20 research outputs found
INFRARED SPECTRA OF MAGNESIUM HALIDES IN SOLID ARGON AND KRYPTON MATRICES
Author Institution: Space Science Laboratory, General Electric Company; Cryogenic Laboratory, The Ohio State UniversityThe infrared absorption spectra of magnesium fluoride and magnesium chloride isolated in solid krypton and argon matrices have been investigated from . The molecules were generated in a high temperature cell and trapped at liquid and He temperatures. The spectrum of indicates that the apex angle F---Mg---F is . Complete assignment and other details will be discussed
INFRARED ABSORPTION SPECTRA OF LiO, AND IN SOLID KRYPTON MATRICES
Author Institution: Cryogenic Laboratory, The Ohio State University; Space Science Laboratory, General Electric company; Molecular Spectroscopy Section, National Bureau of Standards“The infrared absorption spectra of LiO, AND isolated in solid krypton matrices have been investigated from . The molecules were generated by vaporising solid in it high temperature effusion cell and trapped in solid krypton matrices at approximately and . The spectrum indicates that is almost linear and is rhombic with an angle of at Li atom. On the basis of ionic model the equilibrium angle is found to be . The similarity of Lithium Oxide dimer to Lithium Chloride dimer, along with other details will be discussed.