A low-fluorine solution with a 2:1 F/Ba mole ratio for the fabrication of YBCO films:Paper

In the reported low-fluorine MOD-YBCO studies, the lowest F/Ba mole ratio of the precursor solution was 4.5. However, further lowering the F/Ba ratio is important according to the researches of YBCO thick film. On the other hand, the F/Ba ratio is necessary to be at least 2 for the full conversion of the Ba precursor to BaF_2 to avoid the formation of BaCO_3, which is detrimental to the superconducting performance. In this study, a novel solution with the F/Ba mole ratio of 2 was developed, in which the fluorine content was only about 10.3% of that used in the conventional TFA-MOD method. Attenuated total reflectance-Fourier transformed-infrared spectra(ATR-FT-IR) revealed that BaCO_3 was remarkably suppressed in the as-pyrolyzed film and eliminated at 700 Celsius degree. Thus YBCO films with a critical current density (J_c) over 5 MA cm^{-2} (77 K, 0 T, 200 nm thickness) could be obtained on LAO single crystal substrates. In-situ FT-IR spectra showed that no obvious fluorinated gaseous by-products were detected in the pyrolysis step, which indicated that all of the F atoms might remain in the film as fluorides. X-ray diffraction (XRD) \theta/2\theta-scan showed that BaF_2, but neither YF_3 nor CuF_2, was detected in the films quenched at 400 - 800 Celsius degree. The formation priority of BaF_2 over YF_3 and CuF_2 was interpreted by the chemical equilibrium of the potential reactions. Our study could enlarge the synthesis window of the precursor solution for MOD-YBCO fabrication and open a gate to study the fluorine content in the precursor solution continuously and systematically