A Selected Ion Flow Tube Study of the Reactions of Several Cations with the Group 6B Hexafluorides SF6, SeF6, and TeF6

The first investigation of the ion chemistry of SeF$_6$ and TeF$_6$ is presented. Using a selected ion flow tube, the thermal rate coefficients and ion product distributions have been determined at 300 K for the reactions of fourteen atomic and molecular cations, namely H$_3$O$^+$, CF$_3^+$, CF$^+$, CF$_2^+$, H$_2$O$^+$, N$_2$O$^+$, O$^+$, CO$_2^+$, CO$^+$, N$^+$, N$_2^+$, Ar$^+$, F$^+$ and Ne$^+$ (in order of increasing recombination energy), with SeF$_6$ and TeF$_6$. The results are compared with those from the reactions of these ions with SF$_6$, for which the reactions with CF$^+$, CF$_2^+$, N$_2$O$^+$ and F$^+$ are reported for the first time. Several distinct processes are observed amongst the large number of reactions studied, including dissociative charge transfer, and F$^-$, F, F$_2^-$ and F$_2$ abstraction from the neutral reactant molecule to the reagent ion. The dissociative charge transfer channels are discussed in relation to vacuum ultraviolet photoelectron and threshold photoelectron-photoion coincidence spectra of XF$_6$ (X = S, Se, and Te). For reagent ions whose recombination energies lie between the first dissociative ionisation limit, XF$_6$ $\rightarrow$ XF$_5^+$ + F + e$^-$, and the onset of ionisation of the XF$_6$ molecule, the results suggest that if dissociative charge transfer occurs, it proceeds via an intimate encounter. For those reagent ions whose recombination energies are greater than the onset of ionisation, long-range electron transfer may occur depending on whether certain physical factors apply, for example non-zero Franck-Condon overlap. From the reaction kinetics, limits for the heats of formation of SeF$_4$, SeF$_5$, TeF$_4$ and TeF$_5$ at 298 K have been obtained; $\Delta_f$H$^o$(SeF$_4$) < -369 kJ mol$^{-1}$, $\Delta_f$H$^o$(SeF$_5$) < -621 kJ mol$^{-1}$, $\Delta_f$H$^o$(TeF$_4$) > -570 kJ mol$^{-1}$, and $\Delta_f$H$^o$(TeF$_5$) < -822 kJ mol$^{-1}$

Infrared Photometry and Dust Absorption in Highly Inclined Spiral Galaxies

We present JHK surface photometry of 15 highly inclined, late-type (Sab-Sc) spirals and investigate the quantitative effects of dust extinction. Using the (J - H, H - K) two-color diagram, we compare the color changes along the minor axis of each galaxy to the predictions from different models of radiative transfer. Models in which scattering effects are significant and those with more than a small fraction of the light sources located near the edge of the dust distribution do not produce enough extinction to explain the observed color gradients across disk absorption features. The optical depth in dust near the plane as deduced from the color excess depends sensitively on the adopted dust geometry, ranging from tau = 4 to 15 in the visual band. This suggests that a realistic model of the dust distribution is required, even for infrared photometry, to correct for dust extinction in the bulges of nearly edge-on systems.Comment: Accepted for publication in the March 1996 AJ. LaTex source which generates 27 pages of text and tables (no figures). Complete (text + figs) compressed Postscript preprint is also available at ftp://bessel.mps.ohio-state.edu/pub/terndrup/inclined.ps.Z (854 Mbyte

Continuum surveys with LOFAR and synergy with future large surveys in the 1-2 GHz band

Radio astronomy is entering the era of large surveys. This paper describes the plans for wide surveys with the LOw Frequency ARray (LOFAR) and their synergy with large surveys at higher frequencies (in particular in the 1-2 GHz band) that will be possible using future facilities like Apertif or ASKAP. The LOFAR Survey Key Science Project aims at conducting large-sky surveys at 15, 30, 60, 120 and 200 MHz taking advantage of the wide instantaneous field of view and of the unprecedented sensitivity of this instrument. Four topics have been identified as drivers for these surveys covering the formation of massive galaxies, clusters and black holes using z>6 radio galaxies as probes, the study of the intercluster magnetic fields using diffuse radio emission and Faraday rotation measures in galaxy clusters as probes and the study of star formation processes in the early Universe using starburst galaxies as probes. The fourth topic is the exploration of new parameter space for serendipitous discovery taking advantage of the new observational spectral window open up by LOFAR. Here, we briefly discuss the requirements of the proposed surveys to address these (and many others!) topics as well as the synergy with other wide area surveys planned at higher frequencies (and in particular in the 1-2 GHz band) with new radio facilities like ASKAP and Apertif. The complementary information provided by these surveys will be crucial for detailed studies of the spectral shape of a variety of radio sources (down to sub-mJy sources) and for studies of the ISM (in particular HI and OH) in nearby galaxies.Comment: to appear in the proceedings of "Panoramic Radio Astronomy: Wide-field 1-2 GHz research on galaxy evolution", G. Heald and P. Serra eds., 8 pages, 3 figure

Shapes and Shears, Stars and Smears: Optimal Measurements for Weak Lensing

We present the theoretical and analytical bases of optimal techniques to measure weak gravitational shear from images of galaxies. We first characterize the geometric space of shears and ellipticity, then use this geometric interpretation to analyse images. The steps of this analysis include: measurement of object shapes on images, combining measurements of a given galaxy on different images, estimating the underlying shear from an ensemble of galaxy shapes, and compensating for the systematic effects of image distortion, bias from PSF asymmetries, and `"dilution" of the signal by the seeing. These methods minimize the ellipticity measurement noise, provide calculable shear uncertainty estimates, and allow removal of systematic contamination by PSF effects to arbitrary precision. Galaxy images and PSFs are decomposed into a family of orthogonal 2d Gaussian-based functions, making the PSF correction and shape measurement relatively straightforward and computationally efficient. We also discuss sources of noise-induced bias in weak lensing measurements and provide a solution for these and previously identified biases.Comment: Version accepted to AJ. Minor fixes, plus a simpler method of shape weighting. Version with full vector figures available via http://www.astro.lsa.umich.edu/users/garyb/PUBLICATIONS

A Novel Joint Space-Wavenumber Analysis of an Unusual Antarctic Gravity Wave Event

As part of a collaborative research program between British Antarctic Survey, U.K. and Utah State University, USA, all sky airglow images were recorded at Halley Station Antarctica (75.5 S, 26.7 W). An unusual mesospheric gravity wave event was observed in the OH nightglow (nominal height 87 km) over a period of 3 hours on the 27–28 May, 2001. The characteristics of the bore wave event were determined by application of the one dimensional spatial S-Transform analysis. This is the first time such analysis has been performed on airglow data. By employing these local spatial spectral analysis, the evolution of the wave packet can be measured. The wave parameters (phase velocity, wave number, wavelength, period) were inferred from as little as 2 images (separated in time), which is a powerful ability when a data set of images is irregularly sampled in time, as is often the case in airglow imager studies. Several interesting and novel results were obtained regarding the dynamic evolution of the wave. The horizontal wavelength of the bore wave packet was seen to decrease as the packet evolved. Coincident with this observation, the horizontal phase speed decreased, with an associated decrease in wave packet amplitude

A close-pair binary in a distant triple supermassive black-hole system

Galaxies are believed to evolve through merging, which should lead to multiple supermassive black holes in some. There are four known triple black hole systems, with the closest pair being 2.4 kiloparsecs apart (the third component is more distant at 3 kiloparsecs), which is far from the gravitational sphere of influence of a black hole with mass $\sim$10$^9$ M$_\odot$ (about 100 parsecs). Previous searches for compact black hole systems concluded that they were rare, with the tightest binary system having a separation of 7 parsecs. Here we report observations of a triple black hole system at redshift z=0.39, with the closest pair separated by $\sim$140 parsecs. The presence of the tight pair is imprinted onto the properties of the large-scale radio jets, as a rotationally-symmetric helical modulation, which provides a useful way to search for other tight pairs without needing extremely high resolution observations. As we found this tight pair after searching only six galaxies, we conclude that tight pairs are more common than hitherto believed, which is an important observational constraint for low-frequency gravitational wave experiments.Comment: 21 pages, 6 figures. Published online by Nature on 25 June 2014. Extremely minor differences with published version exis

Nitrogen fixation by caucasian clover and white clover in irrigated ryegrass pastures

The N₂ fixation ability of caucasian clover was compared with that of white clover in irrigated ryegrass pastures over years 2 and 3 of a grazing experiment, using the ¹⁵N enrichment technique. ‘Endura’ caucasian clover was inoculated with the specific Rhizobium strain ICC148. The N concentration in clover herbage and the proportion of clover N derived from N₂ fixation (PN) were similar for both clovers at averages of 4.6%N and 50–60% respectively over the 2 years. The amount of N₂ fixed per hectare was directly related to the amount of clover dry matter (DM) produced by the two clover species. Caucasian clover produced four times the DM yield of white clover in year 2 (5400 cf. 1450 kg DM/ha) and four times the amount of N₂ fixed in herbage (136 cf. 36 kg N/ ha). In year 3, caucasian clover produced 50% more clover DM (3450 cf. 2370 kg DM/ha) and N₂ fixed (98 cf. 66 kg N/ha) than white clover. The increased N input from caucasian clover increased grass %N and N uptake from soil in caucasian clover pastures resulting in higher total pasture production compared with white clover pastures (15.7 cf. 14.2 t DM/ha) by year 3. In this study, caucasian clover demonstrated greater potential than white clover to meet the N demands of high-yielding perennial ryegrass in an intensive pastoral system.The authors acknowledge funding from the Struthers Trust for the development of the grazing experiment at Lincoln University and FRST funding for provision of ¹⁶N and N analyses. We thank the C. Alma Baker and Struthers Trusts for providing A.D. Black with financial support from post-graduate scholarships