Evolution and stabilization of subnanometric metal species in confined space by in situ TEM

Understanding the behavior and dynamic structural transformation of subnanometric metal species under reaction conditions will be helpful for understanding catalytic phenomena and for developing more efficient and stable catalysts based on single atoms and clusters. In this work, the evolution and stabilization of subnanometric Pt species confined in MCM-22 zeolite has been studied by in situ transmission electron microscopy (TEM). By correlating the results from in situ TEM studies and the results obtained in a continuous fix-bed reactor, it has been possible to delimitate the factors that control the dynamic agglomeration and redispersion behavior of metal species under reaction conditions. The dynamic reversible transformation between atomically dispersed Pt species and clusters/nanoparticles during CO oxidation at different temperatures has been elucidated. It has also been confirmed that subnanometric Pt clusters can be stabilized in MCM-22 crystallites during NO reduction with CO and H2

Levitation of quantum Hall critical states in a lattice model with spatially correlated disorder

The fate of the current carrying states of a quantum Hall system is considered in the situation when the disorder strength is increased and the transition from the quantum Hall liquid to the Hall insulator takes place. We investigate a two-dimensional lattice model with spatially correlated disorder potentials and calculate the density of states and the localization length either by using a recursive Green function method or by direct diagonalization in connection with the procedure of level statistics. From the knowledge of the energy and disorder dependence of the localization length and the density of states (DOS) of the corresponding Landau bands, the movement of the current carrying states in the disorder--energy and disorder--filling-factor plane can be traced by tuning the disorder strength. We show results for all sub-bands, particularly the traces of the Chern and anti-Chern states as well as the peak positions of the DOS. For small disorder strength $W$ we recover the well known weak levitation of the critical states, but we also reveal, for larger $W$, the strong levitation of these states across the Landau gaps without merging. We find the behavior to be similar for exponentially, Gaussian, and Lorentzian correlated disorder potentials. Our study resolves the discrepancies of previously published work in demonstrating the conflicting results to be only special cases of a general lattice model with spatially correlated disorder potentials. To test whether the mixing between consecutive Landau bands is the origin of the observed floating, we truncate the Hilbert space of our model Hamiltonian and calculate the behavior of the current carrying states under these restricted conditions.Comment: 10 pages, incl. 13 figures, accepted for publication in PR

Effects of quantum space time foam in the neutrino sector

We discuss violations of CPT and quantum mechanics due to interactions of neutrinos with space-time quantum foam. Neutrinoless double beta decay and oscillations of neutrinos from astrophysical sources (supernovae, active galactic nuclei) are analysed. It is found that the propagation distance is the crucial quantity entering any bounds on EHNS parameters. Thus, while the bounds from neutrinoless double beta decay are not significant, the data of the supernova 1987a imply a bound being several orders of magnitude more stringent than the ones known from the literature. Even more stringent limits may be obtained from the investigation of neutrino oscillations from active galactic nuclei sources, which have an impressive potential for the search of quantum foam interactions in the neutrino sector.Comment: 5 page

Fredholm Indices and the Phase Diagram of Quantum Hall Systems

The quantized Hall conductance in a plateau is related to the index of a Fredholm operator. In this paper we describe the generic ``phase diagram'' of Fredholm indices associated with bounded and Toeplitz operators. We discuss the possible relevance of our results to the phase diagram of disordered integer quantum Hall systems.Comment: 25 pages, including 7 embedded figures. The mathematical content of this paper is similar to our previous paper math-ph/0003003, but the physical analysis is ne

Quantifying the levitation picture of extended states in lattice models

The behavior of extended states is quantitatively analyzed for two dimensional lattice models. A levitation picture is established for both white-noise and correlated disorder potentials. In a continuum limit window of the lattice models we find simple quantitative expressions for the extended states levitation, suggesting an underlying universal behavior. On the other hand, these results point out that the Quantum Hall phase diagrams may be disorder dependent.Comment: 5 pages, submitted to PR

Organization of atomic bond tensions in model glasses

In order to understand whether internal stresses in glasses are correlated or randomly distributed, we study the organization of atomic bond tensions (normal forces between pairs of atoms). Measurements of the invariants of the atomic bond tension tensor in simulated 2D and 3D binary Lennard-Jones glasses, reveal new and unexpected correlations and provide support for Alexander's conjecture about the non-random character of internal stresses in amorphous solids

Correlated electron emission in laser-induced nonsequence double ionization of Helium

In this paper, we have investigated the correlated electron emission of the nonsequence double ionization (NSDI) in an intense linearly polarized field. The theoretical model we employed is the semiclassical rescattering model, the model atom we used is the helium. We find a significant correlation between magnitude and direction of the momentum of two emission electrons, and give a good explanation for this striking phenomenon by observing the classical collisional trajectories. We argue that this correlation phenomenon is universal in NSDI process, as revealed by the recent experiment on the argon.Comment: 4 pages, 3 figures, accepted for publication in Phys. Rev.

Search for High-Spin Stretched States in 206-Pb

This research was sponsored by the National Science Foundation Grant NSF PHY-931478

High Spin States in the (p,t) Reaction

This research was sponsored by the National Science Foundation Grant NSF PHY-931478

Magnetization and Level Statistics at Quantum Hall Liquid-Insulator Transition in the Lattice Model

Statistics of level spacing and magnetization are studied for the phase diagram of the integer quantum Hall effect in a 2D finite lattice model with Anderson disorder.Comment: 4 pages, 6 figure