UVES radial velocity accuracy from asteroid observations. Implications for the fine structure constant variability

High resolution observations of the asteroids Iris and Juno have been performed by means of the UVES spectrograph at the ESO VLT to obtain the effective accurac y of the spectrograph's radial velocity. The knowledge of this quantity has impo rtant bearings on studies searching for a variability of the fine structure cons tant carried on with this instrument. Asteroids provide a precise radial velocit y reference at the level of 1 m/s which allows instrumental calibration and the recognition of small instrumental drifts and calibration systematics. In particu lar, radial velocity drifts due to non uniform slit illumination and slit optica l misalignment in the two UVES spectrograph arms can be investigated. The positi on of the solar spectrum reflected by the asteroids are compared with the solar wavelength positions or with that of asteroid observations at other epochs or wi th the twilight to asses UVES instrumental accuracy . Radial velocities offsets in the range 10--50 m/s are generally observed likely due to a non uniform slit illumination. However, no radial velocity patterns with wavelength are detected and the two UVES arms provide consistent radial velocities. These results suggest that the detected alpha variability by Levshakov et al. (2007) deduced from a drift of -180 (+/- 85) m/s at z =1.84, between two sets of FeII lines falling in the two UVES arms may be real or induced by other kinds of systematics than those investigated here. The proposed technique allows real time quality check of the spectrograph and should be followed for very accurate measurements.Comment: Accepted A&

Multi-sensor analysis of extreme events in North-Eastern Italy

International audienceThe North-eastern part of Italy is known to be one of the most rainy regions in Europe. In this paper three extreme events are analysed, using a multi-sensor observing system including a weather radar and a dense telemetric network of surface stations, recording precipitation, wind, temperature and relative humidity. The cases examined comprise two long lasting rainfall events impacting two distinct areas, and a vigorous hail-producing thunderstorm event over the plains. In all cases, inter-comparison between remotely sensed and surface observations, including estimates and measures of precipitation and wind, helps to better understand the behaviour of the atmosphere, thus supporting operational fore- and now-casting. In the case of widespread precipitation, a relation is suggested between the wind speed and direction at medium/low levels with the location of the maximum precipitation relative to the mountains. This reflects the dynamical interaction between the mountain barrier and the atmospheric flux impinging upon it. This flux can be estimated by the automatic weather station of Mt. Cesen, a focal point for a now-casting of the rain in the Veneto Region. Analysis of strong thunderstorm activity makes extensive use of radar data. In the examined case the interaction of a sea breeze-like circulation with a mesoscale trough gave rise to a distinct convergence line that triggered a severe and long-lived hail-producing multi-cell thunderstorm. The hail was successfully detected by the radar's hail detection algorithm

The management of atrophies classified as V class according to Cawood & Howell by piezo-electric surgery

Introducción: Los casos analizados presentaban atrofias severas (V clase según Cawood y Howell) (1), que se caracterizan por presentar una densidad de la cresta transversal inferior a 4 mm y vertical inferior a 6 mm; ello hace pensar en la posibilidad de una rehabilitación implanto-soportada. Objetivo: Evaluación de la rehabilitación de pacientes afectados por severa atrofia del maxilar superior clase V según Cawood y Howell) (1) rehabilitados con elevación del seno maxilar e injerto de hueso autólogo. Materiales y métodos: Estudio longitudinal a partir de una muestra de 32 pacientes, con atrofia maxilar severa y edentulismo parcial o total. En todos los pacientes se ha colocado un injerto con técnica de reconstrucción onlay mono o bicortical y se ha adoptado la cirugía piezoeléctrica para realizar el elevación del seno, el cual podía ser mono o bilateral, de hueso autólogo procedente de la cresta ilíaca anterior. Seguimiento realizado durante 2 años. Resultados: A los dos años del control final, el 94,05% de todos los implantes colocados tras la intervención de elevación se presentan osteointegrados y cargados protésicamente. La cresta ilíaca anterior resulta ser la zona idónea para la extracción medular, necesaria para la elevación del seno. Las posibilidades de supervivencia del implante son realmente elevadas si se espera el tiempo clínico necesario para la recuperación y la integración del injerto. El éxito de todas las intervenciones de elevación del seno maxilar se debe a la adopción de la cirugía piezoeléctrica, que permite efectuar la incisión de entrada y realizar el desprendimiento de los tejidos con un traumatismo mínimo para la membrana de Schneider. La integridad de la membrana y la utilización de bone-chips de origen autólogo no ha hecho necesario recurrir a la utilización de membranas reabsorbibles, simplificando así el procedimiento quirúrgico. La utilización de la cresta ilíaca anterior como zona donante, permite disponer de abundante tejido óseo cortical, necesario para colocar los onlay y para reconstruir el defecto óseo. Introduction: Valutation of rehabilitated patients by sinus lift in upper jaw and by autologous bone graft from iliac crest. Materials and methods: Rehabilitation of 32 patients with severe atrophies of upper jaw and partial or total edentulism by positioning of mono- or bicortical onlay with piezosurgery to obtain a sinus lift mono- or bilateral by autologous bone grafts from anterior iliac crest. Results: 94.05% of successes after a two years follow-up. Conclusions: Respecting of timing surgery, a correct use of the piezosurgery technique and of the autologous bone graft from anterior iliac crest let a successful implantological rehabilitation. Moreover the iliac crest is a very good donor site of bone tissue for the management of severe atrophies in the upper jaw. An accidental laceration of Schneider's membrane was observed in filling phase in the 5.26% of cases

A Frequency Comb calibrated Solar Atlas

The solar spectrum is a primary reference for the study of physical processes in stars and their variation during activity cycles. In Nov 2010 an experiment with a prototype of a Laser Frequency Comb (LFC) calibration system was performed with the HARPS spectrograph of the 3.6m ESO telescope at La Silla during which high signal-to-noise spectra of the Moon were obtained. We exploit those Echelle spectra to study the optical integrated solar spectrum . The DAOSPEC program is used to measure solar line positions through gaussian fitting in an automatic way. We first apply the LFC solar spectrum to characterize the CCDs of the HARPS spectrograph. The comparison of the LFC and Th-Ar calibrated spectra reveals S-type distortions on each order along the whole spectral range with an amplitude of +/-40 m/s. This confirms the pattern found by Wilken et al. (2010) on a single order and extends the detection of the distortions to the whole analyzed region revealing that the precise shape varies with wavelength. A new data reduction is implemented to deal with CCD pixel inequalities to obtain a wavelength corrected solar spectrum. By using this spectrum we provide a new LFC calibrated solar atlas with 400 line positions in the range of 476-530, and 175 lines in the 534-585 nm range. The new LFC atlas improves the accuracy of individual lines by a significant factor reaching a mean value of about 10 m/s. The LFC--based solar line wavelengths are essentially free of major instrumental effects and provide a reference for absolute solar line positions. We suggest that future LFC observations could be used to trace small radial velocity changes of the whole solar photospheric spectrum in connection with the solar cycle and for direct comparison with the predicted line positions of 3D radiative hydrodynamical models of the solar photosphere.Comment: Accept on the 15th of October 2013. 9 pages, 10 figures. ON-lINE data A&A 201

Correction: Propane to olefins tandem catalysis: a selective route towards light olefins production

Correction for ‘Propane to olefins tandem catalysis: a selective route towards light olefins production’ by Matteo Monai et al., Chem. Soc. Rev., 2021, 50, 11503–11529, https://doi.org/10.1039/D1CS00357G

SVILUPPO E RISULTATI DI UNA METODICA COMPUTER ASSISTITA PER L’ANALISI APPROFONDITA DI EVENTI INFORTUNISTICI LAVORO CORRELATI

In Italia si deve tutt’ora registrare un elevato numero di eventi mortali lavoro correlati, per la stragrande maggioranza in contesti non ascrivibili a scenari di incidente rilevante, e raramente associabili a guasto di impianti ed attrezzature correttamente scelti, usati e mantenuti. Un approccio efficace di prevenzione non può che fare riferimento all’analisi dei dati storici, ad integrazione della quale occorre peraltro disporre di una metodica di analisi della catena di eventi casuali dell’incidente formalizzata e priva di deviazioni valutative soggettive. Il modello originale di cui si riferisce si fonda su casi caratterizzati da informazioni approfondite acquisite in ambito di accertamenti tecnici a fini di giustizia. Esso si propone come valido riferimento nelle valutazioni sino alle cause prime dell’evento, lungo tutta la catena incidentale, e consente la revisione critica della valutazione e gestione proattiva dei rischi

Climate and atmospheric models of rocky planets: habitability and observational properties

The quest for atmospheric spectral signatures that may witness biological activity in exoplanets is focused on rocky planets. The best targets for future, challenging spectroscopic observations will be selected among potentially habitable planets. Surface habitability can be quantified and explored with climate and atmospheric models according to temperature-based criteria. The conceptual, modellistic, technological and interpretative complexity of the problem requires to develop flexible climate and atmospheric models suited for a comprehensive exploration of observationally unconstrained parameters, and to simulate and interpret definitely non-terrestrial conditions. We present a summary and preliminary results on the work we are performing on multi-parametric explorations of the habitability and observational properties of rocky planets.Comment: to appear on MemSAIt, vol 94. Proceedings of the Hack100 Conference: Past, Present and Future of Astrophysical Spectroscopy, 6-10 June 2022, Trieste, Ital

The Role of Water in Carbon Dioxide Adsorption in Porphyrinic Metal-Organic Frameworks

Capturing and converting CO2 through artificial photosynthesis using photoactive, porous materials is a promising approach for addressing increasing CO2 concentrations. Porphyrinic Zr-based metal-organic frameworks (MOFs) are of particular interest as they incorporate a photosensitizer in the porous structure. Herein, the initial step of the artificial photosynthesis is studied: CO2 sorption and activation in the presence of water. A combined vibrational and visible spectroscopic approach was used to monitor the adsorption of CO2 into PCN-222 and PCN-223 MOFs, and the photophysical changes of the porphyrinic linker as a function of water concentration. A shift in CO2 sorption site and bending of the porphyrin macrocycle in response to humidity was observed, and CO2/H2O competition experiments revealed that the exchange of CO2 with H2O is pore-size dependent. Therefore, humidity and pore-size can be used to tune CO2 sorption, CO2 capacity, and light harvesting in porphyrinic MOFs, which are key factors for CO2 photoreduction

In Situ X-ray Raman Scattering Spectroscopy of the Formation of Cobalt Carbides in a Co/TiO2 Fischer–Tropsch Synthesis Catalyst

We present in situ experiments to study the possible formation of cobalt carbides during Fischer–Tropsch synthesis (FTS) in a Co/TiO2 catalyst at relevant conditions of pressure and temperature. The experiments were performed by a combination of X-ray Raman scattering (XRS) spectroscopy and X-ray diffraction (XRD). Two different experiments were performed: (1) a Fischer–Tropsch Synthesis (FTS) reaction of an ∼14 wt % Co/TiO2 catalyst at 523 K and 5 bar under H2 lean conditions (i.e., a H2:CO ratio of 0.5) and (2) carburization of pure cobalt (as reference experiment). In both experiments, the Co L3-edge XRS spectra reveal a change in the oxidation state of the cobalt nanoparticles, which we assign to the formation of cobalt carbide (Co2C). The C K edge XRS spectra were used to quantify the formation of different carbon species in both experiments.Peer reviewe