809 research outputs found
Numerical simulation of the upward propagation of a flame in a vertical tube filled with a very lean mixture.
Upwardpropagation of a premixed flame in averticaltubefilled with a very leanmixture is simulated numerically using a single irreversible Arrhenius reaction model with infinitely high activation energy. In the absence of heat losses and preferential diffusion effects, a curved flame with stationary shape and velocity close to those of an open bubble ascending in the same tube is found for values of the fuel mass fraction above a certain minimum that increases with the radius of the tube, while the numerical computations cease to converge to a stationary solution below this minimum mass fraction. The vortical flow of the gas behind the flame and in its transport region is described for tubes of different radii. It is argued that this flow may become unstable when the fuel mass fraction is decreased, and that this instability, together with the flame stretch due to the strong curvature of the flame tip in narrow tubes, may be responsible for the minimum fuel mass fraction. Radiation losses and a Lewis number of the fuel slightly above unity decrease the final combustion temperature at the flame tip and increase the minimum fuel mass fraction, while a Lewis number slightly below unity has the opposite effect
Characterization and wear performance of boride phases over tool steel substrates
This research work was conducted to characterize boride phases, obtained from the powder-pack process, on AISI H13 and D2 steel substrates, and investigate their tribological behavior. The boriding was developed at a temperature of 1273âK with an exposure time of 8âh. X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were conducted on the borided material to characterize the presence of the FeB, Fe2B, and CrB phases and the distribution of heavy elements on the surface of the substrates. The adherence of the boride layers was evaluated, in a qualitative form, through the Daimler-Benz Rockwell-C indentation technique. Sliding wear tests were then performed using a reciprocating wear test machine. All tests were conducted in dry conditions at room temperature. A frequency of 10âHz and 15-mm sliding distance were used. The applied Hertzian pressure was 2.01âGPa. Scanning electron microscopy was used to observe and analyze the wear mechanisms. Additionally, the variation of the friction coefficient versus the number of cycles was obtained. Experimental results showed that the characteristic wear mechanism for the borided surface was plastic deformation and mild abrasive wear; for unborided substrates, cracking and spalling were observed
Strong duality in conic linear programming: facial reduction and extended duals
The facial reduction algorithm of Borwein and Wolkowicz and the extended dual
of Ramana provide a strong dual for the conic linear program in the absence of any constraint qualification. The facial
reduction algorithm solves a sequence of auxiliary optimization problems to
obtain such a dual. Ramana's dual is applicable when (P) is a semidefinite
program (SDP) and is an explicit SDP itself. Ramana, Tuncel, and Wolkowicz
showed that these approaches are closely related; in particular, they proved
the correctness of Ramana's dual using certificates from a facial reduction
algorithm.
Here we give a clear and self-contained exposition of facial reduction, of
extended duals, and generalize Ramana's dual:
-- we state a simple facial reduction algorithm and prove its correctness;
and
-- building on this algorithm we construct a family of extended duals when
is a {\em nice} cone. This class of cones includes the semidefinite cone
and other important cones.Comment: A previous version of this paper appeared as "A simple derivation of
a facial reduction algorithm and extended dual systems", technical report,
Columbia University, 2000, available from
http://www.unc.edu/~pataki/papers/fr.pdf Jonfest, a conference in honor of
Jonathan Borwein's 60th birthday, 201
A temperate former West Antarctic ice sheet suggested by an extensive zone of bed channels
Several recent studies predict that the West Antarctic Ice Sheet will become increasingly unstable under warmer conditions. Insights on such change can be assisted through investigations of the subglacial landscape, which contains imprints of former ice-sheet behavior. Here, we present radio-echo sounding data and satellite imagery revealing a series of ancient large sub-parallel subglacial bed channels preserved in the region between the Möller and Foundation Ice Streams, West Antarctica. We suggest that these newly recognized channels were formed by significant meltwater routed along the icesheet bed. The volume of water required is likely substantial and can most easily be explained by water generated at the ice surface. The Greenland Ice Sheet today exemplifies how significant seasonal surface melt can be transferred to the bed via englacial routing. For West Antarctica, the Pliocene (2.6â5.3 Ma) represents the most recent sustained period when temperatures could have been high enough to generate surface melt comparable to that of present-day Greenland. We propose, therefore, that a temperate ice sheet covered this location during Pliocene warm periods
Ab initio study of the beta$-tin->Imma->sh phase transitions in silicon and germanium
We have investigated the structural sequence of the high-pressure phases of
silicon and germanium. We have focussed on the cd->beta-tin->Imma->sh phase
transitions. We have used the plane-wave pseudopotential approach to the
density-functional theory implemented within the Vienna ab-initio simulation
package (VASP). We have determined the equilibrium properties of each structure
and the values of the critical parameters including a hysteresis effect at the
phase transitions. The order of the phase transitions has been obtained
alternatively from the pressure dependence of the enthalpy and of the internal
structure parameters. The commonly used tangent construction is shown to be
very unreliable. Our calculations identify a first-order phase transition from
the cd to the beta-tin and from the Imma to the sh phase, and they indicate the
possibility of a second-order phase-transition from the beta-tin to the Imma
phase. Finally, we have derived the enthalpy barriers between the phases.Comment: 12 pages, 16 figure
Coastal squeeze on temperate reefs: Long-term shifts in salinity, water quality, and oyster-associated communities
Foundation species, such as mangroves, saltmarshes, kelps, seagrasses, and oysters, thrive within suitable environmental envelopes as narrow ribbons along the landâsea margin. Therefore, these habitat-forming species and resident fauna are sensitive to modified environmental gradients. For oysters, many estuaries impacted by sea-level rise, channelization, and municipal infrastructure are experiencing saltwater intrusion and water-quality degradation that may alter reef distributions, functions, and services. To explore decadal-scale oysterâreef community patterns across a temperate estuary in response to environmental change, we resampled reefs in the Newport River Estuary (NRE) during 2013â2015 that had previously been studied during 1955â1956. We also coalesced historical NRE reef distribution (1880sâ2015), salinity (1913â2015), and water-quality-driven shellfish closure boundary (1970sâ2015) data to document environmental trends that could influence reef ecology and service delivery. Over the last 60â120 years, the entire NRE has shifted toward higher salinities. Consequently, oysterâreef communities have become less distinct across the estuary, manifest by 20%â27% lower species turnover and decreased faunal richness among NRE reefs in the 2010s relative to the 1950s. During the 2010s, NRE oysterâreef communities tended to cluster around a euhaline, intertidal-reef type more so than during the 1950s. This followed faunal expansions farther up estuary and biological degradation of subtidal reefs as NRE conditions became more marine and favorable for aggressive, reef-destroying taxa. In addition to these biological shifts, the area of suitable bottom on which subtidal reefs persist (contracting due to up-estuary intrusion of marine waters) and support human harvest (driven by water quality, eroding from up-estuary) has decreased by >75% since the natural history of NRE reefs was first explored. This âcoastal squeezeâ on harvestable subtidal oysters (reduced from a 4.5-km to a 0.75-km envelope along the NRE's main axis) will likely have consequences regarding the economic incentives for future oyster conservation, as well as the suite of services delivered by remaining shellfish reefs (e.g., biodiversity maintenance, seafood supply). More broadly, these findings exemplify how âsqueezeâ may be a pervasive concern for biogenic habitats along terrestrial or marine ecotones during an era of intense global change
Vibrational Properties of Nanoscale Materials: From Nanoparticles to Nanocrystalline Materials
The vibrational density of states (VDOS) of nanoclusters and nanocrystalline
materials are derived from molecular-dynamics simulations using empirical
tight-binding potentials. The results show that the VDOS inside nanoclusters
can be understood as that of the corresponding bulk system compressed by the
capillary pressure. At the surface of the nanoparticles the VDOS exhibits a
strong enhancement at low energies and shows structures similar to that found
near flat crystalline surfaces. For the nanocrystalline materials an increased
VDOS is found at high and low phonon energies, in agreement with experimental
findings. The individual VDOS contributions from the grain centers, grain
boundaries, and internal surfaces show that, in the nanocrystalline materials,
the VDOS enhancements are mainly caused by the grain-boundary contributions and
that surface atoms play only a minor role. Although capillary pressures are
also present inside the grains of nanocrystalline materials, their effect on
the VDOS is different than in the cluster case which is probably due to the
inter-grain coupling of the modes via the grain-boundaries.Comment: 10 pages, 7 figures, accepted for publication in Phys. Rev.
Optical properties of structurally-relaxed Si/SiO superlattices: the role of bonding at interfaces
We have constructed microscopic, structurally-relaxed atomistic models of
Si/SiO superlattices. The structural distortion and oxidation-state
characteristics of the interface Si atoms are examined in detail. The role
played by the interface Si suboxides in raising the band gap and producing
dispersionless energy bands is established. The suboxide atoms are shown to
generate an abrupt interface layer about 1.60 \AA thick. Bandstructure and
optical-absorption calculations at the Fermi Golden rule level are used to
demonstrate that increasing confinement leads to (a) direct bandgaps (b) a blue
shift in the spectrum, and (c) an enhancement of the absorption intensity in
the threshold-energy region. Some aspects of this behaviour appear not only in
the symmetry direction associated with the superlattice axis, but also in the
orthogonal plane directions. We conclude that, in contrast to Si/Ge, Si/SiO
superlattices show clear optical enhancement and a shift of the optical
spectrum into the region useful for many opto-electronic applications.Comment: 11 pages, 10 figures (submitted to Phys. Rev. B
Ecological Invasion, Roughened Fronts, and a Competitor's Extreme Advance: Integrating Stochastic Spatial-Growth Models
Both community ecology and conservation biology seek further understanding of
factors governing the advance of an invasive species. We model biological
invasion as an individual-based, stochastic process on a two-dimensional
landscape. An ecologically superior invader and a resident species compete for
space preemptively. Our general model includes the basic contact process and a
variant of the Eden model as special cases. We employ the concept of a
"roughened" front to quantify effects of discreteness and stochasticity on
invasion; we emphasize the probability distribution of the front-runner's
relative position. That is, we analyze the location of the most advanced
invader as the extreme deviation about the front's mean position. We find that
a class of models with different assumptions about neighborhood interactions
exhibit universal characteristics. That is, key features of the invasion
dynamics span a class of models, independently of locally detailed demographic
rules. Our results integrate theories of invasive spatial growth and generate
novel hypotheses linking habitat or landscape size (length of the invading
front) to invasion velocity, and to the relative position of the most advanced
invader.Comment: The original publication is available at
www.springerlink.com/content/8528v8563r7u2742
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