Design of a spiral-shaped Mach Zehnder interferometric sensor for refractive index sensing of watery solutions

The design of a spiral-shaped Mach-Zehnder Interferometric sensor (sMZI sensor) for refractive index sensing of watery solutions is presented. The goal of the running project is to realise a multi-sensing array by placing multiple sMZIs in series to form a sensing branch, and to place several sensing branches in parallel. In such an arrangment it is possible to use a single light source for several sensors. Each sensor will contain an electro-optical modulator, which makes it possible to separately interrogate and accurately read-out each sensor in the same sensing branch

Nano-flow thermal sensor applying dymamic w-2w sensing method

This article presents microchannel thermal flow sensors fabricated using standard micromachining technology. The sensors comprise of a SiXNY microchannel created by etching of a poly-Si sacrificial layer. The channels are released by KOH etching through inlets and outlets etched from the backside of the substrate. Liquid flow is measured by platinum resistors deposited on top of the microchannel, while the channel is thermally isolated from the substrate by a SiXNY membrane. Flow rates of DI water in the order of nl⋅min-1 have been measured using a dynamic sensing method applying heat waves

Density Functional Theory for Chiral Nematic Liquid Crystals

Even though chiral nematic phases were the first liquid crystals experimentally observed more than a century ago, the origin of the thermodynamic stability of cholesteric states is still unclear. In this Letter we address the problem by means of a novel density functional theory for the equilibrium pitch of chiral particles. When applied to right-handed hard helices, our theory predicts an entropy-driven cholesteric phase, which can be either right- or left-handed, depending not only on the particle shape but also on the thermodynamic state. We explain the origin of the chiral ordering as an interplay between local nematic alignment and excluded-volume differences between left- and right-handed particle pairs

On the relation between adjacent inviscid cell type solutions to the rotating-disk equations

Over a large range of the axial coordinate a typical higher-branch solution of the rotating-disk equations consists of a chain of inviscid cells separated from each other by viscous interlayers. In this paper the leading-order relation between two adjacent cells will be established by matched asymptotic expansions for general values of the parameter appearing in the equations. It is found that the relation between the solutions in the two cells crucially depends on the behaviour of the tangential velocity in the viscous interlayer. The results of the theory are compared with accurate numerical solutions and good agreement is obtained

Micro Coriolis mass flow sensor for chemical micropropulsion systems

We have designed a micromachined micro Coriolis flow sensor for the measurement of hydrazine (N2H4, High Purity Grade) propellant flow in micro chemical propulsion systems [1]. The sensor measures mass flow up to 6 mg/s for a single thruster or up to 24 mg/s for four thrusters. The sensor will first be used for measurement and characterization of the micro thruster system in a simulated space vacuum environment. Integration of the sensor chip within the micro thruster flight hardware will be considered at a later stage. The new chip has an increased flow range because of an integrated on-chip bypass channel

Depletion-induced biaxial nematic states of boardlike particles

With the aim of investigating the stability conditions of biaxial nematic liquid crystals, we study the effect of adding a non-adsorbing ideal depletant on the phase behavior of colloidal hard boardlike particles. We take into account the presence of the depletant by introducing an effective depletion attraction between a pair of boardlike particles. At fixed depletant fugacity, the stable liquid crystal phase is determined through a mean-field theory with restricted orientations. Interestingly, we predict that for slightly elongated boardlike particles a critical depletant density exists, where the system undergoes a direct transition from an isotropic liquid to a biaxial nematic phase. As a consequence, by tuning the depletant density, an easy experimental control parameter, one can stabilize states of high biaxial nematic order even when these states are unstable for pure systems of boardlike particles

Frustration of the isotropic-columnar phase transition of colloidal hard platelets by a transient cubatic phase

Using simulations and theory, we show that the cubatic phase is metastable for three model hard platelets. The locally favored structures of perpendicular particle stacks in the fluid prevent the formation of the columnar phase through geometric frustration resulting in vitrification. Also, we find a direct link between structure and dynamic heterogeneities in the cooperative rotation of particle stacks, which is crucial for the devitrification process. Finally, we show that the life time of the glassy cubatic phase can be tuned by surprisingly small differences in particle shape.Comment: Submitted to Phys. Rev. Let

Stereocomplex formation in ABA triblock copolymers of poly(lactide) (A) and poly(ethylene glycol) (B)

Two series of triblock copolymers of poly(ethylene glycol) (PEG, number-average molecular weight [bar M ]n = 6000) and poly(L-lactide) (PLLA) or poly(D-lactide) (PDLA) were prepared by ring-opening polymerization of lactide initiated by PEG end groups using stannous octoate as a catalyst, either in refluxing toluene or in the melt at 175°C. The weight percentage of PLA in the polymers varied between 15 and 75 wt.-%. Blends of polymers containing blocks of opposite chirality were prepared by co-precipitation from homogeneous solutions. The melting temperatures of the crystalline PEG and PLA phases strongly depended on the composition of the polymers. The melting temperature of the PLA phase in the blends was approximately 40°C higher than that of the single block copolymers. Stereocomplex formation between blocks of enantiomeric poly(lactides) in PEG/PLA block copolymers was established for the first time. Water uptake of polymeric films prepared by solution casting was solely determined by the PEG content of the film