560 research outputs found
Theoretical study of electronic damage in single particle imaging experiments at XFELs for pulse durations 0.1 - 10 fs
X-ray free-electron lasers (XFELs) may allow to employ the single particle
imaging (SPI) method to determine the structure of macromolecules that do not
form stable crystals. Ultrashort pulses of 10 fs and less allow to outrun
complete disintegration by Coulomb explosion and minimize radiation damage due
to nuclear motion, but electronic damage is still present. The major
contribution to the electronic damage comes from the plasma generated in the
sample that is strongly dependent on the amount of Auger ionization. Since the
Auger process has a characteristic time scale on the order of femtoseconds, one
may expect that its contribution will be significantly reduced for attosecond
pulses. Here, we study the effect of electronic damage on the SPI at pulse
durations from 0.1 fs to 10 fs and in a large range of XFEL fluences to
determine optimal conditions for imaging of biological samples. We analyzed the
contribution of different electronic excitation processes and found that at
fluences higher than - photons/m (depending on the
photon energy and pulse duration) the diffracted signal saturates and does not
increase further. A significant gain in the signal is obtained by reducing the
pulse duration from 10 fs to 1 fs. Pulses below 1 fs duration do not give a
significant gain in the scattering signal in comparison with 1 fs pulses. We
also study the limits imposed on SPI by Compton scattering.Comment: 35 pages, 9 figures, 1 table, 2 appendixes, 45 reference
Influence of the initial- and final-state configuration interaction on the anisotropy of the resonant Auger decay of Kr 3d<sup>−1</sup>5p and Xe 4d<sup>−1</sup>6p states
The anisotropy of resonant Auger decay of photo-excited Kr 3d−13/2,5/25p and Xe 4d−13/2,5/26p states has been studied by multiconfiguration Dirac-Fock method. The calculations account for the configuration interaction both in the initial and in the final states of the Auger decay. For the nonresolved nd−1(n+2)p(J=1) resonances (n=3 for Kr and n=4 for Xe) the average intensities and anisotropies of Auger lines were calculated by weighing each partial rate by the pertinent Dirac-Fock photoexcitation probabilities. Our results show that, in addition to the initial- and final-state correlation, both the relaxation and the exchange interaction have a substantial effect on the anisotropy of these Auger spectra. For most Auger lines there is good agreement between our calculated β parameters and experimental values for the Kr and Xe nd−15/2(n+2)p photoexcitation resonances; there is also satisfactory agreement for the Kr 3d−13/25p and Xe 4d−13/26p resonant Auger spectra. However, the remaining notable discrepancies between theory and experiment indicate that important correlation effects are still omitted in our calculations. Discrepancies between different experimental results stress the need for further improvements on the experimental side
Coherence and correlation in the anisotropy of Ne KL-LLL satellite Auger decay
The energies, intensities, and angular anisotropies of the Ne KL-LLL satellite Auger lines have been studied by the multiconfiguration Dirac-Fock method. In addition to the initial- and final-state correlation effects we have studied the influence of the quantum beat effect on this Auger spectrum. Since the energy splitting of the Ne 1s−12p−13P multiplet is much smaller than the lifetime broadening, the coherent excitation of these initial states by the in time and space localized electromagnetic pulse of the projectile has a drastic effect on the angular distribution of Auger electrons. To analyze this coherence effect we have generalized the theory of the angular distribution of Auger electrons to the case of coherent excitation of partially overlapping initial states. The results of our calculations are in good overall agreement with experiment. However, for a quantitative study of the influence of the coherence and the initial spin state on the anisotropy of these Auger lines new measurements with lower error limits are necessary
Impact of ultrafast electronic damage in single particle x-ray imaging experiments
In single particle coherent x-ray diffraction imaging experiments, performed
at x-ray free-electron lasers (XFELs), samples are exposed to intense x-ray
pulses to obtain single-shot diffraction patterns. The high intensity induces
electronic dynamics on the femtosecond time scale in the system, which can
reduce the contrast of the obtained diffraction patterns and adds an isotropic
background. We quantify the degradation of the diffraction pattern from
ultrafast electronic damage by performing simulations on a biological sample
exposed to x-ray pulses with different parameters. We find that the contrast is
substantially reduced and the background is considerably strong only if almost
all electrons are removed from their parent atoms. This happens at fluences of
at least one order of magnitude larger than provided at currently available
XFEL sources.Comment: 15 pages, 3 figures submitted to PR
Angular anisotropy in the resonant Auger decay of 2p-photoexcited Mg
We have measured strongly negative β values of the 3s-participator lines at the magnesium 2p→4s and 2p1/2→3d excitations. Observed β values of the spectator lines following 2p→4s excitation are not reproduced by the strict spectator model. Our multiconfiguration Dirac-Fock calculations show that the resonant Auger spectra are influenced by unusually pronounced configuration interaction in the excited state. This influence is strongly enhanced by a change of sign in the Auger amplitude of the leading term near the transition energy, a dynamic effect similar to a Cooper minimum in photoionization
Spin polarization of the Ar* 2p−11/2 4s and 2p−11/2 3d resonant Auger decay
The spin-resolved Auger decay of the Ar 2p−11/2 3d state was measured at moderate energy resolution and compared with the decay of the 2p−11/2 4s. The former shows a lower transferred spin polarization and a similar, if not higher, dynamical spin polarization, supporting the statement that a fully resolved spectrum is not a necessary condition for observing dynamical spin polarization. An interpretation of the spin polarization as configuration interaction induced effect in the final ionic state leads to partial agreement with our relativistic distorted wave calculation utilizing a 36 configuration state function basis set. Comparison of the experimental and numerical results leads to ambiguities for at least one Auger line. A hypothetical, qualitative interpretation is discussed.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/58121/2/b7_17_012.pd
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