Gaussian to Exponential Crossover in the Attenuation of Polarization Echoes in NMR

An ingenious pulse sequence devised by S. Zhang, B. H. Meier, and R. R. Ernst (Phys. Rev. Lett. {\bf 69}, 2149 (1992)) reverses the time evolution (``spin diffusion'') of the local polarization in a dipolar coupled $^{1}$H spin system. This refocusing originates a Polarization Echo whose amplitude attenuates by increasing the time $t_R$ elapsed until the dynamics is reversed. Different functional attenuations are found for a set of dipolar coupled systems: ferrocene, (C$_5$H$_5$)$_2$Fe, cymantrene, (C$_5$H$_5$)Mn(CO)$_3$, and cobaltocene, (C$_5$H$_5$)$_2$Co. To control a relevant variable involved in this attenuation a pulse sequence has been devised to progressively reduce the dipolar dynamics. Since it reduces the evolution of the polarization echo it is referred as REPE sequence. Two extreme behaviors were found while characterizing the materials: In systems with a strong source of relaxation and slow dynamics, the attenuation follows an exponential law (cymantrene). In systems with a strong dipolar dynamics the attenuation is mainly Gaussian. By the application of the REPE sequence the characteristic time of the Gaussian decay is increased until the presence of an underlying dissipative mechanism is revealed (cobaltocene). For ferrocene, however, the attenuation remains Gaussian within the experimental time scale. These two behaviors suggest that the many body quantum dynamics presents an extreme intrinsic instability which, in the presence of small perturbations, leads to the onset of irreversibility. This experimental conclusion is consistent with the tendencies displayed by the numerical solutions of model systems.Comment: 7 pages + 7 Postscript figure

Attenuation of polarization echoes in NMR: A study of the emergence of dynamical irreversibility in many-body quantum systems

The reversal of the time evolution of the local polarization in an interacting spin system involves a sign change of the effective dipolar Hamiltonian which refocuses the 'spin diffusion' process generating a polarization echo. Here, the attenuation of these echo amplitudes as a function of evolution time is presented for cymantrene and ferrocene polycrystalline samples, involving one and two five spin rings per molecule respectively. We calculate the fraction of polarization which is not refocused because only the secular part of the dipolar Hamiltonian is inverted. The results indicate that, as long as the spin dynamics is restricted to a single ring, the non-inverted part of the Hamiltonian is notable by itself to explain the whole decay of the polarization echoes. A cross over from exponential (cymantrene) to Gaussian (ferrocene) attenuation is experimentally observed. This is attributed to an increase of the relative importance of the spin dynamics, as compared with irreversible interactions, which favors dynamical irreversibility.Comment: 6 pages in Revtex, 11 Postscript figures. Final versio

Hierarchy of Floquet gaps and edge states for driven honeycomb lattices

Electromagnetic driving in a honeycomb lattice can induce gaps and topological edge states with a structure of increasing complexity as the frequency of the driving lowers. While the high frequency case is the most simple to analyze we focus on the multiple photon processes allowed in the low frequency regime to unveil the hierarchy of Floquet edge-states. In the case of low intensities an analytical approach allows us to derive effective Hamiltonians and address the topological character of each gap in a constructive manner. At high intensities we obtain the net number of edge states, given by the winding number, with a numerical calculation of the Chern numbers of each Floquet band. Using these methods, we find a hierarchy that resembles that of a Russian nesting doll. This hierarchy classifies the gaps and the associated edge states in different orders according to the electron-photon coupling strength. For large driving intensities, we rely on the numerical calculation of the winding number, illustrated in a map of topological phase transitions. The hierarchy unveiled with the low energy effective Hamiltonians, alongside with the map of topological phase transitions discloses the complexity of the Floquet band structure in the low frequency regime. The proposed method for obtaining the effective Hamiltonian can be easily adapted to other Dirac Hamiltonians of two dimensional materials and even the surface of a 3D topological insulator.Comment: Phys. Rev. A 91, 04362

Spin-orbit induced chirality of Andreev states in Josephson junctions

We study Josephson junctions (JJs) in which the region between the two superconductors is a multichannel system with Rashba spin-orbit coupling (SOC) where a barrier or a quantum point contact (QPC) is present. These systems might present unconventional Josephson effects such as Josephson currents for zero phase difference or critical currents that \textit{depend on} the current direction. Here, we discuss how the spin polarizing properties of the system in the normal state affect the spin characteristic of the Andreev bound states inside the junction. This results in a strong correlation between the spin of the Andreev states and the direction in which they transport Cooper pairs. While the current-phase relation for the JJ at zero magnetic field is qualitatively unchanged by SOC, in the presence of a weak magnetic field a strongly anisotropic behavior and the mentioned anomalous Josephson effects follow. We show that the situation is not restricted to barriers based on constrictions such as QPCs and should generically arise if in the normal system the direction of the carrier's spin is linked to its direction of motion.Comment: 19 pages, 9 figures. To appear in PR

Spin Hall effect in clean two dimensional electron gases with Rashba spin-orbit coupling

We study the spin polarization induced by a current flow in clean two dimensional electron gases with Rashba spin-orbit coupling. This geometric effect originates from special properties of the electron's scattering at the edges of the sample. In wide samples, the spin polarization has it largest value at low energies (close to the bottom of the band) and goes to zero at higher energies. In this case, the spin polarization is dominated by the presence of evanescent modes which have an explicit spin component outside the plane. In quantum wires, on the other hand, the spin polarization is dominated by interference effects induced by multiple scattering at the edges. Here, the spin polarization is quite sensitive to the value of the Fermi energy, especially close to the point where a new channel opens up. We analyzed different geometries and found that the spin polarization can be strongly enhanced.Comment: 10 pages, 13 figures, high quality figures available upon reques

Gate induced enhancement of spin-orbit coupling in dilute fluorinated graphene

We analyze the origin of spin-orbit coupling (SOC) in fluorinated graphene using Density Functional Theory (DFT) and a tight-binding model for the relevant orbitals. As it turns out, the dominant source of SOC is the atomic spin-orbit of fluorine adatoms and not the impurity induced SOC based on the distortion of the graphene plane as in hydrogenated graphene. More interestingly, our DFT calculations show that SOC is strongly affected by both the type and concentrations of the graphene's carriers, being enhanced by electron doping and reduced by hole doping. This effect is due to the charge transfer to the fluorine adatom and the consequent change in the fluorine-carbon bonding. Our simple tight-binding model, that includes the SOC of the $2p$ orbitals of F and effective parameters based on maximally localized Wannier functions, is able to account for the effect. The strong enhancement of the SOC induced by graphene doping opens the possibility to tune the spin relaxation in this material.Comment: 9 pages, 8 figure

Diffusion of fluorine adatoms on doped graphene

We calculate the diffusion barrier of fluorine adatoms on doped graphene in the diluted limit using Density Functional Theory. We found that the barrier $\Delta$ strongly depends on the magnitude and character of the graphene's doping ($\delta n$): it increases for hole doping ($\delta n<0$) and decreases for electron doping ($\delta n>0$). Near the neutrality point the functional dependence can be approximately by $\Delta=\Delta_0-\alpha\, \delta n$ where $\alpha\simeq6\times10^{-12}$ meVcm$^2$. This effect leads to significant changes of the diffusion constant with doping even at room temperature and could also affect the low temperature diffusion dynamics due to the presence of substrate induced charge puddles. In addition, this might open up the possibility to engineer the F dynamics on graphene by using local gates.Comment: 4 pages, 4 figure