Comprehensive Organic Analysis of Antartic Micrometeorites

Introduction: Micrometeorites (MMs) are thought to be significant contributors of organic material to the early Earth [1], and a variety of techniques have been employed to identify their organic composition [2-6]. These include the identification of key organic groups using combinations of infrared, energy dispersive Xray, electron energy loss and Raman spectroscopy and scanning transmission X-ray microscopy [2-4], highlighting similarities between that of MMs and carbonaceous chondrites. Few studies, however, have focused on the characterisation of individual micrometeoritic organic components. Microscopic L2MS has been used to identify up to C5 polycyclic aromatic hydrocarbons and their alkyl derivatives [5]. A combination of ionexchange chromatography and fluorimetric detection has also been successful in identifying a number of protein amino acids including glycine and alanine [6]. We have previously reported a method to analyse ?g-sized quantities of extraterrestrial materials, with prior application to assessing organic volatile release from MM atmospheric entry heating simulations [7]. In this study we utilise this technique to characterise the organic composition of Antarctic terrestrial particles and MMs collected in 1994 from Cap-Prudhomme [8]

Environmental dependence of AGN activity in the supercluster A901/2

We present XMM data for the supercluster A901/2, at z ~ 0.17, which is combined with deep imaging and 17-band photometric redshifts (from the COMBO-17 survey), 2dF spectra and Spitzer 24um data, to identify AGN in the supercluster. The 90ksec XMM image contains 139 point sources, of which 11 are identified as supercluster AGN with L_X(0.5-7.5keV) > 1.7x10^41 erg/cm2/s. The host galaxies have M_R < -20 and only 2 of 8 sources with spectra could have been identified as AGN by the detected optical emission lines. Using a large sample of 795 supercluster galaxies we define control samples of massive galaxies with no detected AGN. The local environments of the AGN and control samples differ at >98 per cent significance. The AGN host galaxies lie predominantly in areas of moderate projected galaxy density and with more local blue galaxies than the control sample, with the exception of one very bright Type I AGN very near the centre of a cluster. These environments are similar to, but not limited to, cluster outskirts and blue groups. Despite the large number of potential host galaxies, no AGN are found in regions with the highest galaxy density (excluding some cluster cores where emission from the ICM obscures moderate luminosity AGN). AGN are also absent from the areas with lowest galaxy density. We conclude that the prevalence of cluster AGN is linked to their environment.Comment: 20 pages, 15 figures. MNRAS accepted. Version with full resolution figures, including Figure 14, is available at http://www.sc.eso.org/~rgilmour

Pyrolysis-GC×GC-TOFMS to characterize carbonaceous chondrites

Using pyrolysis-GCxGC-TOFMS to analyze organic carbon in carbonaceous chondrites gives a massive increase in both sensitivity and structural information from samples when compared to traditional Py-GC-MS

Differential pulmonary retention of diesel exhaust particles in Wistar Kyoto and spontaneously hypertensive rats

Spontaneously hypertensive (SH) and normotensive Wistar Kyoto (WKY) rats have been used for understanding the mechanisms of variations in susceptibility to airborne pollutants. We examined the lung burden of diesel exhaust particles (DEP) following inhalation of diesel engine exhaust (DEE) in both strains. The kinetics of clearance was also examined after single intratracheal (IT) instillation of DEP. Lungs were analyzed for DEP elemental carbon (EC) after exposure to DEE (0, 500, or 2000 μ g/m3 4 h/day, 5 days/week×4 weeks). SH rats had 16% less DEP-EC at 500 and 32% less at 2000 μ g/m3 in the lungs, despite having 50% higher than the average minute volume. No strain-related differences were noted in number of alveolar macrophages or their average DEP load as evident from examining cells in bronchoalveolar lavage fluid (BALF). The kinetics of DEP clearance from lungs of male WKY and SH rats was studied following a single instillation at 0.0 or 8.33 mg/kg of DEP standard reference material (SRM 2975) from the National Institute of Standards Technology. SH rats cleared 60% DEP over 112 days while minimal clearance occurred from the lungs of WKY. The pattern of DEP-induced inflammatory response assessed by BALF analysis was similar in both strains, although the overall protein leak was slightly greater in SH rats. A time-dependent accumulation of DEP occurred in tracheal lymph nodes of both strains (SH &gt; WKY). Thus, SH rats may clear DEP more efficiently from their lungs than normotensive WKY rats, with a small contribution of more effective lymphatic drainage