Electric field effects on nematic wetting layers

We present a theoretical investigation of the temperature and electric field dependence of nematic liquid crystal wetting layers close to an aligning substrate within a confined system. Using a mesoscopic Q tensor theory coupled to Maxwell's equations for the electric field, we consider the existence and stability of homogeneous nematic wetting layers close to the substrate. Numerical results are presented showing the phase diagram for the isotropic (paranematic), nematic and wetting layer states. The effect on the isotropic-wetting transition, from first order to second order, when an electric field is applied is then investigated

Developing and testing a generic micro-combined heat and power model for simulations of dwellings and highly distributed power systems

This paper elaborates an approach to the modelling of domestic micro-combined heat and power (μ-CHP) using a building simulation tool that can provide a detailed picture of the environmental performance of both the μ-CHP heating system and the dwelling it serves. The approach can also provide useful data for the modelling of highly distributed power systems (HDPS). At the commencement of the work described in this paper no μ-CHP device model that was compatible with a building simulation tool was available. The development of such a model is described along with its calibration and verification. The simulation tool with the device model was then applied to the analysis of a dwelling with a Stirling engine-based heating system. Different levels of thermal insulation and occupancy types were modelled. The energy and environmental performance of the μ-CHP device was quantified for each case; additionally, the potential for its participation in the control and operation of an HDPS was assessed. Analysis of the simulation results indicated that the parasitic losses associated with the μ-CHP system balance of plant reduced the overall heating system efficiency by up to 40 per cent. Performance deteriorated with increasing levels of insulation in the dwelling, resulting in reduced thermal efficiency and increased cycling, though overall fuel use was reduced. The analysis also indicated that the device was generally available to participate in HDPS control for greater than 90 per cent of the simulation time. The potential length of the participation time ranged from 1 to 800+min and depended upon the state of the μ-CHP system thermal buffer and prevailing heat loads. Probabilities for different participation times and modes were calculated

Cycles of construing in radicalization and deradicalization: a study of Salafist Muslims.

© Taylor & Francis Group, LLC.This article explores radicalization and deradicalization by considering the experiences of six young Tunisian people who had become Salafist Muslims. Their responses to narrative interviews and repertory grid technique are considered from a personal construct perspective, revealing processes of construing and reconstruing, as well as relevant aspects of the structure and content of their construct systems. In two cases, their journeys involved not only radicalization but self-deradicalization, and their experiences are drawn on to consider implications for deradicalization.Peer reviewedFinal Accepted Versio

Band gaps in pseudopotential self-consistent GW calculations

For materials which are incorrectly predicted by density functional theory to be metallic, an iterative procedure must be adopted in order to perform GW calculations. In this paper we test two iterative schemes based on the quasi-particle and pseudopotential approximations for a number of inorganic semiconductors whose electronic structures are well known from experiment. Iterating just the quasi-particle energies yields a systematic, but modest overestimate of the band gaps, confirming conclusions drawn earlier for CaB_6 and YH_3. Iterating the quasi-particle wave functions as well gives rise to an imbalance between the Hartree and Fock potentials and results in bandgaps in far poorer agreement with experiment.Comment: 5 pages, 2 figures, 2 table

Shell tile thermal protection system

A reusable, externally applied thermal protection system for use on aerospace vehicles subject to high thermal and mechanical stresses utilizes a shell tile structure which effectively separates its primary functions as an insulator and load absorber. The tile consists of structurally strong upper and lower metallic shells manufactured from materials meeting the thermal and structural requirements incident to tile placement on the spacecraft. A lightweight, high temperature package of insulation is utilized in the upper shell while a lightweight, low temperature insulation is utilized in the lower shell. Assembly of the tile which is facilitated by a self-locking mechanism, may occur subsequent to installation of the lower shell on the spacecraft structural skin

Attitude determination and calibration using a recursive maximum likelihood-based adaptive Kalman filter

An adaptive Kalman filter design that utilizes recursive maximum likelihood parameter identification is discussed. At the center of this design is the Kalman filter itself, which has the responsibility for attitude determination. At the same time, the identification algorithm is continually identifying the system parameters. The approach is applicable to nonlinear, as well as linear systems. This adaptive Kalman filter design has much potential for real time implementation, especially considering the fast clock speeds, cache memory and internal RAM available today. The recursive maximum likelihood algorithm is discussed in detail, with special attention directed towards its unique matrix formulation. The procedure for using the algorithm is described along with comments on how this algorithm interacts with the Kalman filter

Some Aspects of Measurement Error in Linear Regression of Astronomical Data

I describe a Bayesian method to account for measurement errors in linear regression of astronomical data. The method allows for heteroscedastic and possibly correlated measurement errors, and intrinsic scatter in the regression relationship. The method is based on deriving a likelihood function for the measured data, and I focus on the case when the intrinsic distribution of the independent variables can be approximated using a mixture of Gaussians. I generalize the method to incorporate multiple independent variables, non-detections, and selection effects (e.g., Malmquist bias). A Gibbs sampler is described for simulating random draws from the probability distribution of the parameters, given the observed data. I use simulation to compare the method with other common estimators. The simulations illustrate that the Gaussian mixture model outperforms other common estimators and can effectively give constraints on the regression parameters, even when the measurement errors dominate the observed scatter, source detection fraction is low, or the intrinsic distribution of the independent variables is not a mixture of Gaussians. I conclude by using this method to fit the X-ray spectral slope as a function of Eddington ratio using a sample of 39 z < 0.8 radio-quiet quasars. I confirm the correlation seen by other authors between the radio-quiet quasar X-ray spectral slope and the Eddington ratio, where the X-ray spectral slope softens as the Eddington ratio increases.Comment: 39 pages, 11 figures, 1 table, accepted by ApJ. IDL routines (linmix_err.pro) for performing the Markov Chain Monte Carlo are available at the IDL astronomy user's library, http://idlastro.gsfc.nasa.gov/homepage.htm

Abstract Tensor Systems as Monoidal Categories

The primary contribution of this paper is to give a formal, categorical treatment to Penrose's abstract tensor notation, in the context of traced symmetric monoidal categories. To do so, we introduce a typed, sum-free version of an abstract tensor system and demonstrate the construction of its associated category. We then show that the associated category of the free abstract tensor system is in fact the free traced symmetric monoidal category on a monoidal signature. A notable consequence of this result is a simple proof for the soundness and completeness of the diagrammatic language for traced symmetric monoidal categories.Comment: Dedicated to Joachim Lambek on the occasion of his 90th birthda

Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles

© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k

Shuttle derived atmospheric density model. Part 2: STS atmospheric implications for AOTV trajectory analysis, a proposed GRAM perturbation density model

A perturbation model to the Marshall Space Flight Center (MSFC) Global Reference Atmosphere Model (GRAM) was developed for use in the Aeroassist Orbital Transfer Vehicle (AOTV) trajectory and analysis. The model reflects NASA Space Shuttle experience over the first twelve entry flights. The GRAM was selected over the Air Force 1978 Reference Model because of its more general formulation and wider use throughout NASA. The add-on model, a simple scaling with altitude to reflect density structure encountered by the Shuttle Orbiter was selected principally to simplify implementation. Perturbations, by season, can be utilized to minimize the number of required simulations, however, exact Shuttle flight history can be exercised using the same model if desired. Such a perturbation model, though not meteorologically motivated, enables inclusion of High Resolution Accelerometer Package (HiRAP) results in the thermosphere. Provision is made to incorporate differing perturbations during the AOTV entry and exit phases of the aero-asist maneuver to account for trajectory displacement (geographic) along the ground track