34 research outputs found

    The Potential Role of Migratory Birds in the Spread of Tick-borne Infections in Siberia and the Russian Far East

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    AbstractFrom 2006 to 2011, in the Tomsk region (south of Western Siberia), eight species of pathogens were detected in birds and the ticks feeding on them: Tick-borne encephalitis virus (TBEV), West Nile virus (WNV), Borrelia spp., Rickettsia spp., Bartonella spp., Anaplasma spp., Ehrlichia spp., and Babesia spp. The identification of a number of strains of viruses and bacterial genovariants related geographically with the Russian Far East, Eastern Siberia, China and Japan and confirms the possibility of the role of birds in the spread of pathogens in the direction of Western Siberia and back. Most of the species that breed and migrate in Western Siberia are of Eastern origin and mostly fly for wintering to South-East Asia. Among these species in our samples, Phylloscopus proregulus was a carrier of both TBEV and Bartonella spp.; Luscinia calliope were infected with both TBEV and Borrelia, while Tarsiger cyanurus were infected with WNV

    Study on the microporous structure parameters of BEA type zeolites

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    The paper considers a series of zeolite materials used as catalysts. Since the formation of mesoporosity in a microporous matrix is one of the methods for increasing the efficiency of zeolite materials in catalysis, it is necessary to control their porous structure parameters. The effect of post-synthetic treatment with acid and alkali solutions on the specific surface area of zeolites of the BEA type has been studied. The method of low-temperature (at 77 K) adsorption of nitrogen vapors was used to determine the external specific surface area (excluding micropores) and the volume of micropores in the samples on a Sorbi device. It has been shown that modification of BEA-type zeolite with concentrated mineral acids leads to both a decrease in the volume of micropores and a decrease in the specific surface area. At the same time, it was established by the X-ray phase analysis that the treatment with concentrated acids does not lead to destruction of the crystal structure of zeolites. In the case of treatment with alkali solutions, the specific surface area of the samples increases and the volume of micropores sharply decreases

    Light conversion in thin films of mixtures of mesotetraphenylporphyrin and yttrium vanadate crystallites doped with erbium. I. Photovoltaic properties and structure

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    The optical and photovoltaic properties of two-component TPP–Yt0.95Er0.05VO4 films prepared by the spincoating method are for the first time studied. A 30% increase in the photovoltage (PV) of TPP: Yt0.95Er0.05VO4 = 3: 2 films on silicon carbide (SiC) supports as compared to TPP one-component films is observed. In contrast, for films on tin dioxide (SnO2) supports, the PV drops by 35–96% as the TPP content in the film decreases from 80 to 20%. The properties of the films are monitored by atomic force microscopy. The highest roughness of the films corresponds to a 40–60% TPP content. © 2016, Pleiades Publishing, Ltd

    Light conversion in thin films of mixtures of mesotetraphenylporphyrin and yttrium vanadate crystallites doped with erbium. I. Photovoltaic properties and structure

    No full text
    The optical and photovoltaic properties of two-component TPP–Yt0.95Er0.05VO4 films prepared by the spincoating method are for the first time studied. A 30% increase in the photovoltage (PV) of TPP: Yt0.95Er0.05VO4 = 3: 2 films on silicon carbide (SiC) supports as compared to TPP one-component films is observed. In contrast, for films on tin dioxide (SnO2) supports, the PV drops by 35–96% as the TPP content in the film decreases from 80 to 20%. The properties of the films are monitored by atomic force microscopy. The highest roughness of the films corresponds to a 40–60% TPP content. © 2016, Pleiades Publishing, Ltd

    Nickel(II) complexes with tripodal NNN ligands as homogenous and supported catalysts for ethylene oligomerization

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    Four new coordination compounds of nickel (II) with derivatives of N,N-bis(pyrazol-1-ylmethyl)propylamine were synthesized; their composition and structure were confirmed with IR-spectroscopy and elemental analysis. The structures of products 13 and 15 were unambiguously established in an X-ray diffraction study. Compounds 13 and 15 crystallize in the orthorhombic space groups Pna21 and P212121 correspondingly and represent a monomeric octahedral nickel complexes, that are typical for tridentate scorpion-type ligands. New method for immobilization of nickel complexes with derivatives of N,N-bis(pyrazol-1-ylmethyl)propylamine on silica gel modified with aminopropyl groups was proposed. The EXAFS/XANES analysis indicated that Ni atom in the supported complexes adopt almost octahedral geometry, being partly surrounded by nitrogen atoms from organic ligand and partly grafted to silica surface through silanol groups, with Br− in outer coordination sphere. Both the original and the supported complexes, when activated with Et2AlCl or Et3Al2Cl3, catalyze ethylene oligomerization with the predominant formation of butene isomers. Generally, the immobilized complexes show higher activity and better selectivity towards 1-butene formation. © 2018 Elsevier B.V
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