Potential platinum DNA-Metallointercalators : synthesis, characterisation and 1H NMR studies on [Pt(diimine)(N,N-di(n-butyl)-N'-acylthioureato)]+PF6 complexes in solution

Summary in English.Includes bibliographical references.A series of mixed-ligand [Pt(diimine)(N,N-di(n-butyl)-N'-acylthioureato)fPF6- complexes has been synthesised and fully characterised (where diimine is: 1,10 phenanthroline; 4,7-diphenyl-1,10- phenanthroline; 2,2'-bipyridyl; 4,4'-dimethyl-2,2'-bipyridyl and 4,4'-di-tert-butyl-2,2'-bipyridyl and acyl is: benzoyl or naphthoyl)

ECONOMIC INSIGHTS INTO THE SITING PROBLEM: AN APPLICATION OF THE EXPECTED UTILITY MODEL

Despite the generally recognized need for facilities such as power plants, landfills, prisons, and medical laboratories, finding host sites has become extremely difficult. This study uses the expected utility (EU) model to explain individiuals' preferences in the hypothetical case of siting a municipal solid waste composting facility. The three principal factors which EU theory prescribes would affect the decision process- benefits of the proposed facility, losses from the facility, and the (perceived) probability of various scenarios occurring- embodied by the variables in a multinomial logit model explain a substantial amount of the variation in siting decisions.Public Economics,

A Private Underworld: The Naked Body in Law and Society

In general, the literature on privacy stresses, quite naturally, our right to keep things private, or to make our own decisions. The individual, the citizen, is the center of gravity. There is a great deal of material on the limits of privacy, on threats to privacy, and the like. In this Article, the authors want to discuss what one might call mandatory privacy: those aspects of life that we are required to keep secret, hidden, or private, the things that we must keep private, whether we want to or not. This is a subject that has been mostly, though not entirely, ignored in the privacy literature. The authors conclude that there is no longer an ironclad rule that the body, or at least the private parts, have to remain that way: private. It has become a matter of choice. Forced bodily privacy has declined; now it is much more a matter for each person to decide, although there are still strong rules about behavior that seems threatening, abusive or pathological

CMBPol Mission Concept Study: A Mission to Map our Origins

Quantum mechanical metric fluctuations during an early inflationary phase of the universe leave a characteristic imprint in the polarization of the cosmic microwave background (CMB). The amplitude of this signal depends on the energy scale at which inflation occurred. Detailed observations by a dedicated satellite mission (CMBPol) therefore provide information about energy scales as high as $10^{15}$ GeV, twelve orders of magnitude greater than the highest energies accessible to particle accelerators, and probe the earliest moments in the history of the universe. This summary provides an overview of a set of studies exploring the scientific payoff of CMBPol in diverse areas of modern cosmology, such as the physics of inflation, gravitational lensing and cosmic reionization, as well as foreground science and removal .Comment: 6 pages, 3 figure

Shift schedule, work-family relationships, marital communication, job satisfaction and health among transport service shift workers

Objectives: Existing research has documented that shiftwork consequences may depend on the shift system parameters. Fast rotating systems (1-3 shifts of the same kind in a row) and day work have been found to be less disruptive biologically and socially than slower rotating systems and afternoon and night work. The aim of this study was to compare day workers and shift workers of different systems in terms of rotation speed and shifts worked with regard to work-family and family-work positive and negative spillover, marital communication style, job satisfaction and health. Material and Methods: Employees (N = 168) of the maintenance workshops of transportation service working different shift systems (day shift, weekly rotating 2 and 3‑shift system, and fast rotating 3-shift system) participated in the study. They completed the Work-Family Spillover Questionnaire, Marital Communication Questionnaire, Minnesota Job Satisfaction Questionnaire and the Physical Health Questionnaire (a part of the Standard Shiftwork Index). Results: The workers of quicker rotating 3-shift systems reported significantly higher scores of family-to-work facilitation (F(3, 165) = 4.175, p = 0.007) and a higher level of constructive style of marital communication (Engagement F(3, 165) = 2.761, p = 0.044) than the workers of slower rotating 2-shift systems. There were no differences between the groups of workers with regard to health and job satisfaction. Conclusions: A higher level of work–family facilitation and a more constructive style of marital communication were found among the workers of faster rotating 3-shift system when compared to the workers of a slower rotating 2-shift system (afternoon, night). This may indicate that the fast rotating shift system in contrary to the slower rotating one is more friendly for the work and family domains and for the relationship between them