12 research outputs found
All-Photonic Multifunctional Molecular Logic Device
Photochromes are photoswitchable, bistable chromophores which, like transistors, can implement binary logic operations. When several photochromes are combined in one molecule, interactions between them such as energy and electron transfer allow design of simple Boolean logic gates and more complex logic devices with all-photonic inputs and outputs. Selective isomerization of individual photochromes can be achieved using light of different wavelengths, and logic outputs can employ absorption and emission properties at different wavelengths, thus allowing a single molecular species to perform several different functions, even simultaneously. Here, we report a molecule consisting of three linked photochromes that can be configured as AND, XOR, INH, half-adder, half-subtractor, multiplexer, demultiplexer, encoder, decoder, keypad lock, and logically reversible transfer gate logic devices, all with a common initial state. The system demonstrates the advantages of light-responsive molecules as multifunctional, reconfigurable nanoscale logic devices that represent an approach to true molecular information processing units
Synthesis and Photophysical Characterization of Azoheteroarenes
A set
of azoheteroarenes have been synthesized with BuchwaldāHartwig
coupling and microwave-assisted O<sub>2</sub> oxidation as the key
steps. Several compounds exhibit good to excellent photoswitching
properties (high switching efficiency, good fatigue resistance, and
thermal stability of <i>Z</i>-isomer) relevant for photocontrolled
applications, which pave the way for use in photopharmacology
Interactions of a Photochromic Spiropyran with Liposome Model Membranes
The interactions between anionic or zwitterionic liposomes
and
a water-soluble, DNA-binding photochromic spiropyran are studied using
UV/vis absorption and linear dichroism (LD) spectroscopy. The spectral
characteristics as well as the kinetics of the thermal isomerization
process in the absence and presence of the two different liposome
types provide information about the environment and whether or not
the spiropyran resides in the liposome membrane. By measuring LD on
liposomes deformed and aligned by shear flow, further insight is obtained
about interaction and binding geometry of the spiropyran at the lipid
membranes. We show that the membrane interactions differ between the
two types of liposomes used as well as the isomeric forms of the spiropyran
photoswitch
The Open and Closed Forms of a Perfluoro Diarylethene PhotoswitchHalogen Bonding, Network Topology, and CSD Analysis
The structure of the perfluoro cyclopentene diarylethene
photoswitch
3,3ā²-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-ethyl-6-iodobenzo[b]thiophene 1,1-dioxide) (C25H16F6I2O4S2) 1 at
100 K has a tetragonal (I41/a) symmetry. The compound has a halogen-bonded network structure described
by the uninodal five-connected joa net. This net is related
to another uninodal six-connected net sfo. Analysis using
the Cambridge Structural Database (CSD) shows that the majority of
structures with the perfluoro cyclopentene diarylethene motif, >85%,
have a CĀ·Ā·Ā·C distance of around 3.5 Ć
where a
new single bond will develop during photoswitching, whereas compound 1 falls in a second smaller category with CĀ·Ā·Ā·C
distances of around 4.2 Ć
. The photochemical reaction of 1 under UV light in ethanol gave a closed form that crystallized
as ethanol solvate 2a in the P21/c space group, and recrystallization in
acetone gave the nonsolvated form 2b crystallizing in
the space group Fdd2. We did not observe, and do
not believe that it is possible, to photoswitch 1 in
the solid state as the CĀ·Ā·Ā·C distance where a new single
bond will develop is very long
An All-Photonic Molecule-Based D Flip-Flop
The photochromic fluorescence switching of a fulgimide
derivative
was used to implement the first molecule-based D (<i>delay</i>) flip-flop device, which works based on the principles of sequential
logic. The device operates exclusively with photonic signals and can
be conveniently switched in repeated cycles
An All-Photonic Molecule-Based Parity Generator/Checker for Error Detection in Data Transmission
The
function of a parity generator/checker, which is an essential
operation for detecting errors in data transmission, has been realized
with multiphotochromic switches by taking advantage of a neuron-like
fluorescence response and reversible light-induced transformations
between the implicated isomers
Characterization of the Thermal and Photoinduced Reactions of Photochromic Spiropyrans in Aqueous Solution
Six water-soluble spiropyran derivatives
have been characterized
with respect to the thermal and photoinduced reactions over a broad
pH-interval. A comprehensive kinetic model was formulated including
the spiro- and the merocyanine isomers, the respective protonated
forms, and the hydrolysis products. The experimental studies on the
hydrolysis reaction mechanism were supplemented by calculations using
quantum mechanical (QM) models employing density functional theory.
The results show that (1) the substitution pattern dramatically influences
the p<i>K</i><sub>a</sub>-values of the protonated forms
as well as the rates of the thermal isomerization reactions, (2) water
is the nucleophile in the hydrolysis reaction around neutral pH, (3)
the phenolate oxygen of the merocyanine form plays a key role in the
hydrolysis reaction. Hence, the nonprotonated merocyanine isomer is
susceptible to hydrolysis, whereas the corresponding protonated form
is stable toward hydrolytic degradation
Optically Switchable NIR Photoluminescence of PbS Semiconducting Nanocrystals using Diarylethene Photoswitches
Precisely modulated photoluminescence (PL) with external
control
is highly demanded in material and biological sciences. However, it
is challenging to switch the PL on and off in the NIR region with a high modulation contrast. Here, we demonstrate
that reversible on and off switching
of the PL in the NIR region can be achieved in a bicomponent system
comprised of PbS semiconducting nanocrystals (NCs) and diarylethene
(DAE) photoswitches. Photoisomerization of DAE to the ring-closed
form upon UV light irradiation causes substantial quenching of the
NIR PL of PbS NCs due to efficient triplet energy transfer. The NIR
PL fully recovers to an on state upon reversing the
photoisomerization of DAE to the ring-open form with green light irradiation.
Importantly, fully reversible switching occurs without obvious fatigue,
and the high PL on/off ratio (>100)
outperforms all previously reported assemblies of NCs and photoswitches
OFF-ON-OFF Fluorescence Switch with T-Latch Function
A novel molecular system with characteristics of an OFF-ON-OFF fluorescence switch was designed to integrate the function of a T-latch. In detail, a receptor<sub>1</sub>-fluorophore-receptor<sub>2</sub> architecture was adopted to achieve fluorescence switching upon addition of protons
All-Photonic Multifunctional Molecular Logic Device
Photochromes are photoswitchable, bistable chromophores which, like transistors, can implement binary logic operations. When several photochromes are combined in one molecule, interactions between them such as energy and electron transfer allow design of simple Boolean logic gates and more complex logic devices with all-photonic inputs and outputs. Selective isomerization of individual photochromes can be achieved using light of different wavelengths, and logic outputs can employ absorption and emission properties at different wavelengths, thus allowing a single molecular species to perform several different functions, even simultaneously. Here, we report a molecule consisting of three linked photochromes that can be configured as AND, XOR, INH, half-adder, half-subtractor, multiplexer, demultiplexer, encoder, decoder, keypad lock, and logically reversible transfer gate logic devices, all with a common initial state. The system demonstrates the advantages of light-responsive molecules as multifunctional, reconfigurable nanoscale logic devices that represent an approach to true molecular information processing units