14 research outputs found
Optically active heteroligand chelate complexes 4. The heteroligand chelates of copper with acetylacetone and aromatic amino acids in the solid phase and in solution
Ternary mixed-ligand copper(II) complexes with chiral aminophosphonic acids and amino acids
Copolymerization of propylene with 1-octene initiated by highly efficient isospecific metallocene catalytic systems
Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
Herein we report a metal-free method for the direct anti-Markovnikov hydroamination of unsaturated amines. Irradiation of the amine substrates with visible light in the presence of catalytic quantities of easily synthesized 9-mesityl-10-methylacridinium tetrafluoroborate and thiophenol as a hydrogen atom donor furnished the nitrogen containing heterocycles with complete regio-control. Two examples of in termolecular anti-Markovnikov alkene hydroamination are also disclosed
SERINE, THREONINE AND α-HYDROXYAMINE COORDINATION TO CUPRIC IONS BY HYDROXYL-OXYGEN-METAL BONDS
Mononuclear gold catalysts for the asymmetric intramolecular hydroamination of alkenes
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