10,804 research outputs found
Spin-orbital excitation continuum and anomalous electron-phonon interaction in the Mott insulator LaTiO
Raman scattering experiments on stoichiometric, Mott-insulating LaTiO
over a wide range of excitation energies reveal a broad electronic continuum
which is featureless in the paramagnetic state, but develops a gap of cm upon cooling below the N\'eel temperature K. In the
antiferromagnetic state, the spectral weight below the gap is transferred to
well-defined spectral features due to spin and orbital excitations. Low-energy
phonons exhibit pronounced Fano anomalies indicative of strong interaction with
the electron system for , but become sharp and symmetric for . The electronic continuum and the marked renormalization of the phonon
lifetime by the onset of magnetic order are highly unusual for Mott insulators
and indicate liquid-like correlations between spins and orbitals.Comment: to appear in Phys. Rev. Let
Magnetostrictive Neel ordering of the spin-5/2 ladder compound BaMn2O3: distortion-induced lifting of geometrical frustration
The crystal structure and the magnetism of BaMnO have been studied by
thermodynamic and by diffraction techniques using large single crystals and
powders. BaMnO is a realization of a spin ladder as the
magnetic interaction is dominant along 180 Mn-O-Mn bonds forming the
legs and the rungs of a ladder. The temperature dependence of the magnetic
susceptibility exhibits well-defined maxima for all directions proving the
low-dimensional magnetic character in BaMnO. The susceptibility and
powder neutron diffraction data, however, show that BaMnO exhibits a
transition to antiferromagnetic order at 184 K, in spite of a full frustration
of the nearest-neighbor inter-ladder coupling in the orthorhombic
high-temperature phase. This frustration is lifted by a remarkably strong
monoclinic distortion which accompanies the magnetic transition.Comment: 9 pages, 8 figures, 2 tables; in V1 fig. 2 was included twice and
fig. 4 was missing; this has been corrected in V
National quality indicators and policies from 15 countries leading in adult end-of-life care: A systematic environmental scan
© Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted. Background: The importance of measuring the quality of end-of-life care provision is undisputed, but determining how best to achieve this is yet to be confirmed. This study sought to identify and describe national end-of-life care quality indicators and supporting policies used by countries leading in their end-of-life care provision. Methods: A systematic environmental scan that included a web search to identify relevant national policies and indicators; hand searching for additional materials; information from experts listed for the top 10 (n=15) countries ranked in the 'quality of care' category of the 2015 Quality of Death Index study; and snowballing from Index experts. Findings: Ten countries (66%) have national policy support for end-of-life care measurement, five have national indicator sets, with two indicator sets suitable for all service providers. No countries mandate indicator use, and there is limited evidence of consumer engagement in development of indicators. Two thirds of the 128 identified indicators are outcomes measures (62%), and 38% are process measures. Most indicators pertain to symptom management (38%), social care (32%) or care delivery (27%). Interpretations: Measurement of end-of-life care quality varies globally and rarely covers all care domains or service providers. There is a need to reduce duplication of indicator development, involve consumers, consider all care providers and ensure measurable and relevant indicators to improve end-of-life care experiences for patients and families
Anomalous expansion and phonon damping due to the Co spin-state transition in RCoO_3 with R = La, Pr, Nd and Eu
We present a combined study of the thermal expansion and the thermal
conductivity of the perovskite series RCoO_3 with R = La, Nd, Pr and Eu. The
well-known spin-state transition in LaCoO_3 is strongly affected by the
exchange of the R ions due to their different ionic radii, i.e. chemical
pressure. This can be monitored in detail by measurements of the thermal
expansion, which is a highly sensitive probe for detecting spin-state
transitions. The Co ions in the higher spin state act as additional scattering
centers for phonons, therefore suppressing the phonon thermal conductivity.
Based on the analysis of the interplay between spin-state transition and heat
transport, we present a quantitative model of the thermal conductivity for the
entire series. In PrCoO_3, an additional scattering effect is active at low
temperatures. This effect arises from the crystal field splitting of the 4f
multiplet, which allows for resonant scattering of phonons between the various
4f levels.Comment: 15 pages including 5 figure
The spin state transition in LaCoO; revising a revision
Using soft x-ray absorption spectroscopy and magnetic circular dichroism at
the Co- edge we reveal that the spin state transition in LaCoO
can be well described by a low-spin ground state and a triply-degenerate
high-spin first excited state. From the temperature dependence of the spectral
lineshapes we find that LaCoO at finite temperatures is an inhomogeneous
mixed-spin-state system. Crucial is that the magnetic circular dichroism signal
in the paramagnetic state carries a large orbital momentum. This directly shows
that the currently accepted low-/intermediate-spin picture is at variance.
Parameters derived from these spectroscopies fully explain existing magnetic
susceptibility, electron spin resonance and inelastic neutron data
Evidence for a temperature-induced spin-state transition of Co3+ in La2-xSrxCoO4
We study the magnetic susceptibility of mixed-valent La2-xSrxCoO4 single
crystals in the doping range of 0.5<= x <= 0.8 for temperatures up to 1000 K.
The magnetism below room temperature is described by paramagnetic Co2+ in the
high-spin state and by Co3+ in the non-magnetic low-spin state. Above room
temperature, an increase in susceptibility compared to the behavior expected
from Co2+ is seen, which we attribute to a spin-state transition of Co3+. The
susceptibility is analyzed by comparison to full-multiplet calculations for the
thermal population of the high- and intermediate-spin states of Co3+
- …