The Environmental Contribution to Wayfinding in Museums: Enhancement and Usage by Controlling Flows and Paths

The field of research in which wayfinding is situated refers to the way people move in reaction to environmental stimulation. It therefore fully concerns not just signage but also space designing, its geometric configuration, technical solutions and their material characterization. The focus is consequently on environmental factors that facilitate wayfinding in a museum (accessibility, visibility, etc.) and on other elements such as spatial configuration, architectural features and functional aspects. These factors influence relational phenomena and therefore visitors’ satisfaction. Methods and tools for designing and managing spaces have been studied in the research. The configurational analysis method of space has been used to objectify syntactic features of space. In particular, the outcomes of an experimental project, which have been analyzed in a master’s thesis on the re-functionalization of the museum of Palazzo dei Diamanti in Ferrara, are presented. Permeability, proximity, connections of spaces, namely meaningful features to ensure wayfinding have been examined. Space parameters resulting from the geometry of the layout, from the visual connections and from the changes of direction were then evaluated. The outcomes have been used as inputs for designing a unitary tour route circuit, that also reconnects the museum’s second floor, and for planning three independent alternative routes for a differentiated use of the museum

A Multi-electrode Electrochemical and Scanning Differential Electrochemical Mass Spectrometry Study of Methanol Oxidation on Electrodeposited PtxRuy

Methanol electro-oxidation was studied on a series of electrodeposited PtxRuy catalysts constructed as multielement band electrodes. A combination of electrochemical and scanning differential electrochemical mass spectrometry measurements were performed to evaluate the composition-dependence of methanol oxidation, methanol decomposition, CO2 current efficiency, and the product distribution at 25 and 50 °C. At 25 °C, cyclic voltammetry revealed that the presence of Ru led to enhanced methanol oxidation rates over that of pure Pt. Methanol decomposition showed a similar composition-dependence. Mass spectrometry measurements revealed the evolution of HCOOH and CO2 during methanol oxidation and allowed indirect determination of H2CO produced. Notably, these products were not observed during methanol decomposition. The most active electrode compositions and the highest instantaneous current efficiencies for the formation of CO2 were found to depend on several factors. At 25 °C, the maximum activity was 10% Ru, while at 50 °C the most active composition increased to 25% Ru. Pure Pt had the highest instantaneous current efficiency for CO2 at both temperatures. The product distribution reflected high CO2 evolution for Pt, with an increasing fraction of the product emerging as H2CO at higher Ru content. Increasing the temperature improved the CO2 current efficiency for all electrode compositions. These results confirm that methanol oxidation occurs though a parallel reaction pathway on PtxRuy electrodes. In addition, the balance between the different reaction pathways depends on several factors, including Ru composition and temperature

The UV Scattering Halo of the Central Source Associated with Eta Carinae

We have made an extensive study of the UV spectrum of Eta Carinae, and find that we do not directly observe the star and its wind in the UV. Because of dust along our line of sight, the UV light that we observe arises from bound-bound scattering at large impact parameters. We obtain a reasonable fit to the UV spectrum by using only the flux that originates outside 0.033". This explains why we can still observe the primary star in the UV despite the large optical extinction -- it is due to the presence of an intrinsic coronagraph in the Eta Carinae system, and to the extension of the UV emitting region. It is not due to peculiar dust properties alone. We have computed the spectrum of the purported companion star, and show that it could only be directly detected in the UV spectrum preferentially in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectral region (912-1175 Ang.). However, we find no direct evidence for a companion star, with the properties indicated by X-ray studies and studies of the Weigelt blobs, in UV spectra. This might be due to reprocessing of the companion's light by the dense stellar wind of the primary. Broad FeII and [FeII] emission lines, which form in the stellar wind, are detected in spectra taken in the SE lobe, 0.2" from the central star. The wind spectrum shows some similarities to the spectra of the B & D Weigelt blobs, but also shows some marked differences in that high excitation lines, and lines pumped by Ly-alpha, are not seen. The detection of the broad lines lends support to our interpretation of the UV spectrum, and to our model for Eta Carinae.Comment: To appear in ApJ. 57 pages with 18 figure

Deleuzian dragons: Thinking Chinese strategic spatial planning with Gilles Deleuze

As symbols of adaptability and transformation, together with qualities of vigilance and intelligence, we argue the relevance of dragons for spatial planning in China. We develop a metaphorical concept - the green dragon - for grasping the condition of contemporary Chinese societies and for facilitating the development of theories and practices of spatial planning which are able to face the challenges of rapid change. We ask Chinese scholars and spatial planners to liberate Deleuzian potential for strategic spatial planning in a 'becoming-between, coming-together' of concepts which can effectively make a difference in the world. Having outlined what we regard as key transversals or diagonals between our reading of Gilles Deleuze and aspects of Chinese philosophy, we then offer the metaphor of strategic spatial planning as Chinese literati landscape painting. This is a form of painting which rejects the idea of the world being supremely organised from a particular point of view, preferring to paint immanence and transformation. Chinese literati landscape paintings, like philosophy and strategic spatial planning, 'look only at the movements'. We conclude that connections between what concepts of Chinese philosophy and those of Gilles Deleuze can do, suggest that in China, a conception of strategic spatial planning as metaphorical green dragon may offer academics and planning practitioners a transverse way to relate the legacies of past philosophies and curren

Construction of Cell-Resistant Surfaces by Immobilization of Poly(ethylene glycol) on Gold

Considerable effort has been expended in efforts to create surfaces that resist the adsorption of proteins and cells for biomedical applications. The majority of such work has focused on surfaces constructed from bulk polymers or thin polymer films. However, the fabrication of surfaces via self-assembled monolayers (SAMs) has attracted considerable interest because of the robustness, versatility, and wide-ranging applicability of these materials. SAMs are particularly appealing for biological systems where well-defined surface chemistries can be created to facilitate coupling, biorecognition, or cell adhesion along with a host of other applications in biochemistry and biotechnology