Full Sky Study of Diffuse Galactic Emission at Decimeter Wavelengths

A detailed knowledge of the Galactic radio continuum is of high interest for studies of the dynamics and structure of the Galaxy as well as for the problem of foreground removal in Cosmic Microwave Background measurements. In this work we present a full-sky study of the diffuse Galactic emission at frequencies of few GHz, where synchrotron radiation is by far the dominant component. We perform a detailed combined analysis of the extended surveys at 408, 1420 and 2326 MHz (by Haslam et al. 1982, Reich 1982, Reich & Reich, 1986 and Jonas et al. 1998, respectively). Using the technique applied by Schlegel et al. (1998) to the IRAS data, we produce destriped versions of the three maps. This allows us to construct a nearly-full-sky map of the spectral index and of the normalization factor with sub-degree angular resolution. The resulting distribution of the spectral indices has an average of beta = 2.695 and dispersion sigma_{beta} = 0.120. This is representative for the Galactic diffuse synchrotron emission, with only minor effects from free-free emission and point sources.Comment: 10 pages, 16 jpeg figures, accepted to Astronomy & Astrophysics, Comments and figure adde

Fattori di emissione dalla combustione di legna e pellet in piccoli apparecchi domestici

The aim of this study was to report emission factors of pollutants (i.e., carbon monoxide, nitrogen oxides, non-methane hydrocarbons, particulate matter, polycyclic aromatic hydrocarbons, dioxins) from biomass burning residential heating appliances. The influence of several factors such as biomass type, appliance and combustion cycle was investigated. Four manually fed (6-11 kW) firewood burning and two automatic wood pellets (8.8-25 kW) appliances were tested under real-world operating conditions in order to determine the actual environmental performance of the appliance. The experimental EFs were also compared with the values proposed by the European emission inventory guidebook used in the local inventory in order to evaluate their representativeness of real world emissions. The composite macropollutant EFs for manually fed appliances are: for CO 5858 g GJ-1, for NOx 122 g GJ-1, NMHC 542 g GJ-1, PM 254 g GJ-1, whereas emissions are much lower for automatic pellets appliances: CO 219 g GJ-1, for NOx 66 g GJ-1, NMHC 5 g GJ-1, PM 85 g GJ-1. The open fireplace appears to have very high emission factors, however traditional and advanced stoves show the highest overall CO EFs. Especially for the advanced stove real-world emissions are far worse than those measured under cycles used for type testing of residential solid fuel appliances. No great difference is observed for different firewood types in batch working appliances, diversely the quality of the pellets is observed to influence directly the emission performance of the automatic appliances. Benzo(b)fluoranthene is the PAH with the highest contribution (110 mg GJ-1 for manual appliances and 2 mg GJ-1 for automatic devices) followed by benzo(a)pyrene (77 mg GJ-1 for manual appliances and 0,8 mg GJ-1 for automatic devices)

Le emissioni in atmosfera dalle combustioni in Lombardia

Il lavoro presenta le stime delle emissioni in atmosfera di polveri fini, precursori di polveri fini e gas serra in Lombardia provenienti dalle attività di combustione di combustibili e carburanti, come stimate dall’inventario regionale INEMAR per l’anno 2003. I dati dei consumi elaborati nell’inventario derivano da informazioni raccolte sia mediante questionari relativi alle principali sorgenti puntuali della regione, sia consultando le diverse fonti statistiche. Le emissioni in atmosfera sono stimate sia attraverso dati derivanti da misure effettuate presso gli impianti che tramite fattori di emissione proposti in letteratura e utilizzati in ambito EMEP-Corinair e IPCC (Intergovernmental Panel on Climate Change). La combustione nel settore del trasporto stradale risulta essere la principale sorgente per numerosi inquinanti, fra cui PM10, NOx, SO2 e CO. L’olio combustibile utilizzato per la produzione di energia è la maggiore fonte di SO2 (56% delle emissioni totali regionali), mentre il gasolio per autotrazione fornisce il principale contributo alle emissioni di NOx (44% del totale). Per le emissioni di polveri (sia PM10 che PM2,5), oltre ai determinanti contributi della combustione del gasolio per autotrazione e della legna in ambito domestico, sono rilevanti anche i processi di usura nel traffico stradale (pneumatici, freni, abrasione dell’asfalto) e le attività relative al settore agro-zootecnico. La benzina è la principale fonte di CO (50%), mentre il metano costituisce una sorgente di grande importanza (45%) per la CO2 e di interesse anche per gli ossidi di azoto (21% del totale regionale). Il lavoro fornisce altresì una valutazione dei fattori di emissione medi dalle attività di combustione in Lombardia a diverse scale di dettaglio

10 ANNI DI CAMBIAMENTI CLIMATICI: IL PESO DEI RITARDI E I PRIMI TIMIDI SEGNALI DI AZIONE

Se negli ultimi 10 anni gli effetti del riscaldamento globale sono diventati sempre più evidenti, come del resto previsto dalla comunità scientifica, è cresciuta anche la risposta globale alla crisi climatica, seppure in modo del tutto insufficiente rispetto a quanto necessario per stabilizzare l’aumento delle temperature globali. I continui record delle temperature globali, uniti ad un aumento degli impatti delle ondate di calore e degli estremi di precipitazione, sempre più percepibili, mostrano l’urgenza di un’azione maggiormente incisiva contro il cambiamento climatico. L’articolo passa in rassegna l’andamento dei principali fattori climalteranti, di alcuni indicatori del riscaldamento globale, nonché delle principali tendenze nelle azioni di contrasto alla crisi climatica.If in the last 10 years the effects of global warming are increasingly evident, as predicted by the scientific community, the global response to the climate crisis has grown, albeit in a completely insufficient way compared to what is necessary to stabilise the increase in global temperatures. Continued global temperature records, coupled with an increasing impact of heat waves and precipitation extremes, show the urgency of the need for action against climate change. The article reviews the trend of the main climate-changing factors, some indicators of global warming, as well as the main trends in actions to combat the climate crisis

Techno-economic evaluation of buffered accelerated weathering of limestone as a CO2 capture and storage option

Carbon dioxide storage technologies are needed not only to store the carbon captured in the emissions of hard-to-abate sectors but also for some carbon dioxide removal technologies requiring a final and permanent storage of CO2. The pace and scale of geological CO2 storage deployment have fallen short of expectations, and there is a growing interest in ocean-based CO2 storage options. As complementary to geological storage, buffered accelerated weathering of limestone (BAWL) has been proposed to produce a buffered ionic solution at seawater pH, derived from the reaction in seawater between a CO2 stream and a micron-sized powder of calcium carbonate (CaCO3), within a long tubular reactor. The addition of calcium hydroxide to buffer the unreacted CO2 before the discharge in seawater is also envisaged. BAWL avoids the risks of CO2 degassing back into the atmosphere and does not induce seawater acidification. This work presents a mass and energy balance and preliminary cost analysis of the technology for different configurations of discharge depth (100, 500, 3,000 m), pipeline length (10, 25, 100 km) and diameter of CaCO3 particles (1, 2, 10 mu m) fed in the tubular reactor. The total energy consumption to capture and store 1 t of CO2 generated by a steam-methane reforming (SMR) process ranges from 1.3 to 2.2 MWh. The CO2 released from the CaCO3 calcination to produce the buffering solution leads to a total CO2 storage requirement 43-85% higher than the CO2 derived by SMR. The total cost to capture and store 1 t of CO2 from SMR is estimated in the range 142-189 euro

Ocean liming effects on dissolved organic matter dynamics

Ocean liming has gained attention as a potential solution to mitigate climate change by actively removing carbon dioxide (CO2) from the atmosphere. The addition of hydrated lime to oceanic surface water leads to an increase in alkalinity, which in turn promotes the uptake and sequestration of atmospheric CO2.Despite the potential of this technique, its effects on the marine ecosystem are still far from understood, and there is currently no information on the potential impacts on the concentration and quality of dissolved organic matter (DOM), which is one of the largest, most complex and yet least understood mixtures of organic molecules on Earth.The aim of this study is to provide the first experimental evidence about the potential effects of hydrated lime addition on DOM dynamics in the oceans by assessing changes in its concentration and optical properties (absorption and fluorescence).To investigate the effects of liming on DOM pools with different concentrations and quality, seawater was collected from two contrasting environments: the oligotrophic Mediterranean Sea, known for its dissolved organic carbon (DOC) concentration comparable to that observed in the oceans, and the eutrophic Baltic Sea, characterized by high DOM concentration mostly of terrestrial origin. Hydrated lime was added to both waters to reach pH values of 9 and 10.Our findings reveal that the addition of hydrated lime has a noticeable effect on DOM dynamics in both the Mediterranean Sea and Baltic Sea, determining a reduction in DOC concentration and a change in the optical properties (absorption and fluorescence) of DOM. These effects, detectable at pH 9, become significant at pH 10 and are more pronounced in the Mediterranean Sea than in the Baltic Sea. These potential short-term effects should be considered within the context of the physicochemical properties of seawater and the seasonal variability

3rd International Conference on Negative CO2 Emissions Conference Proceedings

These conference proceedings contain extended abstracts submitted to the 3rd International Conference on Negative CO₂ Emissions. While these abstracts were all selected for presentation at the conference, the contents have not undergone formal peer review

Alkalinization Scenarios in the Mediterranean Sea for Efficient Removal of Atmospheric CO2 and the Mitigation of Ocean Acidification

It is now widely recognized that in order to reach the target of limiting global warming to well below 2°C above pre-industrial levels (as the objective of the Paris agreement), cutting the carbon emissions even at an unprecedented pace will not be sufficient, but there is the need for development and implementation of active Carbon Dioxide Removal (CDR) strategies. Among the CDR strategies that currently exist, relatively few studies have assessed the mitigation capacity of ocean-based Negative Emission Technologies (NET) and the feasibility of their implementation on a larger scale to support efficient implementation strategies of CDR. This study investigates the case of ocean alkalinization, which has the additional potential of contrasting the ongoing acidification resulting from increased uptake of atmospheric CO2 by the seas. More specifically, we present an analysis of marine alkalinization applied to the Mediterranean Sea taking into consideration the regional characteristics of the basin. Rather than using idealized spatially homogenous scenarios of alkalinization as done in previous studies, which are practically hard to implement, we use a set of numerical simulations of alkalinization based on current shipping routes to quantitatively assess the alkalinization efficiency via a coupled physical-biogeochemical model (NEMO-BFM) for the Mediterranean Sea at 1/16° horizontal resolution (~6 km) under an RCP4.5 scenario over the next decades. Simulations suggest the potential of nearly doubling the carbon-dioxide uptake rate of the Mediterranean Sea after 30 years of alkalinization, and of neutralizing the mean surface acidification trend of the baseline scenario without alkalinization over the same time span. These levels are achieved via two different alkalinization strategies that are technically feasible using the current network of cargo and tanker ships: a first approach applying annual discharge of 200 Mt Ca(OH)2 constant over the alkalinization period and a second approach with gradually increasing discharge proportional to the surface pH trend of the baseline scenario, reaching similar amounts of annual discharge by the end of the alkalinization period. We demonstrate that the latter approach allows to stabilize the mean surface pH at present day values and substantially increase the potential to counteract acidification relative to the alkalinity added, while the carbon uptake efficiency (mole of CO2 absorbed by the ocean per mole of alkalinity added) is only marginally reduced. Nevertheless, significant local alterations of the surface pH persist, calling for an investigation of the physiological and ecological implications of the extent of these alterations to the carbonate system in the short to medium term in order to support a safe, sustainable application of this CDR implementation