1,152 research outputs found
Effect of exchange interaction on superparamagnetic relaxation
We use Langer's approach to calculate the reaction rate of a system of two
(classical) spins interacting via the exchange coupling in a magnetic field
, with uniaxial anisotropy of constant .
We find a particular value of the exchange coupling, that is , where , which separates two regimes
corresponding to a two-stage and one-stage switching.
For the N\'eel-Brown result for the one-spin problem is recovered.Comment: 7 pages, 2 eps figures, fig.1 of better quality can be provided upon
reques
Geometric Aspects of the Dipolar Interaction in Lattices of Small Particles
The hysteresis curves of systems composed of small interacting magnetic
particles, regularly placed on stacked layers, are obtained with Monte Carlo
simulations. The remanence as a function of temperature, in interacting
systems, presents a peak that separates two different magnetic states. At low
temperatures, small values of remanence are a consequence of antiferromagnetic
order due to the dipolar interaction. At higher values of temperature the
increase of the component normal to the lattice plane is responsible for the
small values of remanence. The effect of the number of layers, coordination
number and distance between particles are investigated.Comment: 5 pages, 7 figure
Role of dipolar interactions in a system of Ni nanoparticles studied by magnetic susceptibility measurements
The role of dipolar interactions among Ni nanoparticles (NP) embedded in an
amorphous SiO2/C matrix with different concentrations has been studied
performing ac magnetic susceptibility Chi_ac measurements. For very diluted
samples, with Ni concentrations < 4 wt % Ni or very weak dipolar interactions,
the data are well described by the Neel-Arrhenius law. Increasing Ni
concentration to values up to 12.8 wt % Ni results in changes in the
Neel-Arrhenius behavior, the dipolar interactions become important, and need to
be considered to describe the magnetic response of the NPs system. We have
found no evidence of a spin-glasslike behavior in our Ni NP systems even when
dipolar interactions are clearly present.Comment: 7 pages, 5 figures, 3 table
Spin Disorder and Magnetic Anisotropy in Fe3O4 Nanoparticles
We have studied the magnetic behavior of dextran-coated magnetite
(FeO) nanoparticles with median particle size \left=8 .
Magnetization curves and in-field M\"ossbauer spectroscopy measurements showed
that the magnetic moment of the particles was much smaller than the bulk
material. However, we found no evidence of magnetic irreversibility or
non-saturating behavior at high fields, usually associated to spin canting. The
values of magnetic anisotropy from different techniques indicate that
surface or shape contributions are negligible. It is proposed that these
particles have bulk-like ferrimagnetic structure with ordered A and B
sublattices, but nearly compensated magnetic moments. The dependence of the
blocking temperature with frequency and applied fields, ,
suggests that the observed non-monotonic behavior is governed by the strength
of interparticle interactions.Comment: 11 pages, 7 figures, 3 Table
Phase transition in nanomagnetite
Recently, the application of nanosized magnetite particles became an area of growing interest for
their potential practical applications. Nanosized magnetite samples of 36 and 9 nm sizes were
synthesized. Special care was taken on the right stoichiometry of the magnetite particles. Mössbauer
spectroscopy measurements were made in 4.2–300 K temperature range. The temperature
dependence of the intensities of the spectral components indicated size dependent transition taking
place in a broad temperature range. For nanosized samples, the hyperfine interaction values and their
relative intensities changed above the Verwey transition temperature value of bulk megnetite. The
continuous transition indicated the formation of dendritelike granular assemblies formed during the
preparation of the samples
Tailoring Fe/Ag Superparamagnetic Composites by Multilayer Deposition
The magnetic properties of Fe/Ag granular multilayers were examined by SQUID
magnetization and Mossbauer spectroscopy measurements. Very thin (0.2 nm)
discontinuous Fe layers show superparamagnetic properties that can be tailored
by the thickness of both the magnetic and the spacer layers. The role of
magnetic interactions was studied in novel heterostructures of
superparamagnetic and ferromagnetic layers and the specific contribution of the
ferromagnetic layers to the low field magnetic susceptibility was identified.Comment: 5 pages and 3 figure
Magnetic properties of polypyrrole - coated iron oxide nanoparticles
Iron oxide nanoparticles were prepared by sol -gel process. Insitu
polymerization of pyrrole monomer in the presence of oxygen in iron oxide
ethanol suspension resulted in a iron oxide - polypyrrole nanocomposite. The
structure and magnetic properties were investigated for varying pyrrole
concentrations. The presence of the gamma - iron oxide phase and polypyrrole
were confirmed by XRD and FTIR respectively. Agglomeration was found to be
comparatively much reduced for the coated samples, as shown by TEM. AC
susceptibility measurements confirmed the superparamagnetic behaviour.
Numerical simulations performed for an interacting model system are performed
to estimate the anisotropy and compare favourably with experimental results.Comment: 11 pages,8 figure
Magnetic relaxation in finite two-dimensional nanoparticle ensembles
We study the slow phase of thermally activated magnetic relaxation in finite
two-dimensional ensembles of dipolar interacting ferromagnetic nanoparticles
whose easy axes of magnetization are perpendicular to the distribution plane.
We develop a method to numerically simulate the magnetic relaxation for the
case that the smallest heights of the potential barriers between the
equilibrium directions of the nanoparticle magnetic moments are much larger
than the thermal energy. Within this framework, we analyze in detail the role
that the correlations of the nanoparticle magnetic moments and the finite size
of the nanoparticle ensemble play in magnetic relaxation.Comment: 21 pages, 4 figure
Structural and magnetic properties of CoPt mixed clusters
In this present work, we report a structural and magnetic study of mixed
Co58Pt42 clusters. MgO, Nb and Si matrix can be used to embed clusters,
avoiding any magnetic interactions between particles. Transmission Electron
Microscopy (TEM) observations show that Co58Pt42 supported isolated clusters
are about 2nm in diameter and crystallized in the A1 fcc chemically disordered
phase. Grazing Incidence Small Angle X-ray Scattering (GISAXS) and Grazing
Incidence Wide Angle X-ray Scattering (GIWAXS) reveal that buried clusters
conserve these properties, interaction with matrix atoms being limited to their
first atomic layers. Considering that 60% of particle atoms are located at
surface, this interactions leads to a drastic change in magnetic properties
which were investigated with conventional magnetometry and X-Ray Magnetic
Circular Dichro\"{i}sm (XMCD). Magnetization and blocking temperature are
weaker for clusters embedded in Nb than in MgO, and totally vanish in silicon
as silicides are formed. Magnetic volume of clusters embedded in MgO is close
to the crystallized volume determined by GIWAXS experiments. Cluster can be
seen as a pure ferromagnetic CoPt crystallized core surrounded by a
cluster-matrix mixed shell. The outer shell plays a predominant role in
magnetic properties, especially for clusters embedded in niobium which have a
blocking temperature 3 times smaller than clusters embedded in MgO
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