48 research outputs found
Diammonium potassium citrate, (NH4)2KC6H5O7
The crystal structure of diÂammonium potassium citrate, 2NH(4) (+)·K(+)·C(6)H(5)O(7) (3−), has been solved and refined using laboratory X-ray powder diffraction data and optimized using density functional theory. The KO(7) coordination polyhedra are isolated. The ammonium cations and the hydroÂphobic methylÂene sides of the citrate anions occupy the spaces between the coordination polyhedra. Each hydrogen atom of the ammonium ions acts as a donor in a charge-assisted N—H⋯O, N—H⋯(O,O) or N—H⋯(O,O,O) hydrogen bond. There is an intraÂmolecular O—H⋯O hydrogen bond in the citrate anion between the hydroxide group and one of the terminal carboxylÂate groups. [Image: see text