6,699 research outputs found
A Selected Ion Flow Tube Study of the Reactions of Several Cations with the Group 6B Hexafluorides SF6, SeF6, and TeF6
The first investigation of the ion chemistry of SeF and TeF is presented. Using a selected ion flow tube, the thermal rate coefficients and ion product distributions have been determined at 300 K for the reactions of fourteen atomic and molecular cations, namely HO, CF, CF, CF, HO, NO, O, CO, CO, N, N, Ar, F and Ne (in order of increasing recombination energy), with SeF and TeF. The results are compared with those from the reactions of these ions with SF, for which the reactions with CF, CF, NO and F are reported for the first time. Several distinct processes are observed amongst the large number of reactions studied, including dissociative charge transfer, and F, F, F and F abstraction from the neutral reactant molecule to the reagent ion. The dissociative charge transfer channels are discussed in relation to vacuum ultraviolet photoelectron and threshold photoelectron-photoion coincidence spectra of XF (X = S, Se, and Te). For reagent ions whose recombination energies lie between the first dissociative ionisation limit, XF XF + F + e, and the onset of ionisation of the XF molecule, the results suggest that if dissociative charge transfer occurs, it proceeds via an intimate encounter. For those reagent ions whose recombination energies are greater than the onset of ionisation, long-range electron transfer may occur depending on whether certain physical factors apply, for example non-zero Franck-Condon overlap. From the reaction kinetics, limits for the heats of formation of SeF, SeF, TeF and TeF at 298 K have been obtained; H(SeF) < -369 kJ mol, H(SeF) < -621 kJ mol, H(TeF) > -570 kJ mol, and H(TeF) < -822 kJ mol
Infrared Photometry and Dust Absorption in Highly Inclined Spiral Galaxies
We present JHK surface photometry of 15 highly inclined, late-type (Sab-Sc)
spirals and investigate the quantitative effects of dust extinction. Using the
(J - H, H - K) two-color diagram, we compare the color changes along the minor
axis of each galaxy to the predictions from different models of radiative
transfer. Models in which scattering effects are significant and those with
more than a small fraction of the light sources located near the edge of the
dust distribution do not produce enough extinction to explain the observed
color gradients across disk absorption features. The optical depth in dust near
the plane as deduced from the color excess depends sensitively on the adopted
dust geometry, ranging from tau = 4 to 15 in the visual band. This suggests
that a realistic model of the dust distribution is required, even for infrared
photometry, to correct for dust extinction in the bulges of nearly edge-on
systems.Comment: Accepted for publication in the March 1996 AJ. LaTex source which
generates 27 pages of text and tables (no figures). Complete (text + figs)
compressed Postscript preprint is also available at
ftp://bessel.mps.ohio-state.edu/pub/terndrup/inclined.ps.Z (854 Mbyte
Therapists' perceptions of implementing constraint induced movement therapy: the enablers and barriers
Continuum surveys with LOFAR and synergy with future large surveys in the 1-2 GHz band
Radio astronomy is entering the era of large surveys. This paper describes
the plans for wide surveys with the LOw Frequency ARray (LOFAR) and their
synergy with large surveys at higher frequencies (in particular in the 1-2 GHz
band) that will be possible using future facilities like Apertif or ASKAP. The
LOFAR Survey Key Science Project aims at conducting large-sky surveys at 15,
30, 60, 120 and 200 MHz taking advantage of the wide instantaneous field of
view and of the unprecedented sensitivity of this instrument. Four topics have
been identified as drivers for these surveys covering the formation of massive
galaxies, clusters and black holes using z>6 radio galaxies as probes, the
study of the intercluster magnetic fields using diffuse radio emission and
Faraday rotation measures in galaxy clusters as probes and the study of star
formation processes in the early Universe using starburst galaxies as probes.
The fourth topic is the exploration of new parameter space for serendipitous
discovery taking advantage of the new observational spectral window open up by
LOFAR. Here, we briefly discuss the requirements of the proposed surveys to
address these (and many others!) topics as well as the synergy with other wide
area surveys planned at higher frequencies (and in particular in the 1-2 GHz
band) with new radio facilities like ASKAP and Apertif. The complementary
information provided by these surveys will be crucial for detailed studies of
the spectral shape of a variety of radio sources (down to sub-mJy sources) and
for studies of the ISM (in particular HI and OH) in nearby galaxies.Comment: to appear in the proceedings of "Panoramic Radio Astronomy:
Wide-field 1-2 GHz research on galaxy evolution", G. Heald and P. Serra eds.,
8 pages, 3 figure
Shapes and Shears, Stars and Smears: Optimal Measurements for Weak Lensing
We present the theoretical and analytical bases of optimal techniques to
measure weak gravitational shear from images of galaxies. We first characterize
the geometric space of shears and ellipticity, then use this geometric
interpretation to analyse images. The steps of this analysis include:
measurement of object shapes on images, combining measurements of a given
galaxy on different images, estimating the underlying shear from an ensemble of
galaxy shapes, and compensating for the systematic effects of image distortion,
bias from PSF asymmetries, and `"dilution" of the signal by the seeing. These
methods minimize the ellipticity measurement noise, provide calculable shear
uncertainty estimates, and allow removal of systematic contamination by PSF
effects to arbitrary precision. Galaxy images and PSFs are decomposed into a
family of orthogonal 2d Gaussian-based functions, making the PSF correction and
shape measurement relatively straightforward and computationally efficient. We
also discuss sources of noise-induced bias in weak lensing measurements and
provide a solution for these and previously identified biases.Comment: Version accepted to AJ. Minor fixes, plus a simpler method of shape
weighting. Version with full vector figures available via
http://www.astro.lsa.umich.edu/users/garyb/PUBLICATIONS
A Novel Joint Space-Wavenumber Analysis of an Unusual Antarctic Gravity Wave Event
As part of a collaborative research program between British Antarctic Survey, U.K. and Utah State University, USA, all sky airglow images were recorded at Halley Station Antarctica (75.5 S, 26.7 W). An unusual mesospheric gravity wave event was observed in the OH nightglow (nominal height 87 km) over a period of 3 hours on the 27â28 May, 2001. The characteristics of the bore wave event were determined by application of the one dimensional spatial S-Transform analysis. This is the first time such analysis has been performed on airglow data. By employing these local spatial spectral analysis, the evolution of the wave packet can be measured. The wave parameters (phase velocity, wave number, wavelength, period) were inferred from as little as 2 images (separated in time), which is a powerful ability when a data set of images is irregularly sampled in time, as is often the case in airglow imager studies. Several interesting and novel results were obtained regarding the dynamic evolution of the wave. The horizontal wavelength of the bore wave packet was seen to decrease as the packet evolved. Coincident with this observation, the horizontal phase speed decreased, with an associated decrease in wave packet amplitude
A close-pair binary in a distant triple supermassive black-hole system
Galaxies are believed to evolve through merging, which should lead to
multiple supermassive black holes in some. There are four known triple black
hole systems, with the closest pair being 2.4 kiloparsecs apart (the third
component is more distant at 3 kiloparsecs), which is far from the
gravitational sphere of influence of a black hole with mass 10
M (about 100 parsecs). Previous searches for compact black hole systems
concluded that they were rare, with the tightest binary system having a
separation of 7 parsecs. Here we report observations of a triple black hole
system at redshift z=0.39, with the closest pair separated by 140
parsecs. The presence of the tight pair is imprinted onto the properties of the
large-scale radio jets, as a rotationally-symmetric helical modulation, which
provides a useful way to search for other tight pairs without needing extremely
high resolution observations. As we found this tight pair after searching only
six galaxies, we conclude that tight pairs are more common than hitherto
believed, which is an important observational constraint for low-frequency
gravitational wave experiments.Comment: 21 pages, 6 figures. Published online by Nature on 25 June 2014.
Extremely minor differences with published version exis
Nitrogen fixation by caucasian clover and white clover in irrigated ryegrass pastures
The Nâ fixation ability of caucasian clover was
compared with that of white clover in irrigated
ryegrass pastures over years 2 and 3 of a grazing
experiment, using the Âčâ”N enrichment technique.
âEnduraâ caucasian clover was inoculated with
the specific Rhizobium strain ICC148. The N
concentration in clover herbage and the proportion
of clover N derived from Nâ fixation (PN) were
similar for both clovers at averages of 4.6%N and
50â60% respectively over the 2 years. The amount
of Nâ fixed per hectare was directly related to the
amount of clover dry matter (DM) produced by
the two clover species. Caucasian clover produced
four times the DM yield of white clover in year 2
(5400 cf. 1450 kg DM/ha) and four times the
amount of Nâ fixed in herbage (136 cf. 36 kg N/
ha). In year 3, caucasian clover produced 50%
more clover DM (3450 cf. 2370 kg DM/ha) and
Nâ fixed (98 cf. 66 kg N/ha) than white clover.
The increased N input from caucasian clover
increased grass %N and N uptake from soil in
caucasian clover pastures resulting in higher total
pasture production compared with white clover
pastures (15.7 cf. 14.2 t DM/ha) by year 3. In this
study, caucasian clover demonstrated greater
potential than white clover to meet the N demands
of high-yielding perennial ryegrass in an intensive
pastoral system.The authors acknowledge funding from the Struthers
Trust for the development of the grazing experiment at
Lincoln University and FRST funding for provision of
Âčâ¶N and N analyses. We thank the C. Alma Baker and Struthers
Trusts for providing A.D. Black with financial support
from post-graduate scholarships
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