14 research outputs found

    Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System

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    Herein we report a metal-free method for the direct anti-Markovnikov hydroamination of unsaturated amines. Irradiation of the amine substrates with visible light in the presence of catalytic quantities of easily synthesized 9-mesityl-10-methylacridinium tetrafluoroborate and thiophenol as a hydrogen atom donor furnished the nitrogen containing heterocycles with complete regio-control. Two examples of in termolecular anti-Markovnikov alkene hydroamination are also disclosed

    Highly Enantioselective Zirconium-Catalyzed Cyclization of Aminoalkenes

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    Mononuclear gold catalysts for the asymmetric intramolecular hydroamination of alkenes

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