Theory of photoinduced charge transfer in weakly coupled donor-acceptor conjugated polymers: application to an MEH-PPV:CN-PPV pair

In a pair of coupled donor-acceptor conjugated polymer chains, it is possible for an exciton photoexcited on either polymer to decay into a hole in the donor polymer's valence band and an electron in the conduction band of the acceptor polymer. We calculate the corresponding exciton decay rate and its dependence on inter-polymer distance. For a pair of derivatives of poly(phenylene vinylene), PPV, specifically poly[2-methoxy, 5-(2$^\prime$-ethyl-hexyloxy)-1, 4 PPV], MEH-PPV, and poly(2,5-hexyloxy $p$-phenylene cyanovinylene), CN-PPV, at a separation of 6 \AA the characteristic decay time is 2.2 ps, whereas at 4 \AA it is $\sim 50$ fs.Comment: 9 pages, RevTeX, 4 PS files, to be published in a special issue of Chem. Phy

Measurements of the ion concentrations and conductivity over the Arabian Sea during the ARMEX

Measurements of the small-, intermediate-, and large-ion concentrations and the atmospheric electric conductivity of both polarities have been made over the Arabian Sea on four cruises of ORV Sagarkanya during the Arabian Sea Monsoon Experiment (ARMEX)during the monsoon and pre-monsoon seasons of 2002 and 2003. Seasonally averaged values of the total as well as polar conductivity are much higher during the monsoon than pre-monsoon season. Surprisingly, however, the concentration of small ions are less and those of large and intermediate ions are more during the monsoon than pre-monsoon season. The diurnal variations observed during the pre-monsoon season show that the nighttime small ion concentrations are about an order of magnitude higher than their daytime values. On the contrary, the daytime concentrations of the intermediate and large ions are much higher than those of their nighttime values. No such diurnal variations in ion concentrations are observed in monsoon season. Also examined are the variations in ion concentrations of different categories with distance from the coastline in different seasons and the ion-concentration changes associated with the precipitation of various types that occurred over ORV Sagarkanya. It is sufficient to invoke the ion-aerosol attachment process to explain our pre-monsoon observations. However, the generation of highly charged large ions by the bubble-breaking process caused by the wave breaking due to strong southwesterly surface winds ten to twenty meter per second over the Arabian Sea is postulated to explain the monsoon season observations.Comment: 35 pages, 8 figure

Identifying Types of Staying Facilities from Traffic Behavior Log Data

AbstractTraffic behavior surveys by hand require both a lot of money and human resources. Recently, traffic behavior surveys using information technology have been carried out. In this study, we propose a method to extract staying points from GPS-based positional data and identify the types of staying facilities by using Google Places API, a facility ontology, the regularity which is analyzed from trip chains about traffic behavior. This method could identify 68.5% types of staying facilities correctly in the evaluation using GPS location data from the Traffic Behavior Survey in Nagasaki

Quantum tunneling in ^{277}112 and its alpha-decay chain

The $\alpha$-decay half lives of nuclei in the decay from element $^{277}112$ are calculated in a WKB framework using DDM3Y interaction and experimental Q-values. Theoretical estimation of half lives in the same quantum tunneling model, using Q-values from the mass formula of Muntian-Hofmann-Patyk-Sobiczewski, are also presented. Calculated results furnish corroborating evidence for the experimental findings at RIKEN and GSI. Certain discrepancies indicate necessity of a better mass formula. Further experimental data with higher statistics would also be useful.Comment: 10 page

B∗B∗ρB^{\ast}B^{\ast}\rho vertex from QCD sum rules

The form factors and the coupling constants in the $B^{\ast}B^{\ast}\rho$ vertex are evaluated in the framework of three-point QCD sum rules. The correlation functions responsible for the form factors are evaluated considering contributions of both $B^{\ast}$ and $\rho$ mesons as off-shell states. The obtained numerical results for the coupling constants are in agreement with light-cone QCD sum rules calculations.Comment: 18 pages, 11 figures, to appear on Phys. Lett.

Cost-effectiveness Analysis of CO2 Reduction in the Automobile Sector

Various problems relating to energy and the environment clearly exist, such as global warming and a steep rise in the price fossil fuels, and resources. These problems should be addressed in the medium term or long run. As for the abatement of greenhouse gas emission, active discussions have been held on the stage of world politics to achieve the long-term goal. Although various approaches have been proposed by several research institutions and countries, sufficient studies have not yet been conducted on the roles of individual countries and sectors. Specifically, in the automotive transportation sector wherein oil demand and CO2 emissions are estimated to rise in the future with the marked progress of motorization in developing countries, it is increasingly important to study these subjects. We focused on the automotive transportation sector and studied the CO2 abatement potential and its cost performance in this sector. This article reports the results of the study.energy and the environment, Climate change, automotive transportation

Effects of Propofol on Left Ventricular Mechanoenergetics in the Excised Cross-circulated Canine Heart

Although propofol is commonly used for general anesthesia, its direct effects on left ventricular (LV) contractility and energetics remain unknown. Accordingly, we studied the effects of intracoronary propofol on excised cross-circulated canine hearts using the framework of the Emax (a contractility index)-PVA (systolic pressure-volume area, a measure of total mechanical energy)-Vo2 (myocardial oxygen consumption per beat) relationship. We obtained 1) the Vo2-PVA relationship of isovolumic contractions with varied LV volumes at a constant Emax, 2) the Vo2-PVA relationship with varied LV volumes at a constant intracoronary concentration of propofol, and 3) the Vo2-PVA relationship under increased intracoronary concentrations of either propofol or CaCl2 at a constant LV volume to assess the cardiac mechanoenergetic effects of propofol. We found that propofol decreased Emax dose-dependently. The slope of the linear Vo2-PVA relationship (oxygen cost of PVA) remained unchanged by propofol. The PVA-independent Vo2-Emax relationship (oxygen cost of Emax) was the same for propofol and Ca2＋. In conclusion, propofol showed a direct negative inotropic effect on LV. At its clinical concentrations, decreases in contractility by propofol were relatively small. Propofol shows mechanoenergetic effects on the LV that are similar to those of Ca2＋ blockers or ß-antagonists—i.e., it exerts negative inotropic effects without changing the oxygen costs of Emax and PVA

Inter-Intra Molecular Dynamics as an Iterated Function System

The dynamics of units (molecules) with slowly relaxing internal states is studied as an iterated function system (IFS) for the situation common in e.g. biological systems where these units are subjected to frequent collisional interactions. It is found that an increase in the collision frequency leads to successive discrete states that can be analyzed as partial steps to form a Cantor set. By considering the interactions among the units, a self-consistent IFS is derived, which leads to the formation and stabilization of multiple such discrete states. The relevance of the results to dynamical multiple states in biomolecules in crowded conditions is discussed.Comment: 7 pages, 7 figures. submitted to Europhysics Letter

Future of superheavy element research: Which nuclei could be synthesized within the next few years?

Low values of the fusion cross sections and very short half-lives of nuclei with Z$>$120 put obstacles in synthesis of new elements. Different nuclear reactions (fusion of stable and radioactive nuclei, multi-nucleon transfers and neutron capture), which could be used for the production of new isotopes of superheavy (SH) elements, are discussed in the paper. The gap of unknown SH nuclei, located between the isotopes which were produced earlier in the cold and hot fusion reactions, can be filled in fusion reactions of $^{48}$Ca with available lighter isotopes of Pu, Am, and Cm. Cross sections for the production of these nuclei are predicted to be rather large, and the corresponding experiments can be easily performed at existing facilities. For the first time, a narrow pathway is found to the middle of the island of stability owing to possible $\beta^+$-decay of SH isotopes which can be formed in ordinary fusion reactions of stable nuclei. Multi-nucleon transfer processes at near barrier collisions of heavy (and very heavy, U-like) ions are shown to be quite realistic reaction mechanism allowing us to produce new neutron enriched heavy nuclei located in the unexplored upper part of the nuclear map. Neutron capture reactions can be also used for the production of the long-living neutron rich SH nuclei. Strong neutron fluxes might be provided by pulsed nuclear reactors and by nuclear explosions in laboratory conditions and by supernova explosions in nature. All these possibilities are discussed in the paper.Comment: An Invited Plenary Talk given by Valeriy I. Zagrebaev at the 11th International Conference on Nucleus-Nucleus Collisions (NN2012), San Antonio, Texas, USA, May 27-June 1, 2012. To appear in the NN2012 Proceedings in Journal of Physics: Conference Series (JPCS