Deposition of Ti/TiC Composite Coatings on Implant Structures Using Laser Engineered Net Shaping

A new method of depositing hard and wear resistant composite coatings on metal-onmetal bearing surfaces of titanium implant structures is proposed and demonstrated. The method consists of depositing a Ti/TiC composite coating (~ 2.5 mm thick) on titanium implant bearing surfaces using Laser Engineered Net Shaping (LENS®). Defect-free composite coatings were successfully produced at various amounts of the reinforcing TiC phase with excellent interfacial characteristics using a mixture of commercially pure Ti and TiC powders. The coatings consisted of a mixture of coarser unmelted/partially melted (UMC) TiC particles and finer, discreet resolidified (RSC) TiC particles uniformly distributed in the titanium matrix. The amounts of UMC and RSC were found to increase with increasing TiC content of the original powder mixture. The coatings exhibited a high level of hardness, which increased with increasing TiC content of the original powder mixture. Fractographic studies indicated that the coatings, even at 60 vol.% TiC, do not fail in a brittle manner. Various aspects of LENS® deposition of Ti/TiC composite coatings are addressed and a preliminary understanding of structure-property-fracture correlations is presented. The current work shows that the proposed approach to deposit composite coatings using laser-based metal deposition processes is highly-effective, which can be readily utilized on a commercial basis for manufacture of high-performance implants.Mechanical Engineerin

Process Parameters Optimization for Ultrasonically Consolidated Fiber-Reinforced Metal Matrix Composites

As an emerging rapid prototyping technology, Ultrasonic Consolidation (UC) has been used to successfully fabricate metal matrix composites (MMC). The intent of this study is to identify the optimum combination of processing parameters, including oscillation amplitude, welding speed, normal force, operating temperature and fiber orientation, for manufacture of long fiber-reinforced MMCs. The experiments were designed using the Taguchi method, and an L25 orthogonal array was utilized to determine the influences of each parameter. SiC fibers of 0.1mm diameter were successfully embedded into an Al 3003 metal matrix. Two methods were employed to characterize the bonding between the fiber and matrix material: optical/electron microscopy and push-out tests monitored by an acoustic emission (AE) sensor. SEM images and data from push-out tests were analyzed and optimum combinations of parameters were achieved.Mechanical Engineerin

Multi-Material Ultrasonic Consolidation

Ultrasonic consolidation (UC) is a recently developed direct metal solid freeform fabrication process. While the process has been well-demonstrated for part fabrication in Al alloy 3003 H18, including with intricate cooling channels, some of the potential strengths of the process have not been fully exploited. One of them is its flexibility with build materials and the other is its suitability for fabrication of multi-material and functionally graded material parts with enhanced functional or mechanical properties. Capitalizing on these capabilities is critical for broadening the application range and commercial utilization of the process. In the current work, UC was used to investigate ultrasonic bonding of a broad range of engineering materials, which included stainless steels, Ni-base alloys, brass, Al alloys, and Al alloy composites. UC multimaterial part fabrication was examined using Al alloy 3003 as the bulk part material and the above mentioned materials as performance enhancement materials. Studies were focused on microstructural aspects to evaluate interface characteristics between dissimilar material layers. The results showed that most of these materials can be successfully bonded to Al alloy 3003 and vice versa using the ultrasonic consolidation process. Bond formation and interface characteristics between various material combinations are discussed based on oxide layer characteristics, material properties, and others.Mechanical Engineerin

Determination of active ingredients in commercial insecticides using spectral characteristics of Fourier transform infrared spectroscopy (FTIR)

Pesticides have become a basic necessity for yield development. This might be credited to the quickly expanding population, which has presented weight on the food creation industry.Fourier Transform Infra-red Spectroscopy utilizes sample with less course of action, less time consuming, simple, fast, non-destructive and environmental friendly infrared-based method. It makes use of Smart iTR window and pellets use on omnic transmission window. In FTIR the peaks formed for the representative sample are from 800 cm-1 to 4000 cm-1 of wavenumbers against the % transmittance. The FTIR spectra obtained for pesticide formulations were on par with the NIST (National Institute of Standards and Technology) spectra library. Comparing the commercial-grade spectra with the Spectrabase, NIST library and Bio-rad software showed the peak ranges for different functional groups of the compound and can be examined with KnowItAll software’s ProcessItIR and AnalyseItIR. We can obtain the active principle of the peak, peak intensities. This method can be viewed as genuine choices to long and tedious chromatographic strategies as a rule suggested for quality control of commercially accessible pesticide formulations and check for adultered formulations that harm agricultural produce.

Interface Microstructures and Bond Formation in Ultrasonic Consolidation

The quality of ultrasonically consolidated parts critically depends on the bond quality between individual metal foils. This necessitates a detailed understanding of interface microstructures and ultrasonic bonding mechanism. There is a lack of information on interface microstructures in ultrasonically consolidated parts as well as a lack of consensus on the mechanism of metal ultrasonic welding, especially on matters such as plastic deformation and recrystallization. In the current work, interface microstructures of an ultrasonically consolidated multi-material Al 3003-Ni 201 sample were analyzed in detail using optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, and orientation imaging microscopy. Based on the results of microstructural studies, the mechanism of metal ultrasonic welding has been discussed. The reasons for formation of defects/unbonded regions in ultrasonically consolidated parts have also been identified and discussedMechanical Engineerin

Improving Linear Weld Density in Ultrasonically Consolidated Parts

Ultrasonic consolidation is a novel additive manufacturing process with immense potential for fabrication of complex shaped three-dimensional metallic objects from metal foils. The proportion of bonded area to unbonded area along the layer interface, termed linear weld density (LWD), is perhaps the most important quality attribute of ultrasonically consolidated parts. Part mechanical properties largely depend on LWD and a high level of LWD must be ensured in parts intended for load-bearing structural applications. It is therefore necessary to understand what factors influence LWD or defect formation and devise methods to enhance bond formation during ultrasonic consolidation. The current work examines these issues and proposes strategies to ensure near 100% LWD in ultrasonically consolidated aluminum alloy 3003 parts. The work elucidates the effects of various process parameters on LWD and a qualitative understanding of the effects of process parameters on bond formation during ultrasonic consolidation is presented. The beneficial effects of using elevated substrate temperatures and its implications on overall manufacturing flexibility are discussed. A preliminary understanding of defect morphologies and defect formation is presented, based on which a method (involving surface machining) for minimizing defect incidence during ultrasonic consolidation is proposed and demonstrated. Finally, trade-offs between part quality and build time are discussed.Mechanical Engineerin

Maximum Height to Width Ratio of Freestanding Structures Built Using Ultrasonic Consolidation

Ultrasonic consolidation (UC) is a process whereby metal foils can be metallurgically bonded at or near room temperature. The UC process works by inducing high-speed differential motion (~20kHz) between a newly deposited layer and a substrate (which consists of a base plate and any previously deposited layers of material). This differential motion causes plastic deformation at the interface, which breaks up surface oxides and deforms surface asperities, bringing clean metal surfaces into intimate contact, where bonding occurs. If the substrate is not stiff enough to resist deflection during ultrasonic excitation of newly deposited layers, then it deflects along with the newly deposited layer, resulting in no differential motion and lack of bonding. Geometric issues which control substrate stiffness and deflection were investigated at Utah State University by building a number of free-standing rib structures with varying dimensions and orientations. Each structure was built to a height where lack of bonding between the previously deposited layers and the newly deposited layer caused the building process to fail, a height to width ratio (H/W) of approximately 1:1. The parts were then cut, polished, and viewed under a microscope. An ANSYS model was created to investigate analytically the cause of this failure. It appears build failure is due to excessive deflection of the ribs around a 1:1 H/W, resulting in insufficient differential motion and deformation to achieve bonding. Preliminary results show, when the H/W reaches 1:1, the von Mises stress is found to be tensile along portions of the bonding interface, which eliminates the compressive frictional forces necessary for plastic deformation and formation of a metallurgical bond. These tensile stresses are shown to be concentrated at regions near the edges of the newly deposited foil layer.Mechanical Engineerin

VISITOR PREFERENCES AND VALUES FOR WATER-BASED RECREATION: A CASE STUDY OF THE OCALA NATIONAL FOREST

We used the open-ended contingent valuation method to elicit willingnes to pay (WTP) for day visitors and extended visitors on the Ocala National Forest (ONF), Florida. A Tobit model specification was applied to account for the issues involved with censored WTP bids. The results reveal that visitors would pay more for improved recreational facilities at the ONF. In particular, our estimates show that visitors would pay $1 million for basic facilities,$1.9 million for moderate improvements, and $2.5 million for more improvements.contingent valuation, Tobit analysis, water-based recreation, Resource /Energy Economics and Policy, Q23, Q26,

Assessment of Skempton's pore water pressure parameters B and A using a high-capacity tensiometer

Saturation of soils is a prerequisite in many laboratory tests involving consolidation, permeability and stress-strain behaviour. The saturation process is usually time consuming, particularly in clay-rich soils, and this can incur substantial cost and potential delays in reporting findings. The saturation of samples is assessed using the well-established Skempton's pore water pressure parameter B. In a situation where the soil is fully saturated the B-value is approximately one. It is often the case that fine soil samples extracted from the ground, particularly those from below the water table, remain saturated. However, current testing protocols require evidence to verify a complete saturation prior to subsequent laboratory investigations. This paper reports experimental results exploring the hypothesis that, if the sample is ‘perceived’ to be saturated, then further saturation procedures may not be necessary to obtain reliable geotechnical parameters. Laboratory investigations were conducted on three different clays (Kaolin Clay, Belfast Clay and Oxford Clay) in a testing chamber instrumented with a high capacity tensiometer. The confining pressures were applied in a ramped fashion under undrained conditions. The response of the tensiometer confirmed that the samples were saturated from the very beginning of the loading process, as implied by the B-value being close to one. Further supplementary investigations were carried out to assess the Skempton's pore water pressure parameter A and the stress-strain behaviour of the soils. The combined finding provides further evidence to suggest that the saturation process as suggested in standards may not be necessary for fine grained soils to establish reliable geotechnical design parameters