Charge and momentum transfer in supercooled melts: Why should their relaxation times differ?

The steady state values of the viscosity and the intrinsic ionic-conductivity of quenched melts are computed, in terms of independently measurable quantities. The frequency dependence of the ac dielectric response is estimated. The discrepancy between the corresponding characteristic relaxation times is only apparent; it does not imply distinct mechanisms, but stems from the intrinsic barrier distribution for $\alpha$-relaxation in supercooled fluids and glasses. This type of intrinsic ``decoupling'' is argued not to exceed four orders in magnitude, for known glassformers. We explain the origin of the discrepancy between the stretching exponent $\beta$, as extracted from $\epsilon(\omega)$ and the dielectric modulus data. The actual width of the barrier distribution always grows with lowering the temperature. The contrary is an artifact of the large contribution of the dc-conductivity component to the modulus data. The methodology allows one to single out other contributions to the conductivity, as in ``superionic'' liquids or when charge carriers are delocalized, implying that in those systems, charge transfer does not require structural reconfiguration.Comment: submitted to J Chem Phy

Simple Lattice-Models of Ion Conduction: Counter Ion Model vs. Random Energy Model

The role of Coulomb interaction between the mobile particles in ionic conductors is still under debate. To clarify this aspect we perform Monte Carlo simulations on two simple lattice models (Counter Ion Model and Random Energy Model) which contain Coulomb interaction between the positively charged mobile particles, moving on a static disordered energy landscape. We find that the nature of static disorder plays an important role if one wishes to explore the impact of Coulomb interaction on the microscopic dynamics. This Coulomb type interaction impedes the dynamics in the Random Energy Model, but enhances dynamics in the Counter Ion Model in the relevant parameter range.Comment: To be published in Phys. Rev.

Mesoscopic non-equilibrium thermodynamics approach to non-Debye dielectric relaxation

Mesoscopic non-equilibrium thermodynamics is used to formulate a model describing non-homogeneous and non-Debye dielectric relaxation. The model is presented in terms of a Fokker-Planck equation for the probability distribution of non-interacting polar molecules in contact with a heat bath and in the presence of an external time-dependent electric field. Memory effects are introduced in the Fokker-Planck description through integral relations containing memory kernels, which in turn are used to establish a connection with fractional Fokker-Planck descriptions. The model is developed in terms of the evolution equations for the first two moments of the distribution function. These equations are solved by following a perturbative method from which the expressions for the complex susceptibilities are obtained as a functions of the frequency and the wave number. Different memory kernels are considered and used to compare with experiments of dielectric relaxation in glassy systems. For the case of Cole-Cole relaxation, we infer the distribution of relaxation times and its relation with an effective distribution of dipolar moments that can be attributed to different segmental motions of the polymer chains in a melt.Comment: 33 pages, 6 figure

Contributions to the mixed-alkali effect in molecular dynamics simulations of alkali silicate glasses

The mixed-alkali effect on the cation dynamics in silicate glasses is analyzed via molecular dynamics simulations. Observations suggest a description of the dynamics in terms of stable sites mostly specific to one ionic species. As main contributions to the mixed--alkali slowdown longer residence times and an increased probability of correlated backjumps are identified. The slowdown is related to the limited accessibility of foreign sites. The mismatch experienced in a foreign site is stronger and more retarding for the larger ions, the smaller ions can be temporarily accommodated. Also correlations between unlike as well as like cations are demonstrated that support cooperative behavior.Comment: 10 pages, 12 figures, 1 table, revtex4, submitted to Phys. Rev.

Cost-optimal spare parts inventory planning for wind energy systems

For safe and reliable machine operation, maintenance, repair and overhaul (MRO) activities are required. Spare parts demand forecasting and inventory planning, which is an important part of MRO activities, must be accurate to avoid costs because of surplus spare parts or machine downtimes. The restriction of reduced accessibility to wind turbines during the winter months also has to be taken into account when planning maintenance activities and spare part inventories for wind farms. The presented model provides the most economic stock quantity under given environmental conditions. It is based on the proportional hazards model, which is extended to calculate the remaining useful component life time and derive required spare parts inventory levels. The presented model is validated, using condition monitoring data and environmental data of an onshore wind farm. Comparison of the spare part inventory prediction to wind farm's failure data proves the model's accuracy. Parameter analyses show that the model can be applied for spare parts inventory planning under consideration of environmental conditions

Illustrating phallic worship: uses of material objects and the production of sexual knowledge in eighteenth-century antiquarianism and early twentieth-century sexual science

This is the final version of the article. Available from Taylor & Francis via the DOI in this record.This article reveals previously overlooked connections between eighteenth-century antiquarianism and early twentieth-century sexual science by presenting a comparative reading of two illustrated books: An Account of the Remains of the Worship of Priapus, by British antiquarian scholar Richard Payne Knight (1750–1824), and Die Weltreise eines Sexualforschers (The World Journey of a Sexologist), by German sexual scientist Magnus Hirschfeld (1868–1935). A close analysis of these publications demonstrates the special status of material artefacts and the strategic engagement with visual evidence in antiquarian and scientific writings about sex. Through its exploration of the similarities between antiquarian and sexual scientific thought, the article demonstrates the centrality of material culture to the production of sexual knowledge in the Western world. It also opens up new perspectives on Western intellectual history and on the intellectual origins of sexual science. While previous scholarship has traced the beginnings of sexual science back to nineteenth-century medical disciplines, this article shows that sexual scientists drew upon different forms of evidence and varied methodologies to produce sexual knowledge and secure scientific authority. As such, sexual science needs to be understood as a field with diverse intellectual roots that can be traced back (at least) to the eighteenth century.All authors gratefully acknowledge financial support from the Wellcome Trust [grant numbers NC110388, 106654/Z/14/Z and 106653/Z/14/Z]

Surrogate-based optimization of tidal turbine arrays: a case study for the Faro-Olhão inlet

This paper presents a study for estimating the size of a tidal turbine array for the Faro-Olhão Inlet (Potugal) using a surrogate optimization approach. The method compromises problem formulation, hydro-morphodynamic modelling, surrogate construction and validation, and constraint optimization. A total of 26 surrogates were built using linear RBFs as a function of two design variables: number of rows in the array and Tidal Energy Converters (TECs) per row. Surrogates describe array performance and environmental effects associated with hydrodynamic and morphological aspects of the multi inlet lagoon. After validation, surrogate models were used to formulate a constraint optimization model. Results evidence that the largest array size that satisfies performance and environmental constraints is made of 3 rows and 10 TECs per row.Eduardo González-Gorbeña has received funding for the OpTiCA project (http://msca-optica.eu/) from the Marie Skłodowska-Curie Actions of the European Union's H2020-MSCA-IF-EF-RI-2016 / GA#: 748747. The paper is a contribution to the SCORE pro-ject, funded by the Portuguese Foundation for Science and Technology (FCT–PTDC/AAG-TEC/1710/2014). André Pacheco was supported by the Portuguese Foun-dation for Science and Technology under the Portuguese Researchers’ Programme 2014 entitled “Exploring new concepts for extracting energy from tides” (IF/00286/2014/CP1234).info:eu-repo/semantics/publishedVersio

Channel diffusion of sodium in a silicate glass

We use classical molecular dynamics simulations to study the dynamics of sodium atoms in amorphous Na$_2$O-4SiO$_2$. We find that the sodium trajectories form a well connected network of pockets and channels. Inside these channels the motion of the atoms is not cooperative but rather given by independent thermally activated hops of individual atoms between the pockets. By determining the probability that an atom returns to a given starting site, we show that such events are not important for the dynamics of this system.Comment: 10 pages of Latex, 5 figures, one figure added, text expande