Pb and Hf isotope evidence for mantle enrichment processes and melt interactions in the lower crust and lithospheric mantle in Miocene orogenic volcanic rocks from Monte Arcuentu (Sardinia, Italy)

Miocene (ca. 18 Ma) subduction-related basalts and basaltic andesites from Monte Arcuentu, southern Sardinia, Italy, show a remarkable correlation between 87Sr/86Sr (from ~0.705 to ~0.711) over a small range of SiO2 (~51–58 wt%) that contrasts with most other orogenic volcanic suites worldwide. New high-precision Pb and Hf isotope data help to constrain the petrogenesis of these rocks. The most primitive Monte Arcuentu rocks (MgO >8.5 wt%) were sourced from a mantle wedge metasomatized by melts derived from terrigenous sedi­ment, likely derived from Archean terranes of northern Africa. This gave rise to magmas with high 87Sr/86Sr (0.705–0.709) and 207Pb/204Pb (15.65–15.67) with moderate εHf (–1 to +8) and εNd (–6 to +1), but it does not account for the full range of compositions observed. More evolved rocks (MgO <8.5 wt%) have higher 87Sr/86Sr (up to 0.711) and 207Pb/204Pb (up to 15.68), with εHf and εNd as low as –8 and –9, respectively. Mixing calculations suggest that evolved rocks with low Rb/Ba and low 206Pb/204Pb interacted with lower crust similar compositionally to that exposed today in Calabria, Italy, which was formerly in crustal continuity with Sardinia. High Rb/Ba and high 206Pb/204Pb magmas interacted with lithospheric mantle similar to that sampled by Italian lamproites. Partial melting of lower crustal and upper mantle lithologies was facilitated by the rapid extension, and subsequent passive mantle upwelling, that occurred as Sardinia drifted away from the European plate during the Oligo-Miocene (ca. 32–15 Ma). Fractional crystallization under these PT conditions involved ­olivine + clinopyroxene with little or no plagioclase, such that differentiation proceeded without significant increase in SiO2. The Monte Arcuentu rocks provide insights into assimilation process in the lower crust and lithospheric mantle that may be obscured by upper crustal assimilation–fractional crystallization (AFC) processes in other orogenic suites

Isotopic evolution of prehistoric magma sources of Mt. Etna, Sicily: Insights from the Valle Del Bove

Mount Etna in NE Sicily occupies an unusual tectonic position in the convergence zone between the African and Eurasian plates, near the Quaternary subduction-related Aeolian arc and above the down-going Ionian oceanic slab. Magmatic evolution broadly involves a transition from an early tholeiitic phase (~ 500 ka) to the current alkaline phase. Most geochemical investigations have focussed on either historic (> 130-years old) or recent (< 130-years old) eruptions of Mt. Etna or on the ancient basal lavas (ca. 500 ka). In this study, we have analysed and modelled the petrogenesis of alkalic lavas from the southern wall of the Valle del Bove, which represent a time span of Mt. Etna’s prehistoric magmatic activity from ~ 85 to ~ 4 ka. They exhibit geochemical variations that distinguish them as six separate lithostratigraphic and volcanic units. Isotopic data (143Nd/144Nd = 0.51283–0.51291; 87Sr/86Sr = 0.70332–0.70363; 176Hf/177Hf = 0.28288–0.28298; 206Pb/204Pb = 19.76–20.03) indicate changes in the magma source during the ~ 80 kyr of activity that do not follow the previously observed temporal trend. The oldest analysed Valle del Bove unit (Salifizio-1) erupted basaltic trachyandesites with variations in 143Nd/144Nd and 87Sr/86Sr ratios indicating a magma source remarkably similar to that of recent Etna eruptions, while four of the five subsequent units have isotopic compositions resembling those of historic Etna magmas. All five magma batches are considered to be derived from melting of a mixture of spinel lherzolite and pyroxenite (± garnet). In contrast, the sixth unit, the main Piano Provenzana formation (~ 42–30 ka), includes the most evolved trachyandesitic lavas (58–62 wt% SiO2) and exhibits notably lower 176Hf/177Hf, 143Nd/144Nd, and 206Pb/204Pb ratios than the other prehistoric Valle del Bove units. This isotopic signature has not yet been observed in any other samples from Mt. Etna and we suggest that the parental melts of the trachyandesites were derived predominantly from ancient pyroxenite in the mantle source of Etna

Trace-element and isotopic characteristics of small-degree melts of the asthenosphere: Evidence from the alkalic basalts of the Antarctic Peninsula

Miocene-Recent continental alkalic basalts were erupted along the Antarctic Peninsula as a result of decompressional melting of the asthenosphere caused by the formation of slab-windows beneath the continental margin following the cessation of subduction. The basalts appear not to be related to a period of major lithospheric attenuation, nor were they formed as a result of the influence of a mantle plume. They exhibit strong trace-element and isotopic affinities with OIB, Sr- and Nd-isotope compositions ranging from 0.70269 to 0.70343 and 0.512863 to 0.51300, respectively, similar to the composition of HIMU OIB. However, new Pb-isotope analyses show that 206Pb204Pb ratios (18.79–19.28) fall within the range for E-type MORB with Δ84 and Δ74 varying from −28 to +26 and from +1 to +10, respectively. Δ84-values , Sr-isotope ratios and some LILE/HFSE ratios exhibit negative covariations with LanYbn and Nb/Y ratios implying some control of degree of partial melting on geochemical composition. Nb/U ratios (14–40) are considerably lower than most OIB and MORB. The basalts also have unusually low absolute abundances of Rb and Ba and high K/Ba and K/Rb ratios (50–140 and 400–1500, respectively). Correlated PbSrNd isotope and trace-element behaviour suggests that the asthenosphere from which these basalts were derived was subjected to multiple melt extraction/depletion events. One period of melt extraction was ancient (∼ 1.7 Ga) and similar to that affecting MORB source mantle, and was followed by a more recent (?Mesozoic) event. This more recent event resulted in increased U/Pb, U/Nb and U/Th ratios and further depletion in ultra-incompatible element such as Rb and Ba, causing high K/Rb and K/Ba ratios in the erupted lavas. This implies that the asthenosphere beneath the Antarctic Peninsula is heterogeneous on a small scale. Small-degree melts are capable of sampling geochemically, and possibly mineralogically, distinct mantle domains from larger-degree melts. During larger degrees of partial melting, the scale of melting approaches the scale of heterogeneity and integration of melts from different geochemical domains occurs

Hf–Nd evidence for the origin and distribution of mantle domains in the SW Pacific

Pb isotope systematics have already been used successfully to demonstrate that the lavas of the arc-basin terrains of the SW Pacific are derived from two mantle domains, one of Pacific-like character and the other of Indian-like character. However, the mobility of Pb during subduction and alteration has mainly restricted the fingerprinting of domains to fresh lavas of MORB composition. We demonstrate that the less alteration-sensitive Hf–Nd isotope projection also discriminates successfully between ‘Pacific’ and ‘Indian’ domains, and thus enables us to extend mantle domain fingerprinting to the back-arc basin basalts and boninites of the Lau and North Fiji Basins and the volcanic arc lavas of the Kermadec, Tonga and Vanuatu arcs. Fingerprinting is facilitated by the observation that the Hf isotope ratio is independent of subduction-input parameters, indicating that Hf has been essentially conservative during the subduction process. Subducted Nd has been added to the mantle source, but subtracting this numerically using the magnitude of negative Hf anomalies filters out the subduction effect. The data show that the ‘Indian’ domain provides the source for magmas erupted at ridges, and arcs near these ridges, that have propagated southwards following the 12 Ma collision of the Ontong-Java Plateau with the Vitiaz Trench. This indicates that the ‘Indian’ domain is actually derived from SOPITA mantle (South Pacific Isotopic and Thermal Anomaly) — mantle modified by the Samoa and other plumes outboard of the trench which only entered the SW Pacific arc-basin system after the Ontong-Java Plateau collision removed the slab barrier at < 12 Ma. In the west, mantle flows beneath the network of south-propagating ridges in the North Fiji and NW Lau Basins, undergoing progressive depletion until the final loss of plume components produces an N-MORB mantle (Indian MORB Mantle) composition in the south North Fiji Basin and Central Lau Spreading Centre. In the east, newly-depleted Samoan plume mantle provides the source for the boninites and depleted arc tholeiites of the northern Tonga arc

Hf-Nd element and isotope perspective on the nature and provenance of mantle and subduction components in Western Pacific arc-basin systems.

This paper develops methods for using the integrated study of Hf-Nd element and isotope covariations to define the nature and provenance of the mantle and subduction inputs to subduction systems. In particular, it can be demonstrated that (1) Hf-Nd isotope space permits discrimination between mantle of Pacific and Indian provenance, (2) displacements from mantle arrays on Hf-Nd isotope and trace element projections can be related to the magnitude, source and composition of the subduction input, and (3) Hf-Nd isotope and trace element covariations can be used to interpret high field strength element (HFSE) anomalies [specifically, Hf anomalies on extended rare earth element (REE) patterns] in subduction-related magmas. These methods are tested using published volcanic arc data coupled with new data from the many components of the Izu-Bonin-Mariana (IBM) subduction system, namely the pre-subduction marginal basins, the Eocene to Recent volcanic arcs, and the crust, volcanogenic sediments and pelagic sediments of the subducting Pacific plate. The results of the IBM study show that the mantle that fed the IBM system was always of Indian provenance and that Pacific volcanogenic sediments make the most significant, though variable, contribution to the subduction component. Modelling demonstrates that the Nd/Hf ratio of the subduction component probably lay between 40 and infinity and thus was probably the main cause of the negative HFSE anomalies that characterize much of the Recent arc. This result may further indicate that the subducting sediment lost elements to the mantle wedge mostly by dehydration rather than fusion. In contrast, the data also show that the positive Hf anomalies that characterize much of the Protoarc cannot be attributed directly to subduction. One option consistent with Hf-Nd systematics is that the positive Hf anomalies in the Protoarc boninites were caused by fusion of mafic veins in their shallow mantle sources. Comparison with published data on other arcs shows significant inter-arc variations. For example, the subduction components in near-continent arcs (Banda, Lesser Antilles) appear to have lower Nd/Hf ratios more consistent with sediment fusion, and at least one arc (Tonga-Fiji) carries evidence of temporal variations in mantle provenance

Géodynamique andine : résumé étendus = Andean geodynamics : extended abstracts

Le sud-ouest de la Colombie est une région caractérisée par de grandes quantités de roches volcaniques alcalines. Les tuffs de la Toba Granatifera contiennent des inclusions provenant de la croûte inférieure et du manteau. Elles permettent de remonter, à travers des études en éléments traces et isotopiques, à la source des roches volcaniques et au rôle de la plaque subduite. (Résumé d'auteur

Pretogenesis of Devonian lamprophyre and carbonatite minor intrusions, Kandalaksha Gulf (Kola Peninsula, Russia)

Minor magmatic intrusions (dykes and explosion pipes) of lamprophyric and carbonatitic compositions occur on several islands in the Gulf of Kandalaksha (White Sea, Kola Peninsula, Russia). The lamprophyre dykes yielded K-Ar ages of 368 ± 15 Ma and 360 ± 16 Ma, similar to the majority of alkaline rocks from the Kola Alkaline Province. Mineralogical data (presence of perovskite and sodalite, absence of amphibole phenocrysts) and geochemical data (low SiO2 and A12O3, high MgO) indicate an ultramafic lamprophyre affinity for the investigated silicate rocks. The lamprophyres contain a wide variety of xenoliths including hornblende- and biotite-rich cumulate ultramafic rocks. The carbonatite intrusions have ferrocarbonatite affinities and one of them contains xenoliths of coarse-grained Si-rich calciocarbonatites, together with abundant hornblendites and glimmerites which resemble those in the lamprophyres. The calciocarbonatite xenoliths themselves contain fragments of mica- and hornblende-rich rocks. 40Ar-39Ar ages on phlogopite and amphibole from calciocarbonatite and hornblende-rich cumulate xenoliths are between 386 ± 1.0 Ma and 395.6 ± 4.4 Ma, indicating an early Devonian age and suggesting a close relationship between the calciocarbonatite xenoliths and the ultramafic cumulate xenoliths. Thus, the ferrocarbonatite host magma may have disrupted an older calciocarbonatite-hornblendite-glimmerite intrusion at depth and incorporated xenoliths from it. The presence of hornblendite and glimmerite xenoliths with similar parageneses and identical ages in both the ultramafic lamprophyres and ferrocarbonatites suggests a close relationship between the ferrocarbonatite and lamprophyric magmas. REE patterns of the lamprophyric dykes and calciocarbonatite xenoliths show strong similarities, indicating a petrogenetic relationship. The ultramafic lamprophyres have REE patterns which are indistingishable from the contemporaneous kimberlites and melilitites from the nearby Terskii Bereg area, south Kola Peninsula. Age-corrected Sr and Nd isotope compositions demonstrate that the calciocarbonatite xenoliths have close affinities with other Devonian carbonatites from Kola and Karelia, whereas the lamprophyres are similar to the Kola kimberlites and melilitites. Differences between the Sr and Nd isotopic ratios of the silicate and carbonatite magmas throughout the Kola Alkaline Province are probably due to different mantle-source components. The Kola carbonatites mainly show a depleted mantle signature whereas the lamprophyres, melilitites and kimberlites were derived from a more enriched mantle. However, some degree of assimilation of lower continental crust and late-stage hydrothermal alteration of the silicate magmas may also have occurred

Hafnium-Osmium Systematics of Cretaceous Group II Kimberlites from India

V51B-0559 Fall Meeting Supplinfo:eu-repo/semantics/publishe