Methanol as a tracer of fundamental constants

The methanol molecule CH3OH has a complex microwave spectrum with a large number of very strong lines. This spectrum includes purely rotational transitions as well as transitions with contributions of the internal degree of freedom associated with the hindered rotation of the OH group. The latter takes place due to the tunneling of hydrogen through the potential barriers between three equivalent potential minima. Such transitions are highly sensitive to changes in the electron-to-proton mass ratio, mu = m_e/m_p, and have different responses to mu-variations. The highest sensitivity is found for the mixed rotation-tunneling transitions at low frequencies. Observing methanol lines provides more stringent limits on the hypothetical variation of mu than ammonia observation with the same velocity resolution. We show that the best quality radio astronomical data on methanol maser lines constrain the variability of mu in the Milky Way at the level of |Delta mu/mu| < 28x10^{-9} (1sigma) which is in line with the previously obtained ammonia result, |Delta mu/mu| < 29x10^{-9} (1\sigma). This estimate can be further improved if the rest frequencies of the CH3OH microwave lines will be measured more accurately.Comment: 7 pages, 1 table, 1 figure. Accepted for publication in Ap

Sensitivity of the H3O+ inversion-rotational spectrum to changes in m_e/m_p

Quantum mechanical tunneling inversion transition in ammonia NH3 is actively used as a sensitive tool to study possible variations of the electron-to-proton mass ratio, mu = m_e/m_p. The molecule H3O+ has the inversion barrier significantly lower than that of NH3. Consequently, its tunneling transition occurs in the far-infrared (FIR) region and mixes with rotational transitions. Several such FIR and submillimiter transitions are observed from the interstellar medium in the Milky Way and in nearby galaxies. We show that the rest-frame frequencies of these transitions are very sensitive to the variation of mu, and that their sensitivity coefficients have different signs. Thus, H3O+ can be used as an independent target to test hypothetical changes in mu measured at different ambient conditions of high (terrestrial) and low (interstellar medium) matter densities. The environmental dependence of mu and coupling constants is suggested in a class of chameleon-type scalar field models - candidates to dark energy carrier.Comment: 8 pages, 2 figures, accepted to ApJ; v2: reformatted for ApJ and discussion of systematics significantly extende

Electric dipole moment of the electron in YbF molecule

Ab initio calculation of the hyperfine, P-odd, and P,T-odd constants for the YbF molecule was performed with the help of the recently developed technique, which allows to take into account correlations and polarization in the outercore region. The ground state electronic wave function of the YbF molecule is found with the help of the Relativistic Effective Core Potential method followed by the restoration of molecular four-component spinors in the core region of ytterbium in the framework of a non-variational procedure. Core polarization effects are included with the help of the atomic Many Body Perturbation Theory for Yb atom. For the isotropic hyperfine constant A, accuracy of our calculation is about 3% as compared to the experimental datum. The dipole constant Ad (which is much smaller in magnitude), though better than in all previous calculations, is still underestimated by almost 23%. Being corrected within a semiempirical approach for a perturbation of 4f-shell in the core of Yb due to the bond making, this error is reduced to 8%. Our value for the effective electric field on the unpaired electron is 4.9 a.u.=2.5E+10 V/cm.Comment: 7 pages, REVTE