46 research outputs found
Poly[bis(phenethylยญammonium) [diยญbromidoยญplumbate(II)]-di-ฮผ-bromido]]
Crystals of the title compound, {(C6H5C2H4NH3)2[PbBr4]}n, were grown at room temperature from a solution in N,N-dimethylยญformamide (DMF) using nitroยญmethane as the poor solvent. This perovskite-type organicโinorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr6 octaยญhedra separated by bilayers of phenethylยญammonium cations. The octaยญhedra are rotated and tilted due to NโHโฏBr hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetraยญchloridoplumbate (C6H5C2H4NH3)2[PbCl4]