Spontaneous alloying in binary metal microclusters - A molecular dynamics study -

Microcanonical molecular dynamics study of the spontaneous alloying(SA), which is a manifestation of fast atomic diffusion in a nano-sized metal cluster, is done in terms of a simple two dimensional binary Morse model. Important features observed by Yasuda and Mori are well reproduced in our simulation. The temperature dependence and size dependence of the SA phenomena are extensively explored by examining long time dynamics. The dominant role of negative heat of solution in completing the SA is also discussed. We point out that a presence of melting surface induces the diffusion of core atoms even if they are solid-like. In other words, the {\it surface melting} at substantially low temperature plays a key role in attaining the SA.Comment: 15 pages, 12 fgures, Submitted to Phys.Rev.

Evolution of the Far-infrared Cloud at Titan's South Pole

A condensate cloud on Titan identified by its 220 cm (sup -1) far-infrared signature continues to undergo seasonal changes at both the north and south poles. In the north the cloud, which extends from 55 North to the pole, has been gradually decreasing in emission intensity since the beginning of the Cassini mission with a half-life of 3.8 years. The cloud in the south did not appear until 2012 but its intensity has increased rapidly, doubling every year. The shape of the cloud at the South Pole is very different from that in the north. Mapping in December 2013 showed that the condensate emission was confined to a ring with a maximum at 80 South. The ring was centered 4 degrees from Titan's pole. The pattern of emission from stratospheric trace gases like nitriles and complex hydrocarbons (mapped in January 2014) was also offset by 4 degrees, but had a central peak at the pole and a secondary maximum in a ring at about 70 South with a minimum at 80 South. The shape of the gas emissions distribution can be explained by abundances that are high at the atmospheric pole and diminish toward the equator, combined with correspondingly increasing temperatures. We discuss possible causes for the condensate ring. The present rapid build up of the condensate cloud at the South Pole is likely to transition to a gradual decline during 2015-16

Ferrotoroidic ground state in a heterometallic {Cr^IIIDy^III<inf>6</inf>} complex displaying slow magnetic relaxation

© 2017 The Author(s). Toroidal quantum states are most promising for building quantum computing and information storage devices, as they are insensitive to homogeneous magnetic fields, but interact with charge and spin currents, allowing this moment to be manipulated purely by electrical means. Coupling molecular toroids into larger toroidal moments via ferrotoroidic interactions can be pivotal not only to enhance ground state toroidicity, but also to develop materials displaying ferrotoroidic ordered phases, which sustain linear magneto-electric coupling and multiferroic behavior. However, engineering ferrotoroidic coupling is known to be a challenging task. Here we have isolated a {CrIIIDyIII6} complex that exhibits the much sought-after ferrotoroidic ground state with an enhanced toroidal moment, solely arising from intramolecular dipolar interactions. Moreover, a theoretical analysis of the observed sub-Kelvin zero-field hysteretic spin dynamics of {CrIIIDyIII6} reveals the pivotal role played by ferrotoroidic states in slowing down the magnetic relaxation, in spite of large calculated single-ion quantum tunneling rates

Practical Mixed-Integer Optimization for Geometry Processing

Abstract. Solving mixed-integer problems, i.e., optimization problems where some of the unknowns are continuous while others are discrete, is NP-hard. Unfortunately, real-world problems like e.g., quadrangular remeshing usually have a large number of unknowns such that exact methods become unfeasible. In this article we present a greedy strategy to rapidly approximate the solution of large quadratic mixed-integer problems within a practically sufficient accuracy. The algorithm, which is freely available as an open source library implemented in C++, determines the values of the discrete variables by successively solving relaxed problems. Additionally the specification of arbitrary linear equality constraints which typically arise as side conditions of the optimization problem is possible. The performance of the base algorithm is strongly improved by two novel extensions which are (1) simultaneously estimating sets of discrete variables which do not interfere and (2) a fill-in reducing reordering of the constraints. Exemplarily the solver is applied to the problem of quadrilateral surface remeshing, enabling a great flexibility by supporting different types of user guidance within a real-time modeling framework for input surfaces of moderate complexity. Keywords: Mixed-Integer Optimization, Constrained Optimization

Titan Surface Temperatures during the Cassini Mission

By the close of the Cassini mission in 2017 the Composite Infrared Spectrometer had recorded surface brightness temperatures on Titan for 13 yr (almost half a Titan year). We mapped temperatures in latitude from pole to pole in seven time segments from northern mid-winter to northern summer solstice. At the beginning of the mission the warmest temperatures were centered at 13 S where they peaked at 93.9 K. Temperatures fell off by about 4 K toward the north pole and 2 K toward the south pole. As the seasons progressed the warmest temperatures shifted northward, tracking the subsolar point, and at northern summer solstice were centered at 24 N. While moving north the peak temperature decreased by about 1 K, reaching 92.8 K at solstice. At solstice the fall-off toward the north and south poles were 1 K and 3 K, respectively. Thus the temperature range was the same 2 K at the two poles. Our observed surface temperatures agree with recent general circulation model results that take account of methane hydrology and imply that hemispherical differences in Titan's topography may play a role in the north-south asymmetry on Titan

TRPV4 inhibition counteracts edema and inflammation and improves pulmonary function and oxygen saturation in chemically induced acute lung injury

We describe a method of implementing the axisymmetric evolution of general-relativistic hydrodynamics and magnetohydrodynamics through modification of a multipatch grid scheme. In order to ease the computational requirements required to evolve the post-merger phase of systems involving binary compact massive objects in numerical relativity, it is often beneficial to take advantage of these system's tendency to rapidly settle into states that are nearly axisymmetric, allowing for 2D evolution of secular timescales. We implement this scheme in the spectral Einstein code and show the results of application of this method to four test systems including viscosity, magnetic fields, and neutrino radiation transport. Our results show that this method can be used to quickly allow already existing 3D infrastructure that makes use of local coordinate system transformations to be made to run in axisymmetric 2D with the flexible grid creation capabilities of multipatch methods. Our code tests include a simple model of a binary neutron star postmerger remnant, for which we confirm the formation of a massive torus which is a promising source of post-merger ejecta