as
under H = 2 T. Magnetic measurements suggest that ferromagnetic phase fraction
decreases with thermal cycling. We suggest that increase in strains in
ferromagnetic- charge ordered interface could be a possible origin of the
observed effect.Comment: 14 pages, 5 figures and 2 tables (revised
Re-entrant spin glass and magnetoresistance in Co_{0.2}Zn_{0.8}Fe_{1.6}Ti_{0.4}O_4 spinel oxide
We have investigated the static and dynamic response of magnetic clusters in
Co_{0.2}Zn_{0.8}Fe_{1.6}Ti_{0.4}O_4 spinel oxide, where a sequence of magnetic
phase transitions, i.e., paramagnetic (PM) to ferromagnetic at T_{C}
270K and ferromagnetic to canted spin glass state at T_f\leq$ 125K is
observed
A-site Randomness Effect on Structural and Physical Properties of Ba-based Perovskite Manganites
The discovery of novel structural and physical properties in the -site
ordered manganite BaMnO ( = Y and rare earth elements) has
demanded new comprehension about perovskite manganese oxides. In the present
study, the -site disordered form, BaMnO, has been
investigated and compared with both BaMnO and
MnO (: Sr, Ca) in the structures and electromagnetic
properties. BaMnO has a primitive cubic perovskite cell
in the structure and magnetic glassy states are dominant as its ground state,
in contrast to the ordinary disordered MnO (: Sr, Ca).
In Pr-compounds with various degrees of Pr/Ba randomness at the -sites, the
-site disorder gradually suppresses both ferromagnetic and A-type
antiferromagnetic transitions and finally leads to a magnetic glassy state in
PrBaMnO. A peculiar behavior, multi-step magnetization
and resistivity change, has been observed in PrBaMnO.
These properties could be closely related to any spatial heterogeneity caused
by the random distribution of Ba and with much different
ionic radius.Comment: 9 pages, to be published in J. Phys. Soc. Jpn. 73 Aug. (2004
The enhancement of phase separation aspect in electron doped manganite Ca0.8Sm0.16Nd0.04MnO3
The complex lanthanide doping of electron manganites results in enhancement
of various phase separation effects in physical properties of these compounds.
Selecting Ca0.8Sm0.16Nd0.04MnO3 as a model case we show that the first order
structural phase transition from paramagnetic semi-metallic phase into
anti-ferromagnetic semi-metallic phase at TS ~ 158 +- 4 K is marked by an
abrupt decrease in magnetization, a step like anomaly DL/L = 10-4 in thermal
expansion and large latent heat DQ = 610 J/mol. In a certain temperature range
below TS, the high field magnetization exhibits hysteretic metamagnetic
behavior due to field-induced first order transformation. ac-susceptibility,
magnetization and resistivity data suggest rather a non-uniform state in
Ca0.8Sm0.16Nd0.04MnO3 at low temperatures. The metal - insulator transition
occurs at TMI ~112 +- 3 K, accompanied by a step-like increase in
magnetization. These features could be ascribed to "sponging" of electrons from
neighboring anti-ferromagnetic matrix by clusters undergoing the ferromagnetic
ordering.Comment: submitted to J.Phys. Cond. Matte
Nanosized Sodium-Doped Lanthanum Manganites: Role of the Synthetic Route on their Physical Properties
In this paper we present the results of the synthesis and characterisation of
nanocrystalline La1-xNaxMnO3+delta samples. Two synthetic routes were employed:
polyacrylamide-based sol-gel and propellant synthesis. Pure, single phase
materials were obtained with grain size around 35 nm for the sol-gel samples
and around 55 nm for the propellant ones, which moreover present a more broaden
grain size distribution. For both series a superparamagnetic behaviour was
evidenced by means of magnetisation and EPR measurements with peculiar features
ascribable to the different grain sizes and morphology. Preliminary
magnetoresistivity measurements show enhanced low-field (< 1 T)
magnetoresistance values which suggest an interesting applicative use of these
manganites.Comment: 31 Pages 10 Figures to appear in Chem. Mate
Competition of charge, orbital, and ferromagnetic correlations in layered manganites
The competition of charge, orbital, and ferromagnetic interactions in layered
manganites is investigated by magneto-Raman scattering spectroscopy. We find
that the colossal magnetoresistance effect in the layered compounds results
from the interplay of the orbital and ferromagnetic double-exchange
correlations. Inelastic scattering by charge-order fluctuations dominates the
quasiparticle dynamics in the ferromagnetic-metal state. The scattering is
suppressed at low frequencies, consistent with the opening of a charge-density
wave pseudogap.Comment: 10 pages, 4 figure
High Temperature Thermopower in La_{2/3}Ca_{1/3}MnO_3 Films: Evidence for Polaronic Transport
Thermoelectric power, electrical resistivity and magnetization experiments,
performed in the paramagnetic phase of La_{2/3}Ca_{1/3}MnO_3, provide evidence
for polaron-dominated conduction in CMR materials. At high temperatures, a
large, nearly field-independent difference between the activation energies for
resistivity (rho) and thermopower (S), a characteristic of Holstein Polarons,
is observed, and ln(rho) ceases to scale with the magnetization. On approaching
T_c, both energies become field-dependent, indicating that the polarons are
magnetically polarized. Below T_c, the thermopower follows a law S(H) prop.
1/rho (H) as in non saturated ferromagnetic metals.Comment: 10 pages, 5 .gif figures. Phys. Rev B (in press
Magnetic Phases of Electron-Doped Manganites
We study the anisotropic magnetic structures exhibited by electron-doped
manganites using a model which incorporates the double-exchange between orbital
ly degenerate electrons and the super-exchange between
electrons with realistic values of the Hund's coupling(), the
super-exchange coupling(), and the bandwidth(). We look at the
relative stabilities of the G, C and A type antiferromagnetic ph ases. In
particular we find that the G-phase is stable for low electron doping as seen
in experiments. We find good agreement with the experimentally observed
magnetic phase diagrams of electron-doped manganites
() such as NdSrMnO, PrSrMnO,
and SmCaMnO. We can also explain the experimentally
observed orbital structures of the C a nd A phases.
We also extend our calculation for electron-doped bilayer manganites of the
form RAMnO and predict that the C-phase will be
absent in t hese systems due to their reduced dimensionality.Comment: 7 .ps files included. To appear in Phys. Rev. B (Feb 2001
Field-Induced Magnetization Steps in Intermetallic Compounds and Manganese Oxides: The Martensitic Scenario
Field-induced magnetization jumps with similar characteristics are observed
at low temperature for the intermetallic germanide Gd5Ge4and the mixed-valent
manganite Pr0.6Ca0.4Mn0.96Ga0.04O3. We report that the field location -and even
the existence- of these jumps depends critically on the magnetic field sweep
rate used to record the data. It is proposed that, for both compounds, the
martensitic character of their antiferromagnetic-to-ferromagnetic transitions
is at the origin of the magnetization steps.Comment: 4 pages,4 figure
Inhomogeneous Magnetism in La-doped CaMnO3. (II) Mesoscopic Phase Separation due to Lattice-coupled FM Interactions
A detailed investigation of mesoscopic magnetic and crystallographic phase
separation in Ca(1-x)La(x)MnO3, 0.00<=x<=0.20, is reported. Neutron powder
diffraction and DC-magnetization techniques have been used to isolate the
different roles played by electrons doped into the eg level as a function of
their concentration x. The presence of multiple low-temperature magnetic and
crystallographic phases within individual polycrystalline samples is argued to
be an intrinsic feature of the system that follows from the shifting balance
between competing FM and AFM interactions as a function of temperature. FM
double-exchange interactions associated with doped eg electrons are favored
over competing AFM interactions at higher temperatures, and couple more
strongly with the lattice via orbital polarization. These FM interactions
thereby play a privileged role, even at low eg electron concentrations, by
virtue of structural modifications induced above the AFM transition
temperatures.Comment: 8 pages, 7 figure
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