Periferal konumda oksa-aza grubu taşıyan metalli ftalosiyanin sentezi ve karakterizasyonu

Bu çalışmada ilk olarak 1,8 bis-[2-(2-hidroksi-etoksi) amino]-antrakinon bileşiğine tosilleme işlemi yapılmıştır. 1,8 bis-[2-(2-tosiloksietoksi) amino]-antrakinon, 3,4- dihidroksi ftalonitril bileşiği ile reaksiyona sokularak 5,28-dioksa- 4,5,10,11,12,14,15,22,23,25,26,27-dodekahidro-4aH-4,6-metantribenzo [e,n,q][1,4,7,10,13,19]- tetraoksadiazasiklohenicosin -18,19- dikarbonitril bileşiği elde edilmiştir. Son olarak bu bileşiğin Kobalt Ftalosiyanini sentezlenmiştir. Elde edilen yeni maddelerin yapıları, 1H-NMR, 13C-NMR, IR, UV-vis. ve kütle spektroskopik verileri ve elemental analiz değerleri kullanarak aydınlatılmıştır.In this study, firstly it was tosylationed. 1,8 bis-[2-(2-hidroxy-ethoxy) amino]- anthraquinone. 5,28-dioxo-4,5,10,11,12,14,15,22,23,25,26,27-dodecahydro-4aH-4,6- methanotribenzo-[e,n,q][1,4,7,10,13,19]-tetraoxadiazacyclohenicosine-18,19- dicarbonitrile compound was synthesized reaction of between 1,8 bis-[2-(2-tosiloxy-ethoxy) amino]-anthraquinone, 3,4-dihidroxy phthalonitrile. Finally, Cobalt phthalocyanine was synthesized. The structure of novel compounds have been investigated the combination of elemental analysis, IR, 1H and 13C-NMR, MS and UV-vis Data

The synthesis and characterization of novel (E,E)-dioxime and its nickel (II) complexes containing compartmental and twofold macrocyclic moieties

A new (E,E)-dioxime, S,S′-bis(2-acetophenone)dithioglyoxime, has been synthesized by the reaction of dichloroglyoxime with 2-thioacetophenone. Only mononuclear Ni (II) complex with a metal:ligand ratio (1:2) was prepared and then Ni(II) complex bridged BF 2 + was obtained with hydrogen-bridged Ni(II) complex and boron trifluoride etherate. The reaction of BF 2 + -capped Ni(II) complex with 4′,5′- diaminobenzo [15-crown-5] gave a twofold complex. The structure of ligand and Ni(II) complexes are proposed according to elemental analyses, 1 H, 13 C NMR, IR and mass spectral data and semi-empirical quantum chemical calculations. Graphical Abstract: Synthesis and characterization of novel (E,E)-dioxime and its Ni(II) complex as well as the BF 2 -bridged complex were prepared. Then the nickel(II) complex containing compartmental and twofold macrocyclic moieties has been synthesized by the macrocyclization reaction of 4′,5′-diaminobenzo[15-crown-5] with BF 2 + -capped nickel(II) complex. [Figure not available: see fulltext.] © 2012 Springer Science+Business Media B.V

The synthesis and characterization of novel (E,E)-dioxime and its nickel (II) complexes containing compartmental and twofold macrocyclic moieties

A new (E,E)-dioxime, S,S'-bis(2-acetophenone)dithioglyoxime, has been synthesized by the reaction of dichloroglyoxime with 2-thioacetophenone. Only mononuclear Ni (II) complex with a metal:ligand ratio (1:2) was prepared and then Ni(II) complex bridged BF 2 + was obtained with hydrogen-bridged Ni(II) complex and boron trifluoride etherate. The reaction of BF 2 + -capped Ni(II) complex with 4',5'- diaminobenzo [15-crown-5] gave a twofold complex. The structure of ligand and Ni(II) complexes are proposed according to elemental analyses, 1 H, 13 C NMR, IR and mass spectral data and semi-empirical quantum chemical calculations. Graphical Abstract: Synthesis and characterization of novel (E,E)-dioxime and its Ni(II) complex as well as the BF 2 -bridged complex were prepared. Then the nickel(II) complex containing compartmental and twofold macrocyclic moieties has been synthesized by the macrocyclization reaction of 4',5'-diaminobenzo[15-crown-5] with BF 2 + -capped nickel(II) complex. [Figure not available: see fulltext.] © 2012 Springer Science+Business Media B.V

Synthesis and Characterization of New Phthalocyaninato Cobalt Complexes Containing Crown Ether Linked 1,8-Disubstituted Anthraquinones

The synthesis of novel cobalt(II) phthalocyanine complexes, peripheral symmetrically derived from 5,28-dioxo-5,11,12,14,15,22,23,25,26,27-decahydro-10H-4,6-methanotribenzo [e,n,q][1,4,7,10,13,19] tetraoxadiazacyclohenicosine-18,19-dicarbodinitrile or 5,28-dioxo-11,12,14,15,22,23,25,26-octahydro-5H-4,6-methanotribenzo [h,q,f] [1,4,7,10,13,16]hexa-oxacyclohenicosine-18,19-dicarbodinitrile were performed. These compounds were prepared starting 4,5-dihydroxy-1,2-phthalonitrile and 1,8-bis{[2-[2-{[(4-methylphenyl) sulfonyl]oxy}ethoxy]ethyl]amino}-9,10-anthracenedione or 1,8-bis[2-(2-iodoethoxy)ethoxy]-9,10-anthracenedione. Cobalt phthalocyanine complexes were prepared from dinitrile compounds and anyhydro cobalt(II)chloride. The novel compounds were characterized by a elemental analysis, FT-IR, UV-vis, 1H NMR, 13C NMR, and MS. Copyright © Taylor ; Francis Group, LLC 2016