Interaction between graphene and SiO2 surface

With first-principles DFT calculations, the interaction between graphene and SiO2 surface has been analyzed by constructing the different configurations based on {\alpha}-quartz and cristobalite structures. The single layer graphene can stay stably on SiO2 surface is explained based on the general consideration of configuration structures of SiO2 surface. It is also found that the oxygen defect in SiO2 surface can shift the Fermi level of graphene down which opens out the mechanism of hole-doping effect of graphene absorbed on SiO2 surface observed in experiments.Comment: 17 pages, 7 figure

A low-bandgap dimeric porphyrin molecule for 10% efficiency solar cells with small photon energy loss

Dimeric porphyrin molecules have great potential as donor materials for high performance bulk heterojunction organic solar cells (OSCs). Recently reported dimeric porphyrins bridged by ethynylenes showed power conversion efficiencies (PCEs) of more than 8%. In this study, we design and synthesize a new conjugated dimeric D-A porphyrin ZnP2BT-RH, in which the two porphyrin units are linked by an electron accepting benzothiadiazole (BT) unit. The introduction of the BT unit enhances the electron delocalization, resulting in a lower highest occupied molecular orbital (HOMO) energy level and an increased molar extinction coefficient in the near-infrared (NIR) region. The bulk heterojunction solar cells with ZnP2BT-RH as the donor material exhibit a high PCE of up to 10% with a low energy loss (Eloss) of only 0.56 eV. The 10% PCE is the highest for porphyrin-based OSCs with a conventional structure, and this Eloss is also the smallest among those reported for small molecule-based OSCs with a PCE higher than 10% to date

Dissipative chaotic scattering

We show that weak dissipation, typical in realistic situations, can have a metamorphic consequence on nonhyperbolic chaotic scattering in the sense that the physically important particle-decay law is altered, no matter how small the amount of dissipation. As a result, the previous conclusion about the unity of the fractal dimension of the set of singularities in scattering functions, a major claim about nonhyperbolic chaotic scattering, may not be observable.Comment: 4 pages, 2 figures, revte

Resummation Effects in Vector-Boson and Higgs Associated Production

Fixed-order QCD radiative corrections to the vector-boson and Higgs associated production channels, pp -> VH (V=W, Z), at hadron colliders are well understood. We combine higher order perturbative QCD calculations with soft-gluon resummation of both threshold logarithms and logarithms which are important at low transverse momentum of the VH pair. We study the effects of both types of logarithms on the scale dependence of the total cross section and on various kinematic distributions. The next-to-next-to-next-to-leading logarithmic (NNNLL) resummed total cross sections at the LHC are almost identical to the fixed-order perturbative next-to-next-to-leading order (NNLO) rates, indicating the excellent convergence of the perturbative QCD series. Resummation of the VH transverse momentum (p_T) spectrum provides reliable results for small values of p_T and suggests that implementing a jet-veto will significantly decrease the cross sections.Comment: 25 pages, references update

Parity Violation in Neutrino Transport and the Origin of Pulsar Kicks

In proto-neutron stars with strong magnetic fields, the neutrino-nucleon scattering/absorption cross sections depend on the direction of neutrino momentum with respect to the magnetic field axis, a manifestation of parity violation in weak interactions. We study the deleptonization and thermal cooling (via neutrino emission) of proto-neutron stars in the presence of such asymmetric neutrino opacities. Significant asymmetry in neutrino emission is obtained due to multiple neutrino-nucleon scatterings. For an ordered magnetic field threading the neutron star interior, the fractional asymmetry in neutrino emission is about $0.006 (B/10^{14}G)$, corresponding to a pulsar kick velocity of about $200 (B/10^{14}G)$ km/s for a total radiated neutrino energy of $3\times 10^{53}$ erg.Comment: AASTeX, 10 pages including 2 ps figures; ApJ Letter in press (March 10, 1998). Shortened to agree with the published versio

Landing and catalytic characterization of individual nanoparticles on electrode surfaces

We demonstrate a novel and versatile pipet-based approach to study the landing of individual nanoparticles (NPs) on various electrode materials without any need for encapsulation or fabrication of complex substrate electrode structures, providing great flexibility with respect to electrode materials. Because of the small electrode area defined by the pipet dimensions, the background current is low, allowing for the detection of minute current signals with good time resolution. This approach was used to characterize the potential-dependent activity of Au NPs and to measure the catalytic activity of a single NP on a TEM grid, combining electrochemical and physical characterization at the single NP level for the first time. Such measurements open up the possibility of studying the relation between the size, structure and activity of catalyst particles unambiguously