Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions

Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combination of thiol-Michael addition and epoxide ring-opening has been used for the post-functionalisation with amines and thiols to prepare a range of functional materials

Generation linewidth of an auto-oscillator with a nonlinear frequency shift: Spin-torque nano-oscillator

It is shown that the generation linewidth of an auto-oscillator with a nonlinear frequency shift (i.e. an auto-oscillator in which frequency depends on the oscillation amplitude) is substantially larger than the linewidth of a conventional quasi-linear auto-oscillator due to the renormalization of the phase noise caused by the nonlinearity of the oscillation frequency. The developed theory, when applied to a spin-torque nano-contact auto-oscillator, predicts a minimum of the generation linewidth when the nano-contact is magnetized at a critical angle to its plane, corresponding to the minimum nonlinear frequency shift, in good agreement with recent experiments.Comment: 4 pages, 2 figure

A Comparison Of Five Mechanical Work Algorithms For Different Footstrike Patterns And Speeds During Distance Running

The mechanical work done by a runner during an average stride cyde has been calculated with a variety of algorithms that generate values that may vary by an order of magnitude. The application of different algorithms to the same data set is uncommon, and does not seem to have been used at all to compare different foot strike patterns (FSP) during distance running. Average stride cycle values from five work algorithms for forefoot strike (ffs) and heel strike (hs) running at three different running speeds are presented. In general order from most to least restrictive: Wn allows no transfer between segments; Ww, within-segment transfer only; WwbAS, transfer within and between adjacent segments only; WwbLT, within and between segments of the same limb and the trunk; and, Wwb, within- and between-segment transfer with no restrictions. The primary difference in these algorithms is the amount of energy transfer they permit between and among body segments. Twelve highly skilled, male distance runners each ran with both FSP at three speeds ranging from 3.58 to 4.58 m-s-l. High-speed video (200 Hz) was used to track eight segment endpoint markers in the left sagittal plane. An ll-segment model was used with symmetry assumed to generate right side values. Among the algorithms, the no-transfer method (Wn) produced the highest work estimates. An absolute difference of -300 joules-stride-1 (-15-20%) existed across speeds between the no-transfer and within-transfer algorithms. There was then a relatively large decrease to the span of values generated from the other three algorithms. WwbAS was slightly higher than the remaining two algorithms, moreso in relative terms as speed increased. WwbLT increased slightly over speed (-40% slow->fast), while Wwb, the least restrictive, demonstrated almost no change across speeds (-1 % slow->fast). On average, these differences converged absolutely (75->20 joules-stride-1) and relatively (9.8%->2.5%) with increased speed; i.e., differences between the two .FSP decreased as speed increased. At all speeds for each algorithm, hs was lower than ffs. Collapsed across speeds, hs as percentage of ffs was 96.7 (Wn), 96.5 (ww)- 96.7 (WwbAS), 95.8 (WwbLT) and 89.4% (Wwb). Wwb across speeds consistently showed the largest relative differences between FSP, due perhaps in part to low absolute values. However, FSP differences still decreased with increased speed. This algorithm, therefore, appears to preserve the ordinal relationship and the trend in relative change between FSP across speeds reflected in the other four algorithms. Overall, the consistency across all algorithms of absolute and relative decrease between FSP with increased speed suggests variations in actual kinematics, not algorithms, are responsible for observed differences

Kinetic-scale magnetic turbulence and finite Larmor radius effects at Mercury

We use a nonstationary generalization of the higher-order structure function technique to investigate statistical properties of the magnetic field fluctuations recorded by MESSENGER spacecraft during its first flyby (01/14/2008) through the near Mercury's space environment, with the emphasis on key boundary regions participating in the solar wind -- magnetosphere interaction. Our analysis shows, for the first time, that kinetic-scale fluctuations play a significant role in the Mercury's magnetosphere up to the largest resolvable time scale ~20 s imposed by the signal nonstationarity, suggesting that turbulence at this planet is largely controlled by finite Larmor radius effects. In particular, we report the presence of a highly turbulent and extended foreshock system filled with packets of ULF oscillations, broad-band intermittent fluctuations in the magnetosheath, ion-kinetic turbulence in the central plasma sheet of Mercury's magnetotail, and kinetic-scale fluctuations in the inner current sheet encountered at the outbound (dawn-side) magnetopause. Overall, our measurements indicate that the Hermean magnetosphere, as well as the surrounding region, are strongly affected by non-MHD effects introduced by finite sizes of cyclotron orbits of the constituting ion species. Physical mechanisms of these effects and their potentially critical impact on the structure and dynamics of Mercury's magnetic field remain to be understood.Comment: 46 pages, 5 figures, 2 table

Photoionization of Galactic Halo Gas by Old Supernova Remnants

We present new calculations on the contribution from cooling hot gas to the photoionization of warm ionized gas in the Galaxy. We show that hot gas in cooling supernova remnants (SNRs) is an important source of photoionization, particularly for gas in the halo. We find that in many regions at high latitude this source is adequate to account for the observed ionization so there is no need to find ways to transport stellar photons from the disk. The flux from cooling SNRs sets a floor on the ionization along any line of sight. Our model flux is also shown to be consistent with the diffuse soft X-ray background and with soft X-ray observations of external galaxies. We consider the ionization of the clouds observed towards the halo star HD 93521, for which there are no O stars close to the line of sight. We show that the observed ionization can be explained successfully by our model EUV/soft X-ray flux from cooling hot gas. In particular, we can match the H alpha intensity, the S++/S+ ratio, and the C+* column. From observations of the ratios of columns of C+* and either S+ or H0, we are able to estimate the thermal pressure in the clouds. The slow clouds require high (~10^4 cm^-3 K) thermal pressures to match the N(C+*)/N(S+) ratio. Additional heating sources are required for the slow clouds to maintain their ~7000 K temperatures at these pressures, as found by Reynolds, Hausen & Tufte (1999).Comment: AASTeX 5.01; 34 pages, 2 figures; submitted to Astrophysical Journa

Comparative Examination of Plasmoid Ejection at Mercury, Earth, Jupiter, and Saturn

The onset of magnetic reconnection in the near-tail of Earth, long known to herald the fast magnetospheric convection that leads to geomagnetic storms and substorms, is very closely associated with the formation and down-tail ejection of magnetic loops or flux ropes called plasmoids. Plasmoids form as a result of the fragmentation of preexisting cross-tail current sheet as a result of magnetic reconnection. Depending upon the number, location, and intensity of the individual reconnection X-lines and how they evolve, some of these loop-like or helical magnetic structures may also be carried sunward. At the inner edge of the tail they are expected to "re-reconnect' with the planetary magnetic field and dissipate. Plasmoid ejection has now been observed in the magnetotails of Mercury, Earth, Jupiter, and Saturn. These magnetic field and charged particle measurements have been taken by the MESSENGER, Voyager, Galileo, Cassini, and numerous Earth missions. Here we present a comparative examination of the structure and dynamics of plasmoids observed in the magnetotails of these 5 planets. The results are used to learn more about how these magnetic structures form and to assess similarities and differences in the nature of magnetotail reconnection at these planets

Simulation of impact of the Generic Accident-Resistant Packaging (GAP)

Finite element simulations modelling impact of the Generic Accident-Resistant Packaging (GAP) have been performed. The GAP is a nuclear weapon shipping container that will be used by accident response groups from both the United States and the United Kingdom. The package is a thin-walled steel structure filled with rigid polyurethane foam and weighs approximately 5100 lbs when loaded. The simulations examined 250 ft/s impacts onto a rigid target at several orientations. The development of the finite element model included studies of modelling assumptions and material parameters. Upon completion of the simulation series, three full-scale impact tests were performed. A comparison of the simulation results to the test data is given. Differences between the results and data are examined, and possible explanations for the differences are discussed