Municipal Solid Waste Used As Bioethanol Sources And Its Related Environmental Impacts

An investigation into the possibility of replacing the conventional biomass with biodegradable municipal solid waste, which provides an alternative solution for preventing the biodegradable fraction of municipal solid waste (BMSW) going into landfill required by EU Landfill Directives (1999/31/EC) was carried out. However, as every type of energy have some advantages as well as disadvantages. The use of BMSW as biomass sources for the production of bio-ethanol was investigated. The experimental results have shown that more than 90% of the cellulose from the waste can be converted to glucose which can be easily fermented to ethanol production. The potential impacts on related environmental issues, such as sustainable waste management, climate change, water issues, land use and biodiversity, are discussed. Sustainable waste management solutions are also discussed under different environmental, economic, and social scenarios

Method and Apparatus for Characterizing Microscale Formability of Thin Sheet Materials

A method of predicting sheet formability at a microscale level includes the steps of providing a grid pattern on a test sheet, bulging the test sheet to a hemispherical shape until a crack is initiated on the surface of the test sheet, detecting the initiation of the crack, acquiring two images of the surface adjacent to the crack and calculating surface strains on the test sheet

Method and Apparatus for Characterizing Microscale Formability of Thin Sheet Materials

A method of predicting sheet formability at a microscale level includes the steps of providing a grid pattern on a test sheet, bulging the test sheet to a hemispherical shape until a crack is initiated on the surface of the test sheet, detecting the initiation of the crack, acquiring two images of the surface adjacent to the crack and calculating surface strains on the test sheet

Uniaxially-Driven Controlled Biaxial Testing Fixture

A uniaxially-driven controlled biaxial testing fixture includes a base, a first coupler mounted to the base, and a load input drive rack mounted for linear movement with respect to the base. A second coupler and a first specimen grip are both mounted to the load input drive rack. Second, third and fourth specimen grips are also mounted for linear movement with respect to the base. First, second and third drive mechanisms connect the load input drive rack to the second, third and fourth specimen grips. Together the four specimen grips are oriented to provide biaxial application of force to a test specimen

Earth-abundant oxygen evolution catalysts coupled onto ZnO nanowire arrays for efficient photoelectrochemical water cleavage

ZnO has long been considered as a model UV-driven photoanode for photoelectrochemical water splitting, but its performance has been limited by fast charge-carrier recombination, extremely poor stability in aqueous solution, and slow kinetics of water oxidation. These issues were addressed by applying a strategy of optimization and passivation of hydrothermally grown 1D ZnO nanowire arrays. The length and diameter of bare ZnO nanowires were optimized by varying the growth time and precursor concentration to achieve optimal photoelectrochemical performance. The addition of earth-abundant cobalt phosphate (Co-Pi) and nickel borate (Ni-B) oxygen evolution catalysts onto ZnO nanowires resulted in substantial cathodic shifts in onset potential to as low as about 0.3 V versus the reversible hydrogen electrode (RHE) for Ni-B/ZnO, for which a maximum photocurrent density of 1.1 mA cm-2 at 0.9 V (vs. RHE) with applied bias photon-to-current efficiency of 0.4 % and an unprecedented near-unity incident photon-to-current efficiency at 370 nm. In addition the potential required for saturated photocurrent was dramatically reduced from 1.6 to 0.9 V versus RHE. Furthermore, the stability of these ZnO nanowires was significantly enhanced by using Ni-B compared to Co-Pi due to its superior chemical robustness, and it thus has additional functionality as a stable protecting layer on the ZnO surface. These remarkable enhancements in both photocatalytic activity and stability directly address the current severe limitations in the use of ZnO-based photoelectrodes for water-splitting applications, and can be applied to other photoanodes for efficient solar-driven fuel synthesis.China Scholarship Council (CSC File No. 201308060090). European Community Seventh Frame work Programme (4G-PHOTOCAT 309636). Qatar National Research Fund under its National Priorities Research Program Award No. NPRP 09-328-2-22.Scopu

Adsorptive removal of mercury from water by adsorbents derived from date pits

The current work presented here focuses on the remediation of mercury from water using modified low-cost materials. Modified date pits, low cost, minimal pretreatment steps and locally abundant agricultural waste materials were effectively employed as an adsorbent for remediating Hg2+ from aqueous media. Physical and chemical modification were developed such as thermal roasting (RDP), sulfur (SMRDP) and silane (SIMRDP) based modifications. Results showed that maximum adsorption by RDP was at pH 6, AC and both modifications was at pH 4. Furthermore, RDP has exothermic adsorption mechanism while AC, SMRDP, and SIMRDP have endothermic. All adsorbents except SIMRDP have spontaneous adsorption process. SEM analysis showed that the surface morphology of RDP was not significantly affected by different treatments while surface of AC was affected. The investigation for good adsorbents for Hg2+ uptake from different anthropogenic sources has been carried out by many investigators worldwide towards having a safe environment. In the current study, the highest Hg2+ adsorption of SMRDP was relatively high compared to other known adsorbents. - 2019, The Author(s).This paper was made possible by UREP grant # (17-066-1-004) from the Qatar national research fund (a member of Qatar foundation). The statements made herein are solely the responsibility of the author(s). The authors would like to thank the Environmental Science Center – Qatar University in analyzing mercury ions in the samples, and the Central Laboratory Unit at Qatar University for performing the FTIR and SEM for the samples. The authors would also thank Dr Basem Shomar, Ms. Fatma Fahraei, Ms. Mariem Safi, Ms. Sana Khan, Ms. Maymoona Ayesh, and Ms. Haya Alduroobi for their participation in this UREP project. Special thanks to Mr. M. Y. Ashfaq for his efforts in reading the final version of the manuscript. The publication of this article was funded by the Qatar National Library.Scopu

Influence of composite particle formation on the performance and economics of grit removal

Grit is routinely removed at the headworks of municipal wastewater treatment works to limit its onerous impact on downstream processes. Grit separation technologies are normally based on sedimentation of a homogeneous material (usually sand). However, in practice inorganic grit particles are likely to be combined with organic matter, such as fats oils and grease (FOG), producing a composite particle whose settling properties vary with the inorganic/organic content. A study of the impact of particle composition on its sedimentation has been conducted encompassing theoretical description (for particle settling in transitional flow), practical measurement and economic analysis. Practical measurement included sedimentation tests of homogeneous and composite particles along with characterisation of accumulated granular material sampled from actual municipal wastewater treatment works. The economic assessment was based on data from full-scale installations in the UK and US pertaining to remedial measures undertaken as a result of grit impacts, primarily accumulation in vessels and channels and damage of mechanical equipment through abrasion. Practical tests revealed coating of the sand grains with a FOG analogue (candlewax) to generate composite particles containing 45% wax by weight. The coated particles were then 30% less dense, 22% larger and 14% less settleable, on average, than the uncoated particles. Samples of accumulated grit taken from anaerobic digesters and aeration lanes from a full-scale plant indicated a FOG content (43%) similar to that of the waxed particles in the bench-scale tests, thus leading to a similar grain retardation of 14% assuming the FOG to be entirely associated with the grit. An assessment of the impact of the consequential breakthrough of grit particles due to buoyancy generated by composite particle formation indicated a $1.1 increase in operating costs per megalitre (ML) wastewater

Membrane surface modification and functionalization

[No abstract available]Scopu

Polydopamine functionalized graphene oxide as membrane nanofiller: Spectral and structural studies

High-degree functionalization of graphene oxide (GO) nanoparticles (NPs) using polydopamine (PDA) was conducted to produce polydopamine functionalized graphene oxide nanoparticles (GO-PDA NPs). Aiming to explore their potential use as nanofiller in membrane separation processes, the spectral and structural properties of GO-PDA NPs were comprehensively analyzed. GO NPs were first prepared by the oxidation of graphite via a modified Hummers method. The obtained GO NPs were then functionalized with PDA using a GO:PDA ratio of 1:2 to obtain highly aminated GO NPs. The structural change was evaluated using XRD, FTIR-UATR, Raman spectroscopy, SEM and TEM. Several bands have emerged in the FTIR spectra of GO-PDA attributed to the amine groups of PDA confirming the high functionalization degree of GO NPs. Raman spectra and XRD patterns showed different crystalline structures and defects and higher interlayer spacing of GO-PDA. The change in elemental compositions was confirmed by XPS and CHNSO elemental analysis and showed an emerging N 1s core-level in the GO-PDA survey spectra corresponding to the amine groups of PDA. GO-PDA NPs showed better dispersibility in polar and nonpolar solvents expanding their potential utilization for different purposes. Furthermore, GO and GO-PDA-coated membranes were prepared via pressure-assisted self-assembly technique (PAS) using low concentrations of NPs (1 wt. %). Contact angle measurements showed excellent hydrophilic properties of GO-PDA with an average contact angle of (27.8°).Scopu