Measurements of the ClO radical vibrational band intensity and the ClO + ClO + M reaction product

There is considerable interest in the kinetics and concentrations of free radicals in the stratosphere. Chlorine monoxide is a critically important radical because of its role in catalytic cycles for ozone depletion. Depletion occurs under a wide variety of conditions including the Antarctic spring when unusual mechanisms such as the BrO sub x/ClO sub x, ClO dimer (Cl sub 2 O sub 2), and ClO sub x/HO sub x cycles are suggested to operate. Infrared spectroscopy is one of the methods used to measure ClO in the stratosphere (Menzies 1979 and 1983; Mumma et al., 1983). To aid the quantification of such infrared measurements, researchers measured the ClO ground state fundamental band intensity

A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels

Experiments performed in laboratory chambers have contributed significantly to the understanding of the fundamental kinetics and mechanisms of the chemical reactions occurring in the atmosphere. Two chemical regimes, classified as high-NO vs. zero-NO conditions, have been extensively studied in previous chamber experiments. Results derived from these two chemical scenarios are widely parameterized in chemical transport models to represent key atmospheric processes in urban and pristine environments. As the anthropogenic NO_x emissions in the United States have decreased remarkably in the past few decades, the classic high-NO and zero-NO conditions are no longer applicable to many regions that are constantly impacted by both polluted and background air masses. We present here the development and characterization of the NCAR Atmospheric Simulation Chamber, which is operated in steady-state continuous flow mode for the study of atmospheric chemistry under intermediate NO conditions. This particular chemical regime is characterized by constant sub-ppb levels of NO and can be created in the chamber by precise control of the inflow NO concentration and the ratio of chamber mixing to residence timescales. Over the range of conditions achievable in the chamber, the lifetime of peroxy radicals (RO_2), a key intermediate from the atmospheric degradation of volatile organic compounds (VOCs), can be extended to several minutes, and a diverse array of reaction pathways, including unimolecular pathways and bimolecular reactions with NO and HO_2, can thus be explored. Characterization experiments under photolytic and dark conditions were performed and, in conjunction with model predictions, provide a basis for interpretation of prevailing atmospheric processes in environments with intertwined biogenic and anthropogenic activities. We demonstrate the proof of concept of the steady-state continuous flow chamber operation through measurements of major first-generation products, methacrolein (MACR) and methyl vinyl ketone (MVK), from OH- and NO_3- initiated oxidation of isoprene

Classification of color textures with random field models and neural networks

A number of texture classification approaches have been developed in the past but most of these studies target graylevel textures. In this work, novel results are presented on Neural Network based classification of color textures in a very large heterogeneous database. Several different Multispectral Random Field models are used to characterize the textures. The classifying features are based on the estimated parameters of these model and functions defined on them. The approach is tested on a database of 73 different color textures classes. The advantage of utilizing color information is demonstrated by converting color textures to gray-level ones and classifying them using Grey Level Co-Occurrence Matrix (GLCM) based features.Facultad de Informátic

Post-carotid stent ultrasound provides critical data to avoid rare but serious complications

SummaryCarotid stenting is a common procedure for revascularization of carotid artery stenosis. In this study, we evaluated the role of carotid ultrasound post carotid stenting. In a retrospective analysis, we identified 45 patients who received post-stent ultrasound. On routine follow-up we measured a range for peak systolic velocity of 33–150cm/s and end diastolic velocity 11–52cm/s. We also identified two cases, where immediate post-stent ultrasound provided critical data that required further intervention, and potentially avoided serious complications

Quantum Measurement and the Aharonov-Bohm Effect with Superposed Magnetic Fluxes

We consider the magnetic flux in a quantum mechanical superposition of two values and find that the Aharonov-Bohm effect interference pattern contains information about the nature of the superposition, allowing information about the state of the flux to be extracted without disturbance. The information is obtained without transfer of energy or momentum and by accumulated nonlocal interactions of the vector potential $\vec{A}$ with many charged particles forming the interference pattern, rather than with a single particle. We suggest an experimental test using already experimentally realized superposed currents in a superconducting ring and discuss broader implications.Comment: 6 pages, 4 figures; Changes from version 3: corrected typo (not present in versions 1 and 2) in Eq. 8; Changes from version 2: shortened abstract; added refs and material in Section IV. The final publication is available at: http://link.springer.com/article/10.1007/s11128-013-0652-

Response of thin-film SQUIDs to applied fields and vortex fields: Linear SQUIDs

In this paper we analyze the properties of a dc SQUID when the London penetration depth \lambda is larger than the superconducting film thickness d. We present equations that govern the static behavior for arbitrary values of \Lambda = \lambda^2/d relative to the linear dimensions of the SQUID. The SQUID's critical current I_c depends upon the effective flux \Phi, the magnetic flux through a contour surrounding the central hole plus a term proportional to the line integral of the current density around this contour. While it is well known that the SQUID inductance depends upon \Lambda, we show here that the focusing of magnetic flux from applied fields and vortex-generated fields into the central hole of the SQUID also depends upon \Lambda. We apply this formalism to the simplest case of a linear SQUID of width 2w, consisting of a coplanar pair of long superconducting strips of separation 2a, connected by two small Josephson junctions to a superconducting current-input lead at one end and by a superconducting lead at the other end. The central region of this SQUID shares many properties with a superconducting coplanar stripline. We calculate magnetic-field and current-density profiles, the inductance (including both geometric and kinetic inductances), magnetic moments, and the effective area as a function of \Lambda/w and a/w.Comment: 18 pages, 20 figures, revised for Phys. Rev. B, the main revisions being to denote the effective flux by \Phi rather than

Multi-instrument comparison and compilation of non-methane organic gas emissions from biomass burning and implications for smoke-derived secondary organic aerosol precursors

Multiple trace-gas instruments were deployed during the fourth Fire Lab at Missoula Experiment (FLAME- 4), including the first application of proton-transfer-reaction time-of-flight mass spectrometry (PTR-TOFMS) and comprehensive two-dimensional gas chromatography-time-offlight mass spectrometry (GC×GC-TOFMS) for laboratory biomass burning (BB) measurements. Open-path Fourier transform infrared spectroscopy (OP-FTIR) was also deployed, as well as whole-air sampling (WAS) with onedimensional gas chromatography-mass spectrometry (GCMS) analysis. This combination of instruments provided an unprecedented level of detection and chemical speciation. The chemical composition and emission factors (EFs) determined by these four analytical techniques were compared for four representative fuels. The results demonstrate that the instruments are highly complementary, with each covering some unique and important ranges of compositional space, thus demonstrating the need for multi-instrument approaches to adequately characterize BB smoke emissions. Emission factors for overlapping compounds generally compared within experimental uncertainty, despite some outliers, including monoterpenes. Data from all measurements were synthesized into a single EF database that includes over 500 non-methane organic gases (NMOGs) to provide a comprehensive picture of speciated, gaseous BB emissions. The identified compounds were assessed as a function of volatility; 6-11% of the total NMOG EF was associated with intermediate-volatility organic compounds (IVOCs). These atmospherically relevant compounds historically have been unresolved in BB smoke measurements and thus are largely missing from emission inventories. Additionally, the identified compounds were screened for published secondary organic aerosol (SOA) yields. Of the total reactive carbon (defined as EF scaled by the OH rate constant and carbon number of each compound) in the BB emissions, 55-77% was associated with compounds for which SOA yields are unknown or understudied. The best candidates for future smog chamber experiments were identified based on the relative abundance and ubiquity of the understudied compounds, and they included furfural, 2-methyl furan, 2-furan methanol, and 1,3- cyclopentadiene. Laboratory study of these compounds will facilitate future modeling efforts