301 research outputs found
Management of natural resources through automatic cartographic inventory
The author has identified the following significant results. Significant results of the ARNICA program (February - December 1973) were: (1) The quantitative processing of ERTS-1 data was developed along two lines: the study of geological structures and lineaments of Spanish Catalonia, and the phytogeographical study of the forest region of the Landes of Gascony (France). In both cases it is shown that the ERTS-1 imagery can be used in establishing zonings of equal quantitative interpretation value. (2) In keeping with the operational transfer program proposed in previous reports between exploration of the imagery and charting of the object, a precise data processing method was developed, concerning more particularly the selection of digital equidensity samples computer display and rigorous referencing
Ion pump activity generates fluctuating electrostatic forces in biomembranes
We study the non-equilibrium dynamics of lipid membranes with proteins that
actively pump ions across the membrane. We find that the activity leads to a
fluctuating force distribution due to electrostatic interactions arising from
variation in dielectric constant across the membrane. By applying a multipole
expansion we find effects on both the tension and bending rigidity dominated
parts of the membranes fluctuation spectrum. We discuss how our model compares
with previous studies of force-multipole models.Comment: 6 pages, 2 figures, to appear in EP
SURFATM-NH3: a model combining the surface energy balance and bi-directional exchanges of ammonia applied at the field scale
A new biophysical model SURFATM-NH3, simulating the ammonia (NH<sub>3</sub>) exchange between terrestrial ecosystems and the atmosphere is presented. SURFATM-NH3 consists of two coupled models: (i) an energy budget model and (ii) a pollutant exchange model, which distinguish the soil and plant exchange processes. The model describes the exchanges in terms of adsorption to leaf cuticles and bi-directional transport through leaf stomata and soil. The results of the model are compared with the flux measurements over grassland during the GRAMINAE Integrated Experiment at Braunschweig, Germany. The dataset of GRAMINAE allows the model to be tested in various meteorological and agronomic conditions: prior to cutting, after cutting and then after the application of mineral fertilizer. The whole comparison shows close agreement between model and measurements for energy budget and ammonia fluxes. The major controls on the ground and plant emission potential are the physicochemical parameters for liquid-gas exchanges which are integrated in the compensation points for live leaves, litter and the soil surface. Modelled fluxes are highly sensitive to soil and plant surface temperatures, highlighting the importance of accurate estimates of these terms. The model suggests that the net flux depends not only on the foliar (stomatal) compensation point but also that of leaf litter. SURFATM-NH3 represents a comprehensive approach to studying pollutant exchanges and its link with plant and soil functioning. It also provides a simplified generalised approach (SVAT model) applicable for atmospheric transport models
Temporal variability in bioassays of the stomatal ammonia compensation point in relation to plant and soil nitrogen parameters in intensively managed grassland
The exchange of ammonia between crop canopies and the atmosphere depends on a range of plant parameters and climatic conditions. However, little is known about effects of management factors. We have here investigated the stomatal ammonia compensation point in response to cutting and fertilization of a grass sward dominated by Lolium perenne. Tall grass had a very low NH3 compensation point (around 1 nmol mol−1), reflecting the fact that leaf nitrogen (N) concentration was very low. During re-growth after cutting, leaf tissue concentrations of NO3-, NH4+, soluble N and total N increased along with apoplastic NH4+ concentrations. In contrast, apoplastic pH decreased resulting in largely unaltered NH3 compensation points. Nitrogen fertilization one week after cutting caused the apoplastic NH4+ concentration of the newly emerging leaves to increase dramatically. The NH3 compensation point peaked between 15 and 25 nmol mol−1 the day after the fertiliser was applied and thereafter decreased over the following 10 days until reaching the same level as before fertilisation. Ammonium concentrations in leaf apoplast, bulk tissue and litter were positively correlated (P=0.001) throughout the experimental period. Bulk tissue NH4+ concentrations, total plant N and soil NH4+ concentrations also showed a positive correlation. A very high potential for NH3 emission was shown by the plant litter
Concentrations and fluxes of isoprene and oxygenated VOCs at a French Mediterranean oak forest
The CANOPEE project aims to better understand the biosphere–atmosphere exchanges of biogenic volatile organic compounds (BVOCs) in the case of Mediterranean ecosystems and the impact of in-canopy processes on the atmospheric chemical composition above the canopy. Based on an intensive field campaign, the objective of our work was to determine the chemical composition of the air inside a canopy as well as the net fluxes of reactive species between the canopy and the boundary layer. Measurements were carried out during spring 2012 at the field site of the Oak Observatory of the Observatoire de Haute Provence (O3HP) located in the southeast of France. The site is a forest ecosystem dominated by downy oak, Quercus pubescens Willd., a typical Mediterranean species which features large isoprene emission rates. Mixing ratios of isoprene, its degradation products methylvinylketone (MVK) and methacrolein (MACR) and several other oxygenated VOC (OxVOC) were measured above the canopy using an online proton transfer reaction mass spectrometer (PTR-MS), and fluxes were calculated by the disjunct eddy covariance approach. The O3HP site was found to be a very significant source of isoprene emissions, with daily maximum ambient concentrations ranging between 2–16 ppbv inside and 2–5 ppbv just above the top of the forest canopy. Significant isoprene fluxes were observed only during daytime, following diurnal cycles with midday net emission fluxes from the canopy ranging between 2.0 and 9.7 mg m−2 h1. Net isoprene normalized flux (at 30 °C, 1000 μmol quanta m−2 s−1) was estimated at 7.4 mg m−2 h−1. Evidence of direct emission of methanol was also found exhibiting maximum daytime fluxes ranging between 0.2 and 0.6 mg m−2 h−1, whereas flux values for monoterpenes and others OxVOC such as acetone and acetaldehyde were below the detection limit.
The MVK+MACR-to-isoprene ratio provided useful information on the oxidation of isoprene, and is in agreement with recent findings proposing weak production yields of MVK and MACR, in remote forest regions where the NOx concentrations are low. In-canopy chemical oxidation of isoprene was found to be weak and did not seem to have a significant impact on isoprene concentrations and fluxes above the canopy
Agroforestry systems for ammonia air quality management
Air pollution can lead to environmental impacts. Over the past decades there have been some success stories reducing pollutant emission, namely sulphur dioxide (SO2). However, impacts on ecosystems from atmospheric nitrogen (N) pollution are still seen as a major threat for European biodiversity. Across Europe over 70% of Natura 2000 sites are at risk for eutrophication with over 70% of the Natura 2000 area in Europe (EU28( exceeding critical loads for nutrient nitrogen deposition. Agricultural ammonia is a key contributor to the threat to these sites due to the close proximity of agricultural activities and protected sites. Source attribution modelling using an atmospheric transport model showed that agricultural livestock production in the UK is the dominant nitrogen source for N disposition across the UK Natura 2000 network. Nearly 90% of all sites had livestock as their dominant source, contributing 32% of the total nitrogen deposition across the whole network. 76% of all Special Areas of Conservation (SAC) sites exceeded their critical load for nutrient nitrogen, representing 74% of the entire SAC area. The extent of exceedance is also notable with many sites experiencing depositions of >50 kg N/ha/yr over the critical load. the situation for acidity critical load exceedance is less sever, by 51% of sites are still exeeded. Legislation to regulate pollutant emissions to air and protect biodiversity are often not integrated, and there has been no common European approach for determining the impacts of nitrogen deposition on individual Natura sites, or on conservation status. Off-site sources of air pollution present difficulties in assessing and attributing impacts, because deposition can result from local sources (1-2 km), or very far away sources (>1000 kms). Managing nitrogen losses on the farm and improving the efficient use of nitrogen are key components for overall reduction in NH3 emissions. Many nitrogen management options are available to abate ammonia from agricultural activities. On the one hand, technical and management measures include controlling emissions from manure storage and spreading, livestock feeding strategies, and improving housing systems. Trees, on the other hand, are effective scavengers of both gaseous and particulate pollutants from the atmosphere, making tree belts potentially effective landscape features to support ammonia abatement strategies. Using a coupled deposition and turbulence model the recapture efficiency of tree planting around ammonia sources was estimated. Using different canopy structure scenarios, tree depths and differing leaf area density (LAD) and leaf are index (LAI) were adjusted for a main canopy and a backstop canopy. Recapture efficiency for ammonia ranged from 27% (trees planted around housing systems), up to 60% (under-story livestock silvopastoral systems). Practical recapture potential was set at 20% and 40% for housing and silvopastoral systems respectively. Model results from scaling up to national level suggest that tree planting in hot spot areas of ammonia emissions would lead to reduced N deposition on nearby sensitive habitats. Scenarios for on-farm emission control through tree planting showed national reductions in nitrogen deposition to semi-natural areas of 0.14% (0.2 kt N-NHx) to 2.2% (3.15 kt N-NHx). Scenarios mitigating emissions from cattle and pig housing yielded the highest reductions. The afforestation strategy showed national-scale emission reductions of 6% (8.4 kt N-NHx) to 11% (15.7 kt N-NHx) for 25% and 50% afforestation scenarios respectively. Increased capture by the planted trees also generated an added benefit of reducing long-range transport effects, including a decrease in wet deposition of up to 3.7 kt N-NHx (4.6%) and a decrease in export from the UK of up to 8.3 kt N-NHx (6.8%). Agroforestry measures for ammonia abatement were shown to be cost-effective for both planting downwind of housing and in silvopastoral systems, when costs to society were taken into account. Planting trees was also cost-effective from a climate change perspective. Comparing the cost per kg of NH3 abated showed that planting trees is a method of ammonia emission mitigation comparable with other (technical) measures. The costs for planting trees downwind of housing were calculated at €2.6-7.3/kg NH3. Agroforestry for ammonia abatement offers multiple benefits for the farmer and synergistic effects for society as a whole including i) carbon sequestration. ii) visibility screening around housing units, iii) imporved animal welfare for silvopastoral systems, iv) reducing critical load exceedance on protected sites, v) price advantage of 'woodland chick' productions, vi) supporting the Industrial Emission Directive (IED) requirements for emission reduction, vii) supporting national afforestation policies. The results of this work support the notion that in the emerging discussion about the values of ecosystem services and the role of nature-based solution to tackle persistent environmental challenges, tree planting has a large potential in rural and urban environments
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Influence of Dynamic Ozone Dry Deposition on Ozone Pollution
Identifying the contributions of chemistry and transport to observed ozone pollution using regional-to-global models relies on accurate representation of ozone dry deposition. We use a recently developed configuration of the NOAA GFDL chemistry-climate model - in which the atmosphere and land are coupled through dry deposition-to investigate the influence of ozone dry deposition on ozone pollution over northern midlatitudes. In our model, deposition pathways are tied to dynamic terrestrial processes, such as photosynthesis and water cycling through the canopy and soil. Small increases in winter deposition due to more process-based representation of snow and deposition to surfaces reduce hemispheric-scale ozone throughout the lower troposphere by 5-12 ppb, improving agreement with observations relative to a simulation with the standard configuration for ozone dry deposition. Declining snow cover by the end of the 21st-century tempers the previously identified influence of rising methane on winter ozone. Dynamic dry deposition changes summer surface ozone by -4 to +7 ppb. While previous studies emphasize the importance of uptake by plant stomata, new diagnostic tracking of depositional pathways reveals a widespread impact of nonstomatal deposition on ozone pollution. Daily variability in both stomatal and nonstomatal deposition contribute to daily variability in ozone pollution. Twenty-first century changes in summer deposition result from a balance among changes in individual pathways, reflecting differing responses to both high carbon dioxide (through plant physiology versus biomass accumulation) and water availability. Our findings highlight a need for constraints on the processes driving ozone dry deposition to test representation in regional-to-global models.Peer reviewe
Influence of Humidity on Microtribology of Vertically Aligned Carbon Nanotube Film
The aim of this study is to probe the influence of water vapor environment on
the microtribological properties of a forestlike vertically aligned carbon
nanotube (VACNT) film, deposited on a silicon (001) substrate by chemical vapor
deposition. Tribological experiments were performed using a gold tip under
relative humidity varying from 0 to 100%. Very low adhesion forces and high
friction coefficients of 0.6 to 1.3 resulted. The adhesion and friction forces
were independent of humidity, due probably to the high hydrophobicity of VACNT.
These tribological characteristics were compared to those of a diamond like
carbon (DLC) sample
Experience of Forced Sex and Subsequent Sexual, Drug, and Mental Health Outcomes: African American and Hispanic Women in the Southeastern United States
This cross-sectional study examined African American and Hispanic women’s (N = 1,509) self-reports of unwanted forced sex and its association with behavioral and mental health outcomes after the event
Reference procedures for the measurement of gaseous emissions from livestock houses and stores of animal manure.
In the ten years before the EMILI 2012 symposium, gaseous losses from animal farms became increasingly important in the m edia. The paradox of this tendency was the great number of publications, scientific or not, even though the emissions of most animal farms had never been measured. Therefor e, the development of reference tools to measure greenhouse gas and ammonia emissio ns was important. Such tools allow recognition and remuneration of the best pract ices and equipment. Accordingly, ADEME funded an international project associating several research and development organizations involved with the animal production chain. The project proposed an initial set of 18 procedures to measure ammonia and greenho use gas emissions from animal houses and manure stores. These were adapted to the diversity of animal farms found throughout the world. Some methods were compared duri ng a ?building? and a ?liquid manure? experiment. Results showed a high difference among methods (ca. 80%), much higher than the estimated uncertainty. Associat ing independent emission measurements, together with a mass balance of the system, is necessary for the reliability of further results. However, previously published references lack uncertainty estimates of measurements that conform to GUM 2008. In the coming years, this is one of the major concerns for measuring emission factor s. Uncertainty estimates should depend on the measurand (temporal: hourly, per batch, yearly; spatial: animal, house, national) and include the uncertainties associated with system representativity and temporal interpolation.Edited by Mélynda Hassouna and Nadine Guingand
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