14 research outputs found
ISSN-1996-918X Pak
Abstract Banana peel, a common fruit waste has been investigated to remove and preconcentrate Cr(III) from industrial wastewater. It was characterized by FT-IR spectroscopy. The parameters pH, contact time, initial metal ion concentration and temperature were investigated and the maximum sorption was found to be 95%. The binding of metal ions was found to be pH dependent with the optimal sorption occurring at pH 4. The retained species were eluted using 5mL of 2 M HNO 3 . The mechanism for the binding of Cr(III) on the banana peel surface was also studied in detail. The Langmuir and Dubinin-Radushkevich (D-R) isotherms were used to describe the partitioning behavior for the system at different temperatures. Kinetic and thermodynamic measurements of the banana peel for chromium ions were also studied. The method was applied for the removal and preconcentration of Cr(III) from industrial wastewater
Banana Peel: A Green and Economical Sorbent for Cr(III) Removal
Banana peel, a common fruit waste has been investigated to remove and preconcentrate Cr(III) from industrial wastewater. It was characterized by FT-IR spectroscopy. The parameters pH, contact time, initial metal ion concentration and temperature were investigated and the maximum sorption was found to be 95%. The binding of metal ions was found to be pH dependent with the optimal sorption occurring at pH 4. The retained species were eluted using 5mL of 2 M HNO3. The mechanism for the binding of Cr(III) on the banana peel surface was also studied in detail. The Langmuir and Dubinin-Radushkevich (D-R) isotherms were used to describe the partitioning behavior for the system at different temperatures. Kinetic and thermodynamic measurements of the banana peel for chromium ions were also studied. The method was applied for the removal and preconcentration of Cr(III) from industrial wastewater
Focused Ion Beam Analysis of Banana Peel and Its Application for Arsenate Ion Removal
Banana peel, a common fruit waste, has been investigated for its ability to remove arsenate ions from ground water as a function of pH, contact time, and initial metal ion concentration. Focused ion beam (FIB) analysis revealed the internal morphology of the banana peels. Arsenate ions were entered into micropores of banana peel. pH was seen to have no effect on the sorption process. Retained species were eluted using 5 mL of 2 M H2SO4. The kinetics of sorption were observed to follow the pseudo first order rate equation. The sorption data followed Freundlich and D-R isotherms. The energy value obtained from the D-R isotherms indicated that the sorption was physical in nature for arsenate species. Our study has shown that banana peel has the ability to remove arsenate species from ground water samples
Increasing ciprofloxacin resistance of isolates from infected urines of a cross-section of patients in Karachi
<p>Abstract</p> <p>Background</p> <p>The objective of the research was to evaluate the current effectiveness of Ciprofloxacin on the uropathogens prevalent in infected urines of a cross-section of patients in Karachi, Pakistan.</p> <p>Findings</p> <p>An observational study conducted in a private diagnostic laboratory and its branches in key areas of Karachi City from February 2010 to July 2011. A total of 2963 consecutive urine samples were cultured on chocolate agar, CLED medium and selective EMB agar. Growth of possible uropathogens was noted, and compared retrospectively with earlier lab data of suggestive urine cultures (<it>n</it> = 1997) recorded during January 2009 and December 2009. The isolates were identified using routine procedures and the API 20 system and evaluated for their sensitivity to ciprofloxacin by Kirby-Bauer disk diffusion method. Data was subjected to statistical analysis on SPSS version 16. Out of the present-day culture-positive urines, 2409 (80.4%) yielded gram-negative rods, and 554 (18.5%) gram-positive cocci. <it>E.coli</it> (43.1%) was most frequent, followed by <it>Klebsiella pneumoniae</it> (22.4%) and <it>Staphylococcus aureus</it> (15.5%). 57.2% of the Gram-negative bacteria and 48.7% of the Gram-positive isolates were resistant to ciprofloxacin. In the earlier (2009) screening, 39% of Gram-negative rods and 48% of Gram-positive cocci were indifferent to the drug.</p> <p>Conclusions</p> <p>A decrease in bacterial susceptibility of uropathogens to ciprofloxacin, a commonly prescribed drug in our population, is underlined, occurring possibly due to overuse pressure. Empirical initial treatment with ciprofloxacin would be inadequate in more than half of UTI cases, thereby counseling increased C/S testing of urines to provide existing sensitivity data for apt drug prescription.</p
School inspection and supervision in Pakistan: Approaches and issues
This article traces how the concept of educational inspection has evolved in Pakistan, especially in the province of Sindh, and discusses whether the existing inspection system helps to improve quality and establish accountability. The inspection system that originated in colonial days has evolved to incorporate the notion of using supervision to provide a range of support to school-based efforts to improve performance. The shift, however, has been in terminology only, since it has not signalled a major shift in how the job is carried out in practice. The article argues that as a strategy for establishing accountability and improving quality in education, inspection and supervision rely on several interdependent variables. Improvements in educational quality will require a balance among three factors: the availability of relevant and adequate physical, human, and financial resources; effective and empowered leadership; and functional monitoring, evaluation, and professional support for schools