Potential for Farmers’ Cooperatives to Convert Coffee Husks into Biochar and Promote the Bioeconomy in the North Ecuadorian Amazon

Improving the livelihoods of communities living in fragile ecosystems, such as tropical forests, is among the main strategies to promote their conservation and preserve wildlife. In the Ecuadorian Amazon, farmers’ cooperatives are recognized as an important mechanism to improve the socioeconomic conditions of local communities. This study analyzes the integration of pyrolysis processes to convert agricultural waste into biochar as a way to implement the bioeconomy in these organizations. We found that post-harvesting processes in the studied farmers’ cooperatives are similar, and coffee husks are a potential feedstock to produce biochar. Although the environmental policies in Ecuador consider the valorization of agricultural waste, we did not find any specific standard to regulate the operation of pyrolysis facilities. Nonetheless, conversion of agricultural waste into biochar can contribute to (i) replacement of subsidized fossil fuels used in drying processes, (ii) prevention of environmental pollution caused by accumulation of waste, (iii) emergence of new income sources linked with the provision of carbon sequestration services, and (iv) the long-term maintenance of soil fertility. Currently, demonstration projects are needed to stimulate collaboration among farmers’ cooperatives, academia, the government, international cooperation agencies, and existing forest conservation initiatives.Fundação para a Ciência e a TecnologiaBundesministerium für Bildung und ForschungPeer Reviewe

Palm oil kernel shell as solid fuel for the commercial and industrial sector in Ecuador: tax incentive impact and performance of a prototype burner

The Ecuadorian industrial and commercial sectors are in general supported in the use of diesel for energy purposes. An alternative to replace diesel could be the use of palm oil residual biomass as solid fuel. It is estimated that 57.7% of the capital costs required to implement a biomass boiler that use untreated palm oil kernel shell (KS) as fuel in replacement of a diesel boiler would be covered by in force tax incentives. Nonetheless, untaxed and subsidized diesel utilization coupled to the important capital and operating costs associated to the biomass boiler results in relatively high payback periods, within the range of 6 to 7.9 years. Analyzing a base case, it is observed that replacement of diesel by KS results in a reduction of 8 times the fuel costs. Implementation of pre-treatment processes (e.g. pelletizing) could increase the KS price, affecting the potential to lower the costs of thermal energy production. Accordingly, utilization of raw KS for thermal energy production was demonstrated using a horizontal burner prototype. The experimental analysis of the KS combustion process shows that combustion efficiency (99.8%) is as high as that observed in other type of biomass burners. During the steady state operation periods, CO concentration in the flue gases (260.1 mg/Nm3) was below the limit established by the European standards for solid fuel boilers (500 mg/Nm3). Ash sintering was observed in the grate during the combustion experiments. The ash discharge process induced periodic fluctuations in the combustion chamber temperature profile as well as fluctuations in the flue gas composition. Despite these localized and periodic temperature and gas composition fluctuations, in the whole, and considering longer periods of operation, the combustion system was under steady state conditions and showed to be suitable for energetic valorization of untreated KS.publishe

Characteristics of ash and particle emissions during bubbling fluidised bed combustion of three types of residual forest biomass

Combustion of residual forest biomass (RFB) derived from eucalypt (Eucalyptus globulus), pine (Pinus pinaster) and golden wattle (Acacia longifolia) was evaluated in a pilot-scale bubbling fluidised bed reactor (BFBR). During the combustion experiments, monitoring of temperature, pressure and exhaust gas composition has been made. Ash samples were collected at several locations along the furnace and flue gas treatment devices (cyclone and bag filter) after each combustion experiment and were analysed for their unburnt carbon content and chemical composition. Total suspended particles (TSP) in the combustion flue gas were evaluated at the inlet and outlet of cyclone and baghouse filter and further analysed for organic and elemental carbon, carbonates and 57 chemical elements. High particulate matter collection efficiencies in the range of 94-99% were observed for the baghouse, while removal rates of only 1.4-17% were registered for the cyclone. Due to the sand bed, Si was the major element in bottom ashes. Fly ashes, in particular those from eucalypt combustion, were especially rich in CaO, followed by relevant amounts of SiO2, MgO and K2O. Ash characteristics varied among experiments, showing that their inorganic composition strongly depends on both the biomass composition and combustion conditions. Inorganic constituents accounted for TSP mass fractions up to 40 wt%. Elemental carbon, organic matter and carbonates contributed to TSP mass fractions in the ranges 0.58-44%, 0.79-78% and 0.01-1.7%, respectively.publishe

Effect of industrial and domestic ash from biomass combustion, and spent coffee grounds, on soil fertility and plant growth: experiments at field conditions

An experimental study was conducted at field conditions in order to evaluate the effect of application of ash from biomass combustion on some soil fertility characteristics and plant growth. Application of 7.5 Mg ha-1 industrial fly ash (IA), domestic ash (DA), and a 50:50 mix of domestic ash (DA) and spent coffee grounds (SCG) was made in different soil parcels. Lolium perenne seeds were sown and the grown biomass was harvested and quantified after 60 days. Soil samples from each parcel were also collected after that period and characterized. Both soil and grown biomass samples were analyzed for Ca, Mg, Na, K, P, Fe, Mn, Zn, and Al contents. Soil pH was determined before and after amendment. All applications rose significantly soil pH. Domestic ash, whether combined with coffee grounds or not, proved to be efficient at supplying available macronutrients Ca, Mg, K, and P to the soil and also reducing availability of Al (more than industrial ash). However, it inhibited plant growth, even more when combined with spent coffee grounds. As regards to elemental abundance in plant tissue, both domestic ash treatments reduced Ca and enhanced Al contents, unlike industrial ash, which proved less harmful for the load applied in the soil. Hence, it was possible to conclude that application load should be a limiting factor for this management option for the studied materials.publishe

Conversion of quinoa and lupin agro-residues into biochar in the Andes: An experimental study in a pilot-scale auger-type reactor

In the last decades, the cultivation of quinoa and lupin became an important source of income for Andean farmers due to the demand for high nutrient-density foods from the Global North. The increase in the cultivation intensity caused by this exogenous demand led to the overexploitation of local ecosystems and a decrease in soil fertility. As an alternative to recover and improve soil quality, this work uses a pilot-scale auger pyrolysis reactor, implemented in the Andes, to assess the conversion of the agro residues generated in the post-harvesting processes of quinoa and lupin into biochar for soil amendment. Following the European Biochar Certificate guidelines, the pyrolyzed quinoa stems can be classified as biochar while the pyrolyzed quinoa husks can be classified as pyrogenic carbonaceous material. Both can be used for soil amendment considering their molar ratios (H/Corg, O/Corg) and carbon content. It was not possible to carbonize lupin stems and seedcases. Despite the altitude (2,632 m.a.s.l), the CO concentration during the carbonization of quinoa stems and husks were 1,024.4 and 559 mg/Nm3, this last, near the European eco-design standard of 500 mg/Nm3. A subsequent SWOT analysis showed the need to explore low-cost and low-complexity pyrolysis reactors that allow the decentralized conversion of agro residues at the farm-scale. The development of local standards to regulate the production and use of biochar is also essential to grant the safety of the processes, the quality of the products, and mobilize funds that allow implementation at relevant scales

Axial Concentration Profiles and NO Flue Gas in a Pilot-Scale Bubbling Fluidized Bed Coal Combustor

Atmospheric bubbling fluidized bed coal combustion of a bituminous coal and anthracite with particle diameters in the range 500-4000 ím was investigated in a pilot-plant facility. The experiments were conducted at steady-state conditions using three excess air levels (10, 25, and 50%) and bed temperatures in the 750-900 °C range. Combustion air was staged, with primary air accounting for 100, 80, and 60% of total combustion air. For both types of coal, high NO concentrations were found inside the bed. In general, the NO concentration decreased monotonically along the freeboard and toward the exit flue; however, during combustion with high air staging and low to moderate excess air, a significant additional NO formation occurred near the secondary air injection point. The results show that the bed temperature increase does not affect the NO flue gas concentration significantly. There is a positive correlation between excess air and the NO flue gas concentration. The air staging operation is very effective in lowering the NO flue gas, but there is a limit for the first stage stoichiometry below which the NO flue gas starts rising again. This effect could be related with the coal rank

Critical aspects of biomass ashes utilization in soils: composition, leachability, PAH and PCDD/F

Bottom and fly ashes streams collected along a year in several biomass thermal plants were studied. The bulk composition of ashes and other chemical characteristics that may impact soil application showed a high variability depending on the ash stream, combustion technology and ash management practice at the power plants. The acid neutralization capacity (ANC) and metal’s availability for leaching at fixed pH 7 and 4 was performed according with EA NEN 7371, as a quick evaluation method to provide information on the long-term behavior of ashes, regarding heavy metals and also plant nutrients release. Also the pH dependence leachability study was performed according to CEN/TS 14429 for predicting the leaching behavior under different scenarios. Leachability profiles were established between pH 3 and 12, allowing to distinguish different solubility control phenomena of toxic heavy metals (Cu, Cr, Mn, Ni, Zn, Pb) as well as other salts (Ca, K, Mg, Na, Cl). The ANC of fly ashes at pH 4 (3.6–9.6 molH+/kg) were higher than that observed for the bottom ashes (1.2–2.1 molH+/kg). Ashes were also characterized for persistent organic pollutants (POP), such as polycyclic aromatic hydrocarbons (PAH) and paradibenzodioxines and furanes (PCDD/F). Contents were found to be much higher in fly ash than in bottom ash streams. None of the PAH levels did reach the current national limit value of sewage sludge application in soils or the guide value for ash in north European countries. However, PCDD/F contents, which are not regulated, varied from non-detectable levels to high amounts, regardless the level of loss on ignition (LOI) or unburned carbon content in fly ashes. Given the current ash management practices and possible use of blends of bottom and fly ash streams as soil conditioners resembles clear the urgent need to regulate ash utilization in soils, incorporating limit values both for heavy metals, PAH and PCDD/F

Critical review of key variables affecting potential recycling applications of ash produced at large-scale biomass combustion plants

Growing quantities of biomass ash are produced worldwide due to an increasing use of biomass for heat and electricity generation. Physical-chemical properties and elemental composition of ash at industrial biomass thermal power plants show significant variations. Experimental methods to characterize ashes are time-consuming and difficult to implement on a routine basis, posing severe limitations to the selection of most appropriate recycling options for these waste materials at the ash production stage. This review focused on relevant biomass ash properties that must be evaluated prior to environmental applications and recycling and on the identification of key process variables that determine such properties. A database characterizing 77 biomass ashes collected at large-scale industrial facilities was compiled. Ash type (bottom ash (BA) or fly ash (FA)) are distinguished by their pH and electrical conductivity ranges. Ash chemical composition was largely influenced by the type of biomass fuel burnt, and to a lesser extent by the technology and temperature of combustion. Ash from combustion of contaminated biomass, as well as the smallest fraction of FA particles (< 0.200 μm) show constraints for use in soils or construction materials due to high potentially toxic elements concentrations, soluble salts, and/or chloride contents posing both environmental and technical concerns. Both BA and FA generated by combustion of wood and biomass mixtures, regardless of the combustion technology, were found suitable for soil application as well as for incorporation in road or cementitious materials, provided that technical and risk assessment protocols to regulate their use are produced and standardized.publishe

Efficiency of Emission Reduction Technologies for Residential Biomass Combustion Appliances: Electrostatic Precipitator and Catalyst

Residential biomass combustion has been pointed out as one of the largest sources of atmospheric pollutants. Rising awareness of the environmental effects of residential biomass combustion emissions boosted the development of different emission reduction devices that are currently available on the market for small-scale appliances. However, detailed studies on the efficiency of these devices in different combustion systems available in Southern European countries are lacking. In this study, two pollution control devices (catalytic converter and electrostatic precipitator) were tested in two different combustion systems (batch mode operated woodstove and automatically fed pellet stove) in order to assess the emission reduction potential of the devices. Pine firewood was used to fuel the woodstove. One commercial brand of pellets and an agricultural fuel (olive pit) were taken for the experiments in the pellet stove. While the efficiency of the electrostatic precipitator in reducing PM10 was only recorded for woodstove emissions (29%), the effect of the catalyst in decreasing gaseous emissions was only visible when applied to the pellet stove flue gas. For wood pellet combustion, reductions of CO and TOC emissions were in the range of 60–62% and 74–77%, respectively. For olive pit combustion, a lower decrease of 59–60% and 64% in CO and TOC emissions, respectively, was recorded

Efficiency of Emission Reduction Technologies for Residential Biomass Combustion Appliances: Electrostatic Precipitator and Catalyst

Residential biomass combustion has been pointed out as one of the largest sources of atmospheric pollutants. Rising awareness of the environmental effects of residential biomass combustion emissions boosted the development of different emission reduction devices that are currently available on the market for small-scale appliances. However, detailed studies on the efficiency of these devices in different combustion systems available in Southern European countries are lacking. In this study, two pollution control devices (catalytic converter and electrostatic precipitator) were tested in two different combustion systems (batch mode operated woodstove and automatically fed pellet stove) in order to assess the emission reduction potential of the devices. Pine firewood was used to fuel the woodstove. One commercial brand of pellets and an agricultural fuel (olive pit) were taken for the experiments in the pellet stove. While the efficiency of the electrostatic precipitator in reducing PM10 was only recorded for woodstove emissions (29%), the effect of the catalyst in decreasing gaseous emissions was only visible when applied to the pellet stove flue gas. For wood pellet combustion, reductions of CO and TOC emissions were in the range of 60&ndash;62% and 74&ndash;77%, respectively. For olive pit combustion, a lower decrease of 59&ndash;60% and 64% in CO and TOC emissions, respectively, was recorded