Nitrogen Oxides and Ozones from B-747 Measurements (NOXAR) during POLINAT 2 and SONEX: Overview and Case-Studies on Continental and Marine Convection

In the framework of the project POLINAT 2 (Pollution in the North Atlantic Flight Corridor) we measured NO(x) (NO and NO2) and ozone on 98 flights through the North Atlantic Flight Corridor (NAFC) with a fully automated system permanently installed aboard an in-service Swissair B-747 airliner in the period of August to November 1997. The averaged NO, concentrations both in the NAFC and at the U.S. east coast were similar to that measured in autumn 1995 with the same system. The patchy occurrence of NO(x), enhancements up to 3000 pptv over several hundred kilometers (plumes), predominately found over the U.S. east coast lead to a log-normal NO(x) probability density function. In three case-studies we examine the origins of such plumes by combining back-trajectories with brightness temperature enhanced (IR) satellite imagery, with lightning observations from the U.S. National Lightning Detection Network (NLDN) or with the Optical Transient Detector (OTD) satellite. For frontal activity above the continental U.S., we demonstrate that the location of NO(x) plumes can be well explained with maps of convective influence. For another case we show that the number of lightning flashes in a cluster of marine thunderstorms is proportional to the NO(x) concentrations observed several hundred kilometers downwind of the anvil outflows and suggest that lightning was the dominant source. From the fact that in autumn the NO, maximum was found several hundred kilometers off the U.S. east coast, it can be inferred that thunderstorms triggered over the warm Gulf Stream current are an important source for the regional upper tropospheric NO(x) budget in autumn