Structure of complexes between aluminum chloride and other chlorides, 2: Alkali-(chloroaluminates). Gaseous complexes

The structural chemistry of complexes between aluminum chloride and other metal chlorides is important both for practice and theory. Condensed-phase as well as vapor-phase complexes are of interest. Structural information on such complexes is reviewed. The first emphasis is given to the molten state because of its practical importance. Aluminum chloride forms volatile complexes with other metal chlorides and these vapor-phase complexes are dealt with in the second part. Finally, the variations in molecular shape and geometrical parameters are summarized

What is a crystal?

Almost 25 years have passed since Shechtman discovered quasicrystals, and 15 years since the Commission on Aperiodic Crystals of the International Union of Crystallography put forth a provisional definition of the term crystal to mean ``any solid having an essentially discrete diffraction diagram.'' Have we learned enough about crystallinity in the last 25 years, or do we need more time to explore additional physical systems? There is much confusion and contradiction in the literature in using the term crystal. Are we ready now to propose a permanent definition for crystal to be used by all? I argue that time has come to put a sense of order in all the confusion.Comment: Submitted to Zeitschrift fuer Kristallographi

The Misinformation Paradox: Older Adults are Cynical about News Media, but Engage with It Anyway

Misinformation can be easily spread with the click of a button, but can cause irreversible harm and negatively impact news consumers’ ability to discern false information. Some prior work suggests that older adults may engage with (read, share, or believe) misinformation at higher rates than others. However, engagement explanations vary. In an effort to understand older adults' engagement with misinformation better, we investigate the misinformation experiences of older adults through their perception of prior media experiences. Analyzing 69 semi-structured interviews with adults ages 59+ from the US, the Netherlands, Bosnia, and Turkey, we find that people who have decades of potential exposure or experience with both online and traditional news media have reached a state of media cynicism in which they distrust most, or even all, of the news they receive. Yet, despite this media cynicism, the older adults we study rarely fact-check the media they see and continue to read and share news they distrust. These findings suggest that this paradoxical reaction to media cynicism, in addition to prior explanations such as cognitive issues and digital literacy, may in part explain older adults' engagement with misinformation. Thus, we introduce the misinformation paradox, an additional area of research worth explorin

The electromotive force in multi-scale flows at high magnetic Reynolds number

Recent advances in dynamo theory have been made by examining the competition between small and large-scale dynamos at high magnetic Reynolds number Rm. Small-scale dynamos rely on the presence of chaotic stretching whilst the generation of large-scale fields occurs in flows lacking reflectional symmetry via a systematic electromotive force (emf). In this paper we discuss how the statistics of the emf (at high Rm) depend on the properties of the multi-scale velocity that is generating it. In particular, we determine that different scales of flow have different contributions to the statistics of the emf, with smaller-scales contributing to the mean without increasing the variance. Moreover we determine when scales in such a flow act independently in their contribution to the emf. We further examine the role of large-scale shear in modifying the emf. We conjecture that the distribution of the emf, and not simply the mean, largely determines the dominant scale of the magnetic field generated by the flow

Potential for ultrafast dynamic chemical imaging with few-cycle infrared lasers

We studied the photoelectron spectra generated by an intense few-cycle infrared laser pulse. By focusing on the angular distributions of the back rescattered high energy photoelectrons, we show that accurate differential elastic scattering cross sections of the target ion by free electrons can be extracted. Since the incident direction and the energy of the free electrons can be easily changed by manipulating the laser's polarization, intensity, and wavelength, these extracted elastic scattering cross sections, in combination with more advanced inversion algorithms, may be used to reconstruct the effective single-scattering potential of the molecule, thus opening up the possibility of using few-cycle infrared lasers as powerful table-top tools for imaging chemical and biological transformations, with the desired unprecedented temporal and spatial resolutions.Comment: 16 pages, 6 figure

Energy device for monitoring 4-10 MeV industrial electron accelerators

The electron beam energy is one of the critical parameters of electron accelerators since it can affect the dose distribution inside the body or in products to be irradiated with a beam of energetic electrons. A device has been developed for monitoring small variations in the electron beam energy that is easy-to-use during an irradiation run. It involves measurement of currents (or charges) collected by two identical aluminium plates, except for their thickness, and electrically insulated from each other, located in the beam. The ratio of these two currents (or collected charges) is quite sensitive to the beam energy; optimization of sensitivity is obtained by selecting the appropriate thickness of the front plate depending on the beam energy. In the present paper, we have investigated the feasibility of using this energy device at energies, from 4 to 10 MeV

Equality of Participation Online Versus Face to Face: Condensed Analysis of the Community Forum Deliberative Methods Demonstration

Online deliberation may provide a more cost-effective and/or less inhibiting environment for public participation than face to face (F2F). But do online methods bias participation toward certain individuals or groups? We compare F2F versus online participation in an experiment affording within-participants and cross-modal comparisons. For English speakers required to have Internet access as a condition of participation, we find no negative effects of online modes on equality of participation (EoP) related to gender, age, or educational level. Asynchronous online discussion appears to improve EoP for gender relative to F2F. Data suggest a dampening effect of online environments on black participants, as well as amplification for whites. Synchronous online voice communication EoP is on par with F2F across individuals. But individual-level EoP is much lower in the online forum, and greater online forum participation predicts greater F2F participation for individuals. Measured rates of participation are compared to self-reported experiences, and other findings are discussed.Comment: 14 pages, 10 tables, to appear in Efthimios Tambouris, Panos Panagiotopoulos, {\O}ystein S{\ae}b{\o}, Konstantinos Tarabanis, Michela Milano, Theresa Pardo, and Maria Wimmer (Editors), Electronic Participation: Proceedings of the 7th IFIP WG 8.5 International Conference, ePart 2015 (Thessaloniki, August 30-September 2), Springer LNCS Vol. 9249, 201

The Wikipedia Gender Gap Revisited: Characterizing Survey Response Bias with Propensity Score Estimation

Opt-in surveys are the most widespread method used to study participation in online communities, but produce biased results in the absence of adjustments for non-response. A 2008 survey conducted by the Wikimedia Foundation and United Nations University at Maastricht is the source of a frequently cited statistic that less than 13% of Wikipedia contributors are female. However, the same study suggested that only 39.9% of Wikipedia readers in the US were female – a finding contradicted by a representative survey of American adults by the Pew Research Center conducted less than two months later. Combining these two datasets through an application and extension of a propensity score estimation technique used to model survey non-response bias, we construct revised estimates, contingent on explicit assumptions, for several of the Wikimedia Foundation and United Nations University at Maastricht claims about Wikipedia editors. We estimate that the proportion of female US adult editors was 27.5% higher than the original study reported (22.7%, versus 17.8%), and that the total proportion of female editors was 26.8% higher (16.1%, versus 12.7%).Sloan School of ManagementHarvard University. Berkman Center for Internet & SocietyFord Visionary Leadership FundNorthwestern University (Evanston, Ill.

New Symmetries in Crystals and Handed Structures

For over a century, the structure of materials has been described by a combination of rotations, rotation-inversions and translational symmetries. By recognizing the reversal of static structural rotations between clockwise and counterclockwise directions as a distinct symmetry operation, here we show that there are many more structural symmetries than are currently recognized in right- or left-handed handed helices, spirals, and in antidistorted structures composed equally of rotations of both handedness. For example, though a helix or spiral cannot possess conventional mirror or inversion symmetries, they can possess them in combination with the rotation reversal symmetry. Similarly, we show that many antidistorted perovskites possess twice the number of symmetry elements as conventionally identified. These new symmetries predict new forms for "roto" properties that relate to static rotations, such as rotoelectricity, piezorotation, and rotomagnetism. They also enable symmetry-based search for new phenomena, such as multiferroicity involving a coupling of spins, electric polarization and static rotations. This work is relevant to structure-property relationships in all material structures with static rotations such as minerals, polymers, proteins, and engineered structures.Comment: 15 Pages, 4 figures, 3 Tables; Fig. 2b has error